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Effect of Cysteine as Environmentally Friendly Inhibitor on AA6061-T6 Corrosion in 0.5 M HCl: Electrochemical and Surface Studies

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Abstract

The inhibitive action of cysteine was investigated against the corrosion of aluminium alloy 6061-T6 (AA6061-T6) in a 0.5 M hydrochloric acidic medium in the temperatures range of 303–323 K using potentiodynamic polarization as well as electrochemical impedance spectroscopy methods. The electrochemical results of the former were validated by the latter. Cysteine showed mixed inhibitor behavior and exhibited good inhibition performance. The thermodynamic properties indicated mixed adsorption behavior of cysteine, which satisfied the Langmuir adsorption isotherm. The surface morphological investigation of both corroded and inhibited specimens was performed using a scanning electron microscopy and atomic force microscope, which revealed the adsorption of cysteine onto the alloy surface.

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REFERENCES

  1. Davis, J.R., Corrosion of Aluminum and Aluminum Alloys, Materials Park, OH: ASM International, 1999, 1st ed.

    Book  Google Scholar 

  2. Polmear, I.J., Light Alloys from Traditional Alloys to Nanocrystals, Oxford: Elsevier, 2006, 4th ed.

    Google Scholar 

  3. El-Shafei, A.A., Abd El-Maksoud, S.A., and Fouda, A.S., Corros. Sci., 2004, vol. 46, pp. 579–590.

    Article  Google Scholar 

  4. Hamadi, L., Mansouri, S., Oulmi, K., and Kareche, A., Egypt. J. Petrol., 2018, vol. 27, pp. 1157–1165.

    Article  Google Scholar 

  5. Oguzie, E.E., Li, Y., and Wang, F.H., Electrochim. Act-a, 2007, vol. 53, pp. 909–914.

    Article  Google Scholar 

  6. Raja, A.S., Venkatesan, R., Sonisheeba, R., Thomas Paulraj, J., et al., Int. J. Adv. Res. Chem. Sci., 2014, vol. 1, pp. 101–109.

    Google Scholar 

  7. Wang, T., Wang, J., and Wu, Y., Corros. Sci., 2015, vol. 97, pp. 89–99.

    Article  Google Scholar 

  8. Shkirskiy, V., Keil, P., Hintze-Bruening, H., Leroux, F., et al., Corros. Sci., 2015, vol. 100, pp. 101-112.

    Article  Google Scholar 

  9. Mobin, M., Zehra, S., and Parveen, M., J. Mol. Liq., 2016, vol. 216, pp. 598–607.

    Article  Google Scholar 

  10. Fontana, M.G., Corrosion Engineering, New York: McGraw-Hill, 1987, 3rd ed.

    Google Scholar 

  11. Khaled, K.F. and Al-Qahtani, M.M., Mater. Chem. Phys., 2009, vol. 113, pp. 150–158.

    Article  Google Scholar 

  12. Riggs, Jr., O.L., Corrosion Inhibitors, Houston, TX: C.C. Nathan, 1973, 2nd ed.

    Google Scholar 

  13. Ateya, B.G., El-Khair, M.B.A., and Abdel-Hamed, I.A., Corros. Sci., 1976, vol. 16, pp. 163–169.

    Article  Google Scholar 

  14. Abboud, Y., Abourriche, A., Saffaj, T., Berrada, M., et al., Appl. Surf. Sci., 2006, vol. 252, pp. 8178–8184.

    Article  Google Scholar 

  15. Lee, E.J. and Pyun, S.I., Corros. Sci., 1995, vol. 37, pp. 157–168.

    Article  Google Scholar 

  16. Noor, E.A., Mater. Chem. Phys., 2009, vol. 114, pp. 533–541.

    Article  Google Scholar 

  17. Pinto, G.M., Nayak, J., and Nityananda Shetty, A., Mater. Chem. Phys., 2011, vol. 125, pp. 628–640.

    Article  Google Scholar 

  18. Fakrudeen, S.P., Lokesh, H.B., Ananda Murthy, H.C., and Bheema Raju, V., IOSRJ. Appl. Chem., 2012, vol. 2, pp. 37–47.

    Google Scholar 

  19. Ashassi-Sorkhabi, H., Shabani, B. Aligholipour, B., and Seifzadeh, D., Appl. Surf. Sci., 2006, vol. 252, pp. 4039–4047.

    Article  Google Scholar 

  20. Abd El Rehim, S.S., Hassan, H.H., and Amin, M.A., Mater. Chem. Phys., 2001, vol. 20, pp. 64–72.

    Article  Google Scholar 

  21. Ech-chihbi, E., Belghiti, M.E., Salim, R., Oudda, H., et al., Surf. Interfaces, 2017, vol. 9, pp. 206–217.

    Article  Google Scholar 

  22. Metikoš-Huković, M., Babič, R., and Grubač, Z., J. Appl. Electrochem., 1998, vol. 28, pp. 433–439.

    Article  Google Scholar 

  23. Hsu, C.H. and Mansfeld, F., Corrosion, 2001, vol. 57, pp. 747–748.

    Article  Google Scholar 

  24. Fouda, A.S., Mohamed, M.T., and Soltan, M.R., J. Electrochem. Sci. Technol., 2013, vol. 4, pp. 61–70.

    Article  Google Scholar 

  25. Schorr, M. and Yahalom, J., Corros. Sci., 1972, vol. 12, pp. 867–868.

    Article  Google Scholar 

  26. Ashassi-Sorkhabi, H., Shaabani, B., and Seifzadeh, D., Appl. Surf. Sci., 2005, vol. 239, pp. 154–164.

    Article  Google Scholar 

  27. Abd El-Rehim, S.S., Ibrahim, M.A.M., and Khaled, K.F., J. Appl. Electrochem., 1999, vol. 29, pp. 593–599.

    Article  Google Scholar 

  28. Bayol, E., Kayakırılmaz, K., and Erbil, M., Mater. Chem. Phys., 2007, vol. 104, pp. 74–82.

    Article  Google Scholar 

  29. Kumari, P., Shetty, P., Rao, S.A., and Sunil, D., Trans. Indian Inst. Met., 2017, vol. 70, pp. 1139–1150.

    Article  Google Scholar 

  30. Bereket, G. and Pinarbsi, A., Corros. Eng. Sci. Technol., 2004, vol. 39, pp. 308–312.

    Article  Google Scholar 

  31. Abdel Ghanyl, N.A., El-Shenawy, A.E., and Hussien, W.A.M., Modern Appl. Sci., 2011, vol. 5, pp. 19–29.

    Google Scholar 

  32. Hackerman, N., Snavely, E.S., Jr., and Payne, J.S., Jr., J. Electrochem. Soc., 1966, vol. 113, pp. 671–686.

    Article  Google Scholar 

Download references

ACKNOWLEDGMENTS

The authors are grateful to Manipal Institute of Technology, Manipal Academy of Higher Education (A Deemed University), Manipal, India, for providing the laboratory facilities.

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Correspondence to Prakash Shetty.

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Preethi Kumari P., Shetty, P., Nagalaxmi et al. Effect of Cysteine as Environmentally Friendly Inhibitor on AA6061-T6 Corrosion in 0.5 M HCl: Electrochemical and Surface Studies. Surf. Engin. Appl.Electrochem. 56, 624–634 (2020). https://doi.org/10.3103/S1068375520050087

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  • DOI: https://doi.org/10.3103/S1068375520050087

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