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The Influence of Equal Channel Angular Pressing on Structure and Mechanical Properties of New β-Ti Alloy Ti–10Mo–8Nb–6Zr

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Abstract

This work presents comparative studies of structural and mechanical properties of a new β-Ti alloy Ti–10Mo–8Nb–6Zr exposed to conventional cold rotational forging and equal channel angular pressing (ECAP) at 250°C. The main phase in the initial quenched state after forging and ECAP is the BCC β phase. Broadening of X-ray lines of the β phase and TEM data indicate refinement of structure and increase in concentration of lattice defects after deformational treatment. In the initial state, the alloy has ultimate tensile strength of about 700 MPa, the yield stress of 450 MPa, and relative elongation to failure of ~30%. As a consequence of forging, the ultimate strength and yield stress of Ti–10Mo–8Nb–6Zr alloy increase to 1230 and 950 MPa, and after ECAP, they increase to 1280 and 1270 MPa, respectively; also, the relative elongation decreases to 6%. Significant improvement of strength properties of Ti–10Mo–8Nb–6Zr alloy exposed to ECAP makes it more promising for application in the medical field.

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Notes

  1. Here and below compositions of the alloys are give in wt %.

REFERENCES

  1. Brunette, D.M., Tengvall, P., Textor, M., and Thomsen, P., Titanium in Medicine, Berlin: Springer, 2001.

    Book  Google Scholar 

  2. Kolachev, B.A., Pol’kin, I.S., and Talalaev, V.D., Titanovye splavy raznykh stran. Spravochnik (Titanium Alloys of Different Countries, Handbook), Moscow: All-Russian Institute of Light Alloys, 2000.

  3. Khlusov, I.A., Pichugin, V.F., and Ryabtseva, M.A., Osnovy biomekhaniki biosovmestimykh materialov i biologicheskikh tkanei. Uchebnoe posobie (Fundamentals for Biomechanics of Biocompatible Materials and Biological Tissues. Student’s Book), Tomsk: Tomsk Polytechnic Univ., 2007, pp. 95–96.

  4. Rho, J.Y., Tsui, T.Y., and Pharr, G.M., Elastic properties of human cortical and trabecular lamellar bone measured by nanoindentation, Biomaterials, 1997, vol. 18, no. 20, pp. 1325–1330.

    Article  Google Scholar 

  5. Semlitsch, M., Staub, F., and Webber, H., Titanium-aluminum-niobium alloy, development for biocompatible, high strength surgical implants, Biomed. Technol., 1985, vol. 30, no. 12, pp. 334–339.

    Article  Google Scholar 

  6. Rack, H.J. and Qazi, J.I., Titanium alloys for biomedical applications, Mater. Sci. Eng., C, 2006, vol. 26, pp. 1269–1277.

    Article  Google Scholar 

  7. Van der Voet, G.B., Marani, E., Tio, S., and De Wolff, F.A., Aluminum neurotoxicity, Prog. Histochem. Cytochem., 1991, vol. 23, nos. 1–4, pp. 235–242.

    Article  Google Scholar 

  8. Titanovye splavy. Metallovedenie titana i ego splavov (Titanium Alloys. Metal Science of Titanium and its Alloys), Kolachev, B.A. and Glazunov, S.G., Eds., Moscow: Metallurgiya, 1992.

    Google Scholar 

  9. Nnamchi, P.S., First principles studies on structural, elastic and electronic properties of new Ti–Mo–Nb–Zr alloys for biomedical applications, Mater. Des., 2016, vol. 108, pp. 60–67.

    Article  Google Scholar 

  10. Bottino, M.C., Coelho, P.G., Yoshimoto, M., König, B., Henriques, V.A.R., Bressiani, A.H.A., and Bressiani, J.C., Histomorphologic evaluation of Ti–13Nb–13Zr alloys processed via powder metallurgy: A study in rabbits, Mater. Sci. Eng., C, 2008, vol. 28, pp. 223–227.

    Article  Google Scholar 

  11. Chen, Y., Xu, L., Liu, Zn., Kong, F., and Chen, Z., Microstructures and properties of titanium alloys Ti–Mo for dental use, Trans. Nonferrous Met. Soc. China, 2006, vol. 16, pp. 824–828.

    Article  Google Scholar 

  12. Martins, J.R.S., Nogueira, R.A., Oliveira, R., Donato, T.A., Elias, V., Claro, A., Moraes, J., Buzalaf, M., and Grandini, C., Preparation and characterization of Ti–15Mo alloy used as biomaterial, Mater. Res., 2011, vol. 14, no. 1, pp. 107–112.

