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Structure and the electrical and magnetic properties of perovskite-like Gd x Cu3V4O12 oxide

  • Proceedings of the International Interdisciplinary Simposium “Ordering in Minerals and Alloys” OMA-14
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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

A new perovskite-like compound Gd x Cu3V4O12 (x = 0.67−0.73) is synthesized under high pressures (P = 4−9 GPa) and at high temperatures (T = 1000°C). Its structure (space group Im3, Z = 2, a = 7.2930(5) Å) is estrablished by X-ray analysis. The bond lengths and bond angles are determined. The temperature dependences of electrical resistivity (10–300 K) and magnetic susceptibility are studied. The high-pressure Gd x Cu3V4O12 phase is found to have a semi-conductor type of conductivity and paramagnetic properties.

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References

  1. Vasil’ev, A.N. and Volkova, O.S., Fiz. Nizk. Temp., 2007, vol. 33, no. 11, p. 1181.

    Google Scholar 

  2. Xiang, H. and Wu, Z., Inorg. Chem., 2008, vol. 47, no. 7, p. 2706.

    Article  Google Scholar 

  3. Shimakava, Y., Inorg. Chem., 2008, vol. 47, no. 19, p. 8562.

    Article  Google Scholar 

  4. Subramanian, M.A., Li, D., Duan, N., Reisner, B.A., and Sleight, A.W., J. Solid State Chem., 2000, vol. 151, p. 323.

    Article  ADS  Google Scholar 

  5. Volkov, V.L., Kadyrova, N.I., Zakharova, G.S., et al., Russ. J. Inorg. Chem., 2007, vol. 52, p. 329.

    Article  Google Scholar 

  6. Zeng, Z., Greenblatt, M., Subramanian M.A., and Croft, M., Phys. Rev. Lett., 1999, vol. 82, p. 3164.

    Article  ADS  Google Scholar 

  7. Yamatada, I., Takata, K., Hayashi, N., et al., Angew. Chem., Int. Ed., 2008, vol. 47, p. 7032.

    Article  Google Scholar 

  8. Mizokawa, T., Morita, Y., Sudayama, T., et al., Phys. Rev. B, 2009, vol. 80, p. 125105.

    Article  ADS  Google Scholar 

  9. Shannon, R.D., Acta Crystallogr. A, 1976, vol. 32, pp. 751–767.

    Article  ADS  Google Scholar 

Download references

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Correspondence to N. I. Kadyrova.

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Original Russian Text © N.I. Kadyrova, Yu.G. Zainulin, A.P. Tyutyunnik, N.V. Mel’nikova, I.S. Ustinova, A.V. Korolev, 2012, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2012, Vol. 76, No. 7, pp. 832–834.

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Kadyrova, N.I., Zainulin, Y.G., Tyutyunnik, A.P. et al. Structure and the electrical and magnetic properties of perovskite-like Gd x Cu3V4O12 oxide. Bull. Russ. Acad. Sci. Phys. 76, 744–746 (2012). https://doi.org/10.3103/S1062873812070167

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  • DOI: https://doi.org/10.3103/S1062873812070167

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