Abstract
The accumulation of hydrogen peroxide in a plasma-solution system with an electrolyte cathode under glow discharge action in relation to the cathode material has been studied, as well as the kinetics of the accumulation of Cu2+, Ni2+, and Ag+ ions passing from the cathode into the solution at the discharge combustion. It is shown that the Cu2+ concentration is comparable with that of the H2O2, and the use of a silver cathode results in a considerable decrease of the initial formation rate and the highest concentration of hydrogen peroxide in the plasma-solution system under study.
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Maksimov, A.I., Physical and chemical properties of plasma-solution systems and possible technological application, in Entsiklopediya nizkotemperaturnoi plazmy (Encyclopedia of Low-Temperature Plasma), vol. XI-5: Applied Plasma Chemistry, Lebedev, Yu.A, Plate, N.A, and Fortova, V.E, Eds., Moscow: Yanus-K, 2006, pp. 263–309.
Zakharov, A.G., Maksimov, A.I, and Titova, Yu.V., Physical and chemical properties of plasma-solution systems and possible technological applications, Usp. Khim., 2007, vol. 76, no. 3, p. 260.
Kuz’micheva, L.A., Titova, Yu.V., Maksimov, A.I., and Kulentsan, A.L., Effect of additives to electrolyte solutions on hydrogen peroxide yield in a plasma-solution system, Khim. Khim. Tekh., 2008, vol. 51, no. 5, pp. 40–43.
Maximov, A.I., Physics, chemistry and applications of the AD diaphragm discharge and related discharge in electrolyte solutions, Contr. Plasma Phys., 2007, vol. 46, nos. 1–2, pp. 111–118.
Bruggeman, P. and Leys, C., Non-thermal plasmas in and in contact with liquids, J. Phys. D: Appl. Phys., 2009, vol. 42, no.5, pp.
Maksimov, A.I., Titova, Yu.V., and Kuz’micheva, L.A., Kinetic model of oxidation reactions initiated in electrolyte solutions by a glow discharge, Goren. Plazmokhim., 2005, vol. 3, p. 247–249.
Kuz’micheva, L.A., Maksimov, A.I., and Titova, Yu.V., Formation of oxygen peroxide under the action of atmosphere pressure glow discharge on aqueous solutions of electrolytes, Elektron. Obrab. Mater., 2004, vol. 40, no. 4, pp. 57–61.
Kuzmicheva, L.A., Titova, Yu.V., and Maximov, A.I., Influence of different factors on the H2O2 yields in the system of atmospheric pressure grow discharge with electrolyte cathode, Proc. VI Int. Symp. on Theoretical and Applied Plasma Chemistry, Ivanovo, 2011, p. 83.
Locke, B.R., and Shin Kai-Yuan. Review of the methods to form hydrogen peroxide and electrical discharge plasma with liquid water, Plasma Sources Sci. Tech., 2011, vol. 20, no. 3, pp.
Schumb, U., Satterfield, Ch., and Wentworth, R., Perekis’ vodoroda (Hydrogen Peroxide), Moscow: Izdvo inostrannoi literatury, 1958.
Biesaga, M., Pyrzynska, K., and Trojanowicz, M., Porphyrins in analytical chemistry, Talanta, 2000, vol. 51, pp. 209–224.
Kuz’micheva, L.A., Titova, Yu.V., and Maksimov, A.I., Change of solution acidity under the action of glow discharge in the case of initiation of reactions influencing the pH value, Elektron. Obrab. Mater., 2004, vol. 40, no. 5, pp. 37–40.
Skug, D. and West, D., Osnovy analiticheskoi khimii, (Principles of Analytical Chemistry), vol. 1, Moscow: Mir, 1979.
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Original Russian Text © L.A. Kuz’micheva, Yu.V. Titova, A.I. Maksimov, A.S. Vashurin, S.G. Pukhovskaya, 2013, published in Elektronnaya Obrabotka Materialov, 2013, No. 6, pp. 41–44.
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Kuz’micheva, L.A., Titova, Y.V., Maksimov, A.I. et al. Effect of the cathode material on the accumulation of hydrogen peroxide in a plasma-solution system. Surf. Engin. Appl.Electrochem. 49, 485–487 (2013). https://doi.org/10.3103/S1068375513060100
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DOI: https://doi.org/10.3103/S1068375513060100