Skip to main content
Log in

Preparation of Zinc Powders by Acid Electrowinning

  • PRODUCTION PROCESSES AND PROPERTIES OF POWDERS
  • Published:
Russian Journal of Non-Ferrous Metals Aims and scope Submit manuscript

Abstract

During the electrowinning of zinc in a mixture electrolyte of zinc sulfate and ammonium sulfate, the effects of current density, Zn2+ mass concentration and electrolytic additives on the morphology and current efficiency of Zn powders were evaluated. Finer Zn powders were obtained at high current density and low Zn2+ mass concentration. However, the current efficiency decreased. Adding a proper amount of sodium dodecyl sulfate generated spherical Zn powders, and adding ethanol produced dendritic ones.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Hou, X.G., Wang, S., and Wang, Y.M., Preparation and characterization of nanometer ZnO powder, Powder Metall. Ind. (in Chin.), 2004, vol. 14, pp. 10–13.

  2. Tang, Y.Q. and Tang, A.Y., Study on preparation of high grade Zinc from Zinc hydrometallurgy system, Hunan Nonferrous Met. (in Chin.), 2014, vol. 30, pp. 34–37.

  3. Zhou, H.J., Wang, S.L., Deng, B., and Chen, X.L., Preparation and characterization of nanoflake zinc particles by vibration milling, Mater. Mech. Eng. (in Chin.), 2005, vol. 29, pp. 62–68.

  4. Chen, W.M., Wan, X.H., and Sun, Y.Y., Study on technology of producing Zinc powders by gas atomization, Mater. Rev., 2000, vol. 14, pp. 59–61.

    Google Scholar 

  5. Wang, A.P., Liu, K., Wang, Y.J., Guo, L., Yang, Y.P., and Liang, T.B., Preparation of super fine Zinc dust by distillation-condensation technology, Nonferrous Met. (in Chin.), 2008, vol. 60, pp. 46–49.

  6. Wang, P., Zhao, F.X., and Zhang, Z.Z., Preparation of ultrafine zinc powders by dc arc plasma evaporation method, Chin. J. Nonferrous Met. (in Chin.), vol. 21, pp. 2236–2241.

  7. Yasumasa, I., Wei, X., Divyaraj, D., Dan, S., and Sanjoy, B., An indicator of zinc morphology transition in flowing alkaline electrolyte, J. Power Sources, 2012, vol. 211, pp. 119–128.

    Article  Google Scholar 

  8. Li, Q., Zhao, Y.C., and Zhang, C.L., Influence of cetyltrimethylammonium bromide and sodium lauryl sulfate on production of zinc powders by alkaline electrowinning, Russ. J. Nonferrous Met., 2014, vol. 55, pp. 65–72.

    Article  Google Scholar 

  9. Hossein Kamran, H., Davood, M., and Mohammad Hadi, S., Production of zinc powder from Co–Zn plant residue using selective alkaline leaching followed by electrowinning, Physicochem. Probl. Mi, 2015, vol. 51, pp. 411–425.

    Google Scholar 

  10. Ostanina, T.N., Rudoy, V.M., Nikitin, V.S., Darintseva, A.B., and Demakov, S.L., Change in the physical characteristics of the dendritic zinc deposits in the stationary and pulsating electrolysis, J. Electroanal. Chem., 2017, vol. 784, pp. 13–24.

    Article  Google Scholar 

  11. Zhu, Y.C. and Qian, Y.T., Solution-phase synthesis of nanomaterials at low temperature, Sci. China Phys. Mech., 2009, vol. 52, pp. 13–20.

    Article  Google Scholar 

  12. Li, L., Liu, J.T., and Ren, Z.J., Crystallization behavior of disproportionately high and low molecular weight PEO blends, Chin. J. Polym. Sci., 2014, vol. 32, pp. 1199–1209.

    Article  Google Scholar 

  13. Wang, H.J., Feng, H.P., Wang, X.C., Du, Q.C., and Yan, C., Crystallization kinetics and morphology of poly(vinylidene fluoride)/poly(ethylene adipate) blends, Chin. J. Polym. Sci., 2015, vol. 33, pp. 349–361.

    Article  Google Scholar 

  14. Xiao, G.Y., Lu, Y.P., Zhu, R.F., Xu, W.H., and Jiao, Y., Fabrication of hydroxyapatite microspheres with poor crystallinity using a novel flame-drying method, T. Nonferrous Metal. Soc., 2012, vol. 22, pp. s169–s171.

    Article  Google Scholar 

  15. Gu, W.M., Liu, C.Q., Tang, J., Liu, R.Y., Yang, H., and Hu, J.G., Improving zinc electrodeposition in ammoniacal electrolytes with the saturated dissolved methyltrioctylammonium chloride, Hydrometallurgy, 2018, vol. 175, pp. 43–51.

    Article  Google Scholar 

  16. Yuan, L., Ding, Z.Y., Liu, S.J., Shu, W.F., and He, Y.N., Effects of additives on zinc electrodeposition from alkaline zincate solution, T. Nonferrous Metal Soc., 2017, vol. 27, pp. 1656–1664.

    Article  Google Scholar 

Download references

ACKNOWLEDGMENTS

This study was supported by the National Natural Science Foundation of China (51304082).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rong Liang Zhang.

Additional information

The article is published in the original.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Rong Liang Zhang, Huang, A.D., Guo, H. et al. Preparation of Zinc Powders by Acid Electrowinning. Russ. J. Non-ferrous Metals 60, 173–178 (2019). https://doi.org/10.3103/S1067821219020160

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1067821219020160

Keywords:

Navigation