    Article  Google Scholar 

  13. Konopatsky, A.S., Dubinskiy, S.M., Zhukova, Y.S., Sheremetyev, V., Brailovski, V., Prokoshkin, S.D., and Filonov, M.R., Ternary Ti–Zr–Nb and quaternary Ti–Zr–Nb–Ta shape memory alloys for biomedical applications: Structural features and cyclic mechanical properties, Mater. Sci. Eng., A, 2017, vol. 702, pp. 301–311. https://doi.org/10.1016/j.msea.2017.07.046

    Article  Google Scholar 

  14. Kudryashova, A., Sheremetyev, V., Lukashevich, K., Cheverikin, V., Inaekyan, K., Galkin, S., Prokoshkin, S., and Brailovski, V., Effect of a combined thermomechanical treatment on the microstructure, texture and superelastic properties of Ti–18Zr–14Nb alloy for orthopedic implants, J. Alloys Compd., 2020, vol. 843, p. 156066. https://doi.org/10.1016/j.jallcom.2020.156066

    Article  Google Scholar 

  15. Sheremetyev, V., Kudryashova, A., Cheverikin, V., Korotitskiy, A., Galkin, S., Prokoshkin, S., and Brailovski, V., Hot radial shear rolling and rotary forging of metastable beta Ti–18Zr–14Nb (at %) alloy for bone implants: Microstructure, texture and functional properties, J. Alloys Compd., 2019, vol. 800, pp. 320–326.

    Article  Google Scholar 

  16. Valiev, R.Z. and Aleksandrov, I.V., Ob"emnye nanostrukturnye metallicheskie materialy: Poluchenie, struktura, svoistva (Volumetric Nanostructured Metallic Materials: Preparation, Structure, Properties), Moscow: Akademkniga, 2007.

  17. Valiev, R.Z., Zhilyaev, A.P., and Langdon, T.G., Bulk Nanostructured Materials: Fundamentals and Applications, Hoboken, NJ: John Wiley and Sons, 2014.

    Google Scholar 

  18. Semenova, I.P., Raab, G.I., and Valiev, R.Z., Nanostructured titanium alloys: new developments and application prospects, Nanobiotechnol. Rep., 2014, vol. 9, nos. 5–6, pp. 311–324.

    Google Scholar 

  19. Valiev, R.Z., Semenova, I.P., Latysh, V.V., Rack, H., Lowe, T.C., Petruzelka, J., Dluhos, L., Hrusak, D., and Sochova, J., Nanostructured titanium for biomedical applications, Adv. Eng. Mater., 2008, vol. 10, pp. B15–B17.

    Article  Google Scholar 

  20. Gunderov, D.V., Polyakov, A.V., Semenova, I.P., Raab, G.I., Churakova, A.A., Gimaltdinova, E.I., Sabirov, I., Segurado, J., Sitdikov, V.D., Alexandrov, I.V., Enikeev, N.A., and Valiev, R.Z., Evolution of microstructure, macrotexture and mechanical properties of commercially pure Ti during ECAP-conform processing and drawing, Mater. Sci. Eng., A, 2013, vol. 562, pp. 128–136.

    Article  Google Scholar 

  21. Saitova, L.R., Höppel, H.W., Göken, M., Semenova, I.P., Raab, G.I., and Valiev, R.Z., Fatigue behavior of ultrafine-grained Ti-6Al-4V ‘ELI’ alloy for medical applications, Mater. Sci. Eng., A, 2009, vol. 503, pp. 145–147.

    Article  Google Scholar 

  22. Gatina, S.A., Suleimanov, F.G., and Semenova, I.P., Fatigue fracture features of ultrafine-grained Ti–15Mo alloy produced by severe plastic deformation, Deform. Razrushenie Mater., 2015, no. 5, pp. 28–34.

  23. Sheremetyev, V., Derkach, M., Prokoshkin, S., Churakova, A., Gunderov, D., and Raab, G., Effect of ECAP and annealing on structure and mechanical properties of metastable beta Ti–18Zr–15Nb (at %) alloy, Mater. Lett., 2021, vol. 305, p. 130760.

    Article  Google Scholar 

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ACKNOWLEDGMENTS

We are grateful to the Shared Use Center Nanotekh, USATU (http://nanotech.ugatu.ac.ru).

Funding

This work was supported by the Russian Foundation for Basic Research, project BRIKS_t 19-58-80018 (TEM studies), and the Russian Science Foundation, project no. 20-69-47029 (ECAP, XRS).

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Correspondence to D. V. Gunderov, A. A. Churakova, A. V. Polyakov, A. G. Raab, S. D. Gunderova, Yu. A. Lebedev or Ana Paula Rosifini Alves Claro.

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Gunderov, D.V., Churakova, A.A., Polyakov, A.V. et al. The Influence of Equal Channel Angular Pressing on Structure and Mechanical Properties of New β-Ti Alloy Ti–10Mo–8Nb–6Zr. Russ. J. Non-ferrous Metals 63, 664–670 (2022). https://doi.org/10.3103/S1067821222060086

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