Skip to main content
Log in

Abstract

Measurements of electrical resistivity are the most available, sensitive, and informative tools for exploration of the state of the contact surface between individual particles in powder materials. Application of these methods to SHS science and technology enables one to study the oxidation of the particles’ surface, to optimize the processes of intermixing, mechanical activation, sintering, and also to shed light on other physical, chemical, and mechanical transformations taking place in powder materials. The available data of resistivity measurements have been analyzed and found to agree quite well with the chemical composition, burning velocities, mechanical properties, and surface relief characteristics of the materials under consideration.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Bloshenko, V.N., Bokii, V.A., and Borovinskaya, I.P., Dissolution of Metal Oxide Film during Synthesis of Titanium Carbide, Fiz. Goreniya Vzryva, 1984, vol. 20, no. 6, pp. 87–90.

    CAS  Google Scholar 

  2. Mokrushin, V.V., The Theory of Generalized Conductivity of Heterogeneous Systems and Resistometric Study on Oxidation of Metal Powders in a Porous State, Proc. All-Russia Conference on Combustion and Explosion, 2002, Chernogolovka, Moscow, pp. 268–274.

    Google Scholar 

  3. Mokrushin, V.V., Berezhko, P.G., Yaroshenko, V.V., Golubev, V.A., and Balandin, V.A., USSR Inventor’s Certificate 1 598 600, Byull. Izobret., 1999, no. 23.

  4. Mokrushin, V.V., Golubev, V.A., Yaroshenko, V.V., and Balandin, V.A., USSR Inventor’s Certificate 1 540 482, Byull. Izobret., 1999, no. 23.

  5. Kochetov, N.A., Rogachev, A.S., Emel’yanov, A.N., Illarionova, E.V., and Shkiro, V.M., The Microstructure of Heterogeneous Mixtures for Gasless Combustion, Fiz. Goreniya Vzryva, 2004, vol. 40, no. 5, pp. 74–80.

    CAS  Google Scholar 

  6. Emel’yanov, A.N., Shkiro, V.M., Rogachev, A.S., and Rubtsov, V.I., Electrical Resistance and Heat Conductivity of Ti-Based Powder Mixtures for Self-Propagating High-Temperature Synthesis of Materials, Izv. Vyssh. Uchebn. Zaved., Tsvet. Metal., 2002, no. 2, pp. 67–70.

  7. Mokrushin, V.V., Generalized Conductivity of Loaded Powder Materials, Dokl. Akad. Nauk, 1997, vol. 357, no. 3, pp. 332–334.

    CAS  Google Scholar 

  8. Mokrushin, V.V. and Berezhko, P.G., Generalized Conductivity of Heterogeneous Powder Systems and Percolation Theory, Dokl. Akad. Nauk, 1999, vol. 368, no. 4, pp. 470–473.

    CAS  Google Scholar 

  9. Frolov, Yu.V. and Pivkina, A.N., Fractal Structure and Features of Combustion in Heterogeneous Condensed Systems, Fiz. Goreniya Vzryva, 1997, vol. 33, no. 5, pp. 3–19.

    CAS  Google Scholar 

  10. Odelevskii, V.I., Generalized Conductivity of Heterogeneous Systems: Calculation Study, Zh. Tekh. Fiz., 1951, vol. 21, no. 6, pp. 667–677.

    Google Scholar 

  11. Bal’shin, M.Yu. and Kiparisov, S.S., Osnovy poroshkovoi metallurgii, Moscow: Metallurgiya, 1978, pp. 47–53. Translated under the title General Principles of Powder Metallurgy, Moscow: Mir Publishers, 1980.

    Google Scholar 

  12. Shkovskii, B.I. and Efros, A.L., Elektronnye svoistva legirovannykh poluprovodnikov, Moscow: Nauka, 1979, pp. 214–231. Translated under the title Electronic Properties of Doped Semiconductors, Berlin-New York: Springer-Verlag, 1984.

    Google Scholar 

  13. Sokolov, I.M., Dimensions and Other Geometrical Critical Parameters in the Percolation Theory, Usp. Fiz. Nauk., 1986, vol. 150, no. 2, pp. 233–237.

    Google Scholar 

  14. Solonin, S.M. and Chernyshev, L.I., Percolation Approach to Analysis of Conductivity as a Function of Porosity, Poroshk. Metall. (Kiev), 2006, nos. 5–6, pp. 16–21.

  15. Mokrushin, V.V., Model of Generalized Conductivity of Heterogeneous Systems, in Fizika Goreniya i Vzryva (Collection of Works), Sarov: Izd. RFNC-VNIIEF, 1999, pp. 193–199.

    Google Scholar 

  16. Mokrushin, V.V., Theory of Generalized Conductivity of Heterogeneous Systems and Resistometric Study on Oxidation of Metal Powders in a Porous State, Tr. RFNC-VNIIEF (Sarov), 2004, vol. 6, pp. 216–229.

    CAS  Google Scholar 

  17. Kennedy, A.R., Lopez, V.H., Asavavisithchai, S., The Effect of TiH2 Oxidation on Gas Release and Foaming in Compacted Al-TiH2 Powder Precursors, Proc. Int. Conf. on Cellar Metals and Metal Foaming Technology, Berlin, 2003, pp. 95–100.

  18. White, K., Reed, J.W., Love, C.M., Glaub, J.E., and Holy, J.A., Electrical Resistivity of TiHx and TiHx/KClO4, Mound Facility Report, MLM-2589, Energy Res. Abstr., 1979, vol. 4, no. 12, p. 34 739.

    Google Scholar 

  19. Kofstad, P., High-Temperature Oxidation of Metals, New York: Wiley, 1966, p. 264.

    Google Scholar 

  20. Fenelonov, V.B., Vvedenie v fizicheskuyu khimiyu formirovaniya supramolekulyarnoi struktury adsorbentov i katalizatorov (Introduction to Physical Chemistry of Supramolecular Structuring of Adsorbents and Catalysts), Novosibirsk: Izd. Siberian Branch RAS, 2004, pp. 170–188.

    Google Scholar 

  21. Artemova, L.N., Vlasova, M.P., Golubev, A.V., Kreknin, D.A., and Selezenev, A.A., Effect of Vacuum Annealing Temperature on Reaction of Titanium with Hydrogen, Izv. Akad. Nauk SSSR, Met., 1989, no. 5, pp. 200, 201.

  22. Evard, E.A., Gabis, I.E., Voit, A.P., Korzukhin, S.V., Yukhimchuk, A.A., and Golubkov, A.N., Adsorption and Desorption of Hydrogen by Titanium Sponge as Studied by Thermocyclization Method, Proc. 2nd Int. Seminar on Interaction of Hydrogen Isotopes with Constructional Materials (IHISM-04), Sarov, 2004, pp. 288–295.

  23. Poristye pronitsaemye materialy (Porous Permeable Materials), Belov, S.V., Ed., Moscow: Metallurgiya, 1987, p. 77.

    Google Scholar 

  24. Tsarev, M.V. and Mokrushin, V.V., Effect of Granulometric Parameters of Scandium Powders on their Electrical Conductivity, Zh. Tekh. Fiz., 2007, vol. 77, no. 3, pp. 80–86.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

The text was submitted by the authors in English.

About this article

Cite this article

Mokrushin, V.V., Tsarev, M.V. Resistivity measurements for characterization of SHS powders. Int. J Self-Propag. High-Temp. Synth. 16, 96–104 (2007). https://doi.org/10.3103/S1061386207020070

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1061386207020070

Keywords

PACS numbers

Navigation