Abstract
The possibility of developing a luminescence technique for phase composition analysis is demonstrated via the example of bi-phase yttria nanopowders doped with neodymium ions. The deviation from X-ray diffraction reference values is ±2%. It is found that the results depend on the inhomogeneity of the crystalline phase distribution within a sample’s bulk, rather than on the luminescence scattering by powder nanoparticles. A luminescence coefficient that determines the phase inhomogeneity in nanopowders is introduced.
Similar content being viewed by others
References
Ikesue, A. and Aung, Y.L., Nat. Photonics, 2008, vol. 2, p. 721.
Kong, L.B., Huang, Y.Z., Que, W.X., Zhang, T.S., and Li, S., Transparent Ceramics, Springer, 2015.
Wisdom, J., Digonnet, M., and Byer, R.L., Photonics Spectra, 2004, vol. 38, p. 50.
Zhang, L. and Pan, W., J. Am. Ceram. Soc., 2015, vol. 98, no. 10, p. 3326.
Osipov, V.V., Platonov, V.V., Lisenkov, V.V., Podkin, A.V., and Zakharova, E.E., Phys. Status Solidi C, 2013, vol. 10, no. 6, p. 926.
Osipov, V.V., Solomonov, V.I., Shitov, V.V., et al., Ogneupory Tekh. Keram., 2010, nos. 1–2, p. 56.
Osipov, V.V., Solomonov, V.I., and Spirina, A.V., J. Opt. Technol., 2011, vol. 78, no. 6, p. 408.
Kaminskii, A.A., Lazernye kristally (Laser Crystals), Moscow: Nauka, 1975.
Osipov, V.V., Solomonov, V.I., Spirina, A.V., Shitov, V.A., Toropova, P.V., and Orlov, A.N., Opt. Spectrosc., 2015, vol. 118, no. 5, p. 723.
Bakunov, V.S., Belyakov, A.V., Lukin, E.S., and Shayakhmetov, U.Sh., Oksidnaya keramika: Spekanie i polzuchest’ (Oxide Ceramics: Sintering and Creep), Moscow: Ross. Khim.-Tekhnol. Univ., 2007.
Osipov, V.V., Platonov, V.V., and Lisenkov, V.V., Handbook of Nanoparticles, Springer, 2015.
Frish, S.E., Opticheskie spektry atomov (Optical Atomic Spectra), Moscow: Gos. Izd. Fiz.-Mat. Lit., 1963.
Makarov, Yu.I., Apparaty dlya smeshivaniya sypuchikh materialov (Granular Material Mixing Machines), Moscow: Mashinostroenie, 1973.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.V. Osipov, V.I. Solomonov, A.V. Spirina, P.V. Toropova, V.A. Shitov, A.V. Chukin, S.O. Cholakh, 2017, published in Izvestiya Rossiiskoi Akademii Nauk, Seriya Fizicheskaya, 2017, Vol. 81, No. 9, pp. 1227–1231.
About this article
Cite this article
Osipov, V.V., Solomonov, V.I., Spirina, A.V. et al. Determining the phase composition of yttrium oxide nanopowders by means of luminescence. Bull. Russ. Acad. Sci. Phys. 81, 1105–1109 (2017). https://doi.org/10.3103/S1062873817090179
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1062873817090179