Abstract
Sodium (Z)-15-carboxylato-8-(2-(((Z)-3-carboxylatoacryloyl)oxy) ethyl)-4,13-dioxo-5,11,12-trioxa-8,16-diazahentriacont-2-enoate has been synthesized. The chemical structure was confirmed by FT-IR and 1HNMR spectroscopy. The surface properties of the synthesized trianionic surfactant, including the critical micelle concentration (CMC), effectiveness (πcmc), maximum surface excess (Γmax), and minimum surface area (Amin) were determined from surface tension measurements. The efficiency of the trianionic surfactant to remove Pb(II) was determined using a flotation cell at different surfactant concentrations (below, at and beyond the CMC). Flame atomic absorption spectroscopy was used to determine the initial and final concentrations of Pb(II) ions. At pH 6 and a foaming time of 2 hr, the removal efficiency of Pb(II) increases with increasing the trianionic surfactant concentration.
Kurzfassung
Natrium-(Z)-15-carboxylato-8-(2-((Z-(Z)-3-carboxylatoacryloyl)oxy)-ethyl)-4,13-dioxo-5,11,12-trioxa-8,16-diazahentriacont-2-enoat wurde synthetisiert. Die chemische Struktur wurde mittels FT-IR- und 1H-NMR-Spektroskopie bestätigt. Die Oberflächeneigenschaften des synthetisierten trianionischen Tensids, d.h. die kritische Mizellenbildungskonzentration (CMC), der Oberflächendruck (πcmc), der maximale Oberflächenüberschuss (Γmax) und der minimale Platzbedarf (Amin), wurden aus Oberflächenspannungsmessungen bestimmt. Die Effizienz des trianionischen Tensids zur Entfernung von Pb(II)-Ionen wurde unter Verwendung einer Flotationszelle bei verschiedenen Tensidkonzentrationen (unterhalb, bei und oberhalb der CMC) bestimmt. Die Flammenatomabsorptionsspektroskopie wird verwendet, um die anfänglichen und endgültigen Konzentrationen der Pb(II)-Ionen zu bestimmen. Die Effizienz der Entfernung von Pb(II) nahm mit zunehmender Konzentration des Trianiontensids bei einem pH von 6 und einer Schaumbildungsdauer von 2 Stunden zu.
References
1. El-Feky, A. A., Shalaby, M. N. and El-Shamy, O. A. A.: Adsorption of some surfactants onto polyvinyl alcohol as hydrophobic polymer surface, J. Disp. Sci. and Technol.30 (2010) 1091. 10.1080/01932690802548536Search in Google Scholar
2. Elshamy, O. A. A: Effectiveness of some nonionic surfactants as corrosion inhibitors for carbon steel in hydrochloric acid solution, Advanced Materials Researches787 (2013) 2011. 10.4028/www.scientific.net/AMR.787.211Search in Google Scholar
3. Khidr, T. T., Doheim, M. M. and El-Shamy, O. A. A.: Pour point depressant of fuel oil using non-ionic surfactants, Petroleum Science and Technology33 (2015) 1619. 10.1080/10916466.2015.1081942Search in Google Scholar
4. Rosen, M. J.: Surfactants and Interfacial Phenomena, Wiley-Interscience, New York, NY, USA, 3rd edition (2004). 10.1002/0471670561Search in Google Scholar
5. Azzam, E. M. S. and Abd El-Aal, A. A.: Corrosion inhibition efficiency of synthesized poly 12-(3-amino phenoxy) dodecane-1-thiol surfactant assembled on silver nanoparticles,, Egyptian Journal of Petroleum22 (2013) 293. 10.1016/j.ejpe.2013.06.008Search in Google Scholar
6. Habila, M., Yilmaz, E., Alothman, Z. A. and Soylak, M.: Flame atomic absorption pectrometric determination of Cd, Pb and Cu in food samples after pre-concentration using 4-(2-thiazolylazo) resorcinol-modified activated carbon, J. Industrial and Eng. Chemistry20 (2014) 3989. 10.1016j.jiec.2013.12.101Search in Google Scholar
7. Ho, Y. S., Ng, J. C. Y. and McKay, G.: Removal of Lead (II) from Effluents by sorption on peat using second-ordered kinetics, Separation Science and Technology36 (2001). 10.1081/SS-100001077Search in Google Scholar
8. Wingenfelder, U., Hansen, C., Furrer, G. and Schulin, R.: Removal of Heavy metals from mine water by natural zeolites, Environmental Science and Technology39 (2005) 4606. 16047799 10.1021/es048482sSearch in Google Scholar PubMed
9. Senevirate, M.: A practical approache to water conservation for commercial and Industrial Facilities, Elsevier Science (2007).Search in Google Scholar
10. Clarke, A. N. and Wilson, D. J.: Foam flotation: Theory and applications, chemical Industries, Marcel Dekker, New York432 (1983).Search in Google Scholar
11. Suleiman, J. S., Hu, B., Huang, Ch. and Zhang, N.: Determination of Cd, Co, Ni and Pb in biological samples by microcolumn packed with black stone (Pierre noire) online coupled with ICP-OES, J. Hazardous Materials157 (2008) 410. 18329794 10.1016/j.jhazmat.2008.01.014Search in Google Scholar PubMed
12. Daftsis, E. J. and Zachariadis, G. A.: Analytical Performance of ETAAS method for Cd, Co, Cr and Pb determination in blood fractions samples, Talanta71 (2007) 722. 19071365 10.1016/j.talanta.2006.05.029Search in Google Scholar PubMed
13. Candir, S., Narin, I. and Soylak, M.: Ligandless Cloud Point Extraction of Cr(III), Pb(II), Cu(II), Ni(II), Bi(III), and Cd(II) Ions in Environmental Samples with Tween 80 and Flame Atomic Absorption Spectrometric Determination, Talanta77 (2008) 289. 18804635 10.1016/j.talanta.2008.06.024Search in Google Scholar PubMed
14. Al-Sabagh, A. M., Abd-El-Bary, H. M., El-Gazawy, R. A., Mishirif, M. R. and Hussein, B. M.: Surface active and thermodynamic properties of some surfactants derived from locally linear and heavy alkylbenzene in relation to corrosion inhibition efficiency, Materials and Corrosion62 (2001) 1015. 10.1002/maco.201006017Search in Google Scholar
15. Singh, N. and Ghosh, K. K.: Micellar Characteristics and Surface Properties of Some Sulfobetaine Surfactants. Tenside Surfactants Detergents48 (2011) 160. 10.3139/113.110118Search in Google Scholar
16. Zhoua, T., Yang, H., Xua, X., Wang, X., Wang, J. and Dong, G.: Synthesis, surface and aggregation properties of nonionic poly(ethylene oxide) gemini surfactants, Colloids and surfaces A: Physicochem. Eng. Aspects317 (2008) 339–343. 10.1016/j.colsurfa.2007.11.008Search in Google Scholar
17. Liua, X.-P., Fenga, J., Zhang, L., Gong, Q.-T., Zhao, S. and Yua, J.-Y.: Synthesis and properties of a novel class of anionic gemini surfactants with polyoxyethylene spacers, Colloids and surfaces A: Physicochem. Eng. Aspects362 (2010) 39. 10.1016/j.colsurfa.2010.03.037Search in Google Scholar
18. Rujirawanich, V., Chuyingsakulultip, N., Triroj, M., Malakul, P. and Chavadej, S.: Recovery of Surfactants from an aqueous solution using continuous multistage foam fractionation: Influence of design Parameters, Chem Eng. Process.52 (2012) 41. 10.1016/j.cep.2011.12.002Search in Google Scholar
19. Erdem, M., Ucar, S., Karagöz, S. and Tay, T.: Removal of Lead (II) Ions from Aqueous Solutions onto Activated Carbon Derived from Waste Biomass, The Scientific World Journal2013 (2013). 10.1155/2013/146092Search in Google Scholar PubMed PubMed Central
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