Abstract
Five bentonite samples of different compositions and geneses were saturated with Cs and Sr in the static regime. Desorption is examined during the filtration of distilled water through saturated samples. Both elements are firmly retained to most of the bentonite samples. The Cs and Sr desorption values were 12–20%, and 2.5–23%, respectively. Structural changes in the clay fraction of bentonites resulted from the sorption–desorption of Cs and Sr were studied by the method of X-ray diffraction.
Similar content being viewed by others
References
Erdey-Grúz, T., Transport Phenomena in Aqueous Solutions, 2nd ed., London: Adam Hilger, 1974.
Galamboš, M., Kufcáková, J., and Rajec, P., Sorption of strontium on slovak bentonites, J. Radioanal. Nucl. Chem., 2009, vol. 281, p. 347–357.
Galamboš, M., Paucová, V., Kufcáková, J., et al., Cesium sorption on bentonites and montmorillonite K10, J. Radioanal. Nucl. Chem., 2010, vol. 284, pp. 55–64.
Izmenenie okruzhayushchei sredy i klimata: prirodnye i svyazannye s nimi tekhnogennye katastrofy: v 8 t. (Environmental and Climate Change: Natural and Related Man-Made Disasters, 8 vols.), Laverov, N.P., Ed., Moscow: IFZ RAN, 2008.
Khan, S.A., Sorption of the long-lived radionuclides caesium- 134, strontium-85 and cobalt-60 on bentonite, J. Radioanal. Nucl. Chem., 2003, vol. 258, no. 1, pp. 3–6.
Kuleshova, M.L., Danchenko, N.N., Sergeev, V.I., and Shimko, T.G., The properties of bentonites as a material for sorptive barriers, Moscow Univ. Geol. Bull., 2014, vol. 69, no. 5, pp. 356–364.
Laverov, N.P., Velichkin, V.I., Omel’yanenko, B.I., Petrov, V.A., and Tarasov, N.N., New approach to underground keeping of high radioactive wastes of Russia, Geoecology, 2000, no. 1, pp. 3–12.
Lima, E.J., Bosch, P., and Bulbulian, S., Modification of the structure of natural bentonite and study on the sorption of Cs+, J. Radioanal. Nucl. Chem., 1998, vol. 237, nos. 1–2, pp. 41–45.
Maslova, K.M., Dynamic method of investigation of sorption–desorption behavior of 137Cs in soils and organomineral sorbents caused by variations in radioactivity in a solid body, Extended Abstract of Cand. Sci. Dissertation, Obninsk, 2014.
Murali, M.S. and Mathur, J.N., Sorption characteristics of Am(III), Sr(II) and Cs(I) on bentonite and granite, J. Radioanal. Nucl. Chem., 2002, vol. 254, no. 1, pp. 129–136.
Popov, V.E., Maslova, K.M., and Stepina, I.A., Effect of periodic wetting and drying on selective sorption of 137Cs by mixtures of soil and organomineral sorbent, Pochvovedenie, 2013, no. 11, pp. 1357–1366.
Sabodina, M.N., Regularities of behavior of radionuclides for creation of clay-based technogenic-geochemical barrier, Extended Abstract of Cand. Sci. Dissertation, Moscow, 2008.
Sergeev, V.I., Skvaletskii, M.E., and Kuleshova, M.L., Evaluation of a ground strata as a natural barrier on the migration way of toxic pollutants, in Geografiya. Programma “Universitety Rossii” (Geography. Program “Universities of Russia”), Moscow: Mosk. Gos. Univ., 1993, pp. 285–296.
Sergeev, V.I., Shimko, T.G., Kuleshova, M.L., and Svitoch, N.A., Quintitative assessment of the ground sequence as a geochemical barrier, in Geokhimicheskie bar’ery v zone gipergeneza (Geochemical Barriers in the Hypergenesis Zone), Kasimov, N.S. and Vorob’ev, A.E., Eds., Moscow: Mosk. Gos. Univ., 2002, pp. 334–346.
Shlykov, V.G., Rentgenovskii analiz mineral’nogo sostava dispersnykh gruntov (X-Ray Analysis of the Mineral Composition of Dispersed Soils), Moscow: GEOS, 2006.
Yildiz, B., Erten, H.N., and Kis, M., The sorption behavior of Cs+ ion on clay minerals and zeolite in radioactive waste management: kinetics and thermodynamics, J. Radioanal. Nucl. Chem., 2011, vol. 288, pp. 475–483.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.L. Kuleshova, N.N. Danchenko, V.L. Kosorukov, V.I. Sergeev, T.G. Shimko, 2017, published in Vestnik Moskovskogo Universiteta, Seriya 4: Geologiya, 2017, No. 3, pp. 60–68.
About this article
Cite this article
Kuleshova, M.L., Danchenko, N.N., Kosorukov, V.L. et al. A study of strontium and cesium sorption-desorption on bentonites of different composition. Moscow Univ. Geol. Bull. 72, 290–298 (2017). https://doi.org/10.3103/S0145875217040032
Received:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S0145875217040032