Fire Science and Technology
Online ISSN : 1882-0492
Print ISSN : 0285-9521
ISSN-L : 0285-9521
Science
Calcination Temperature Effects to CO-Gas Sensor of Pt-Dispersed Hydrous SnO2 Gel
Takashi HandaHiroshi FukayaOsami SugawaYoshinori TerasawaKoichi EndohYoshiaki Okayama
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1983 Volume 3 Issue 1 Pages 1-12

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Abstract

A CO gas sensor which works at room temperature without an inner heater has been investigated. The sensing material is ceramics made from hydrous SnO2 gel with Pt dispersion. The effect of calcination in the range from room temperature to 1100°C was studied. The increment of crystallite size of SnO2 started from the calcination temperature of 400°C, and increment of its size was lowered by Pt dispersion. The crystallite size of Pt increased in the range from 650°C to 800°C and leveled off above 800°C. The specific surface area of Pt-dispersed hydrous SnO2 gel was larger than that of hydrous SnO2 gel without Pt. The relation between current (I) and voltage (V) was found to be I = KVα. The value of α was larger than 1 for calcination temperature below 650°C for Pt-dispersed hydrous SnO2 gel, and at 450°C the value of α showed a maximum. The conductance of Pt-dispersed hydrous SnO2 gel was less than that of hydrous SnO2 gel without Pt. The ceramic with Pt/Sn = 4.4 mole% calcined at 450°C gave the best response to CO gas.

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© 1983 Center for Fire Science and Technology, Research Institute for Science and Technology, Tokyo University of Science
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