Abstract
A new and sensitive preconcentration procedure was developed for the determination of trace amount of Mn(II) in environmental water samples. Amberlite XAD-4 resin was functionalized with N,N-bis(salicylidene)cyclohexanediamine (SCHD) to preconcentrate and separate Mn(II) at the trace level concentrations. Mn(II) ion in environmental water samples was determined by the formaldoxime spectrophotometric method. The influences of analytical parameters including pH and volume of sample, type and concentration of elution solution, flow rate of sample and elution solution, etc. were investigated on the recoveries of Mn(II) ion. The adsorption was achieved quantitatively for Mn(II) on XAD-4-SCHD resin at the pH range of 3–10 and 3 mL min–1 sample flow rate. Elution was performed with 0.5 mol L–1 nitric acid solution. Under the optimized conditions, calibration curve was found to be linear in the concentration range of 0.1–5 mg L–1 with a limit of detection of 0.65 μg L–1. The effect of foreign ions on the perconcentration and determination of Mn(II) was studied and no adversely affecting ion was observed even at high ionic media. The recovery value was above 90%, with an enrichment factor of 100. The per cent relative standard deviation (%) value was found to be 1.8 for twenty repetitive measurements containing 1 mg L–1 of Mn(II). Sorption capacity of the Mn(II) ion on the XAD-4-SCHD resin was found to be 29.217 μg. The accuracy of the presented preconcentration and determination method was checked by the analysis of TMDA-70.2 Ontario lake Water certified reference material and synthetic water sample. The method was applied for the analyses of tap water and industrial wastewater samