Abstract
The influence of chemical modification on the functional–group composition of humic acids derived from Tisul’sk lignite (Kansko-Achinsk Basin) is studied. The structural changes of the humic acids as a result of destructive alkylation of n-butanol and oxidation of hydrogen peroxide are compared, by means of IR, Raman, ESR, and NMR spectroscopy. Alkylation of the humic acids changes the composition and content of the aliphatic fragments in their structure. Oxidation by hydrogen peroxide increases the content of acid-bearing groups.
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REFERENCES
Lyubchenko, V.I., Dumbai, I.N., Gubanova, E.N., et al., Granulated sorption materials based on lignite humates, Khim. Tverd. Topl. (Moscow), 1999, no. 2, pp. 38–46.
Zherebtsov, S.I., Non-fuel use of Itatsk lignite, Trudy nauchno-tekhnicheskoi konferentsii “Opyt i perspektivy naukoemkikh tekhnologii v ugol’noi promyshlennosti Kuzbassa” (Proc. Sci.-Tech. Conf. “Prospective Use of High Technologies in Coal Industry of Kuzbass”), Kemerovo, 1998, pp. 258–262.
Malyshenko, N.V., Zherebtsov, S.I., Smotrina, O.V., et al., Sorption of zinc cations by modified humic acids, Chem. Sustainable Dev., 2015, vol. 23, no. 4, pp. 451–457.
Zherebtsov, S.I., Malyshenko, N.V., Smotrina, O.V., et al., Sorption of copper cations by native and modified humic acids, Chem. Sustainable Dev., 2016, vol. 24, no. 3, pp. 399–403.
Naumova, G.V., Strigutsky, V.P., Zhmakova, N.A., and Ovchinnikova, T.F., The relation between the molecular structure of humic acids and their biological activity, Solid Fuel Chem., 2001, vol. 35, no. 2, pp. 1–10.
Zherebtsov, S.I., Malyshenko, N.V., Smotrina, O.V., et al., Structural group composition of humic acids in brown coal and their physiological activity, Chem. Sustainable Dev., 2015, vol. 23, no. 4, pp. 439–444.
Zherebtsov, S.I. and Ismagilov, Z.R., Effect of the alkylation of brown coal and peat on the composition and properties of humic acids isolated from them, Solid Fuel Chem., 2012, vol. 46, no. 6, pp. 339–351.
Taits, E.M. and Andreeva, I.A., Metody analiza i ispytaniya uglei (Methods of Analysis and Tests of Coals), Moscow: Nedra, 1983.
Zherebtsov, S.I., Lozbin, V.I., Polubentsova, M.F., Interaction of brown coal of the Aleksandriya coalfield with methanol, Solid Fuel Chem., 2003, vol. 37, no. 2, pp. 1–6.
Shaks, I.A. and Faizullina, E.M., Infrakrasnye spektry iskopaemogo organicheskogo veshchestva (Infrared Spectra of Fossil Organic Matter), Moscow: Nedra, 1974.
Filippov, M.M., Analysis of deeply carbonated organic matter by Raman spectroscopy, Part 1. The general use, Tr. Karel. Nauchn. Tsentra, Ross. Akad. Nauk, 2014, no. 6, p. 115.
Zherebtsov, S.I., Malyshenko, N.V., and Ismagilov, Z.R., Mechanism of the alcohol-mediated alkylation of solid fossil fuels at the low stage of coalification, Chem. Sustainable Dev., 2015, vol. 23, no. 1, pp. 139–145.
Jezierski, A., Czechowski, F., Jerzykiewicz, M., et al., Electron paramagnetic resonance (EPR) studies on stable and transient radicals in humic acids from compost, soil, peat and brown coal, Spectrochim. Acta, Part A, 2000, vol. 56, pp. 379–385.
Ishiwatari, R., Electron spin resonance of sedimentary humic acids in relation to their aromatic character, Geochem. J., 1974, vol. 8, pp. 97–102.
Nonhebel, D.C. and Walton, J.C., Free-Radical Chemistry: Structure and Mechanism, Cambridge: Cambridge Univ. Press, 1974.
Breitmaier, E. and Voelter, W., Carbon-13 NMR Spectroscopy: High-Resolution Methods and Applications in Organic Chemistry and Biochemistry, New York: VCH, 1990, 3rd ed.
ACKNOWLEDGMENTS
Financial support for this research was provided under a grant of the Russian government to the Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences (project AAAA-A17-117041910148-9, under the direction of S. I. Zherebtsiov).
The research was conducted on equipment provided by the Cooperative-Use Center at the Federal Research Center of Coal and Coal Chemistry, Siberian Branch, Russian Academy of Sciences.
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Zherebtsov, S.I., Malyshenko, N.V., Bryukhovetskaya, L.V. et al. Influence of Chemical Modification on the Structure, Composition, and Properties of Lignite Humic Acids. Coke Chem. 61, 396–400 (2018). https://doi.org/10.3103/S1068364X18100083
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DOI: https://doi.org/10.3103/S1068364X18100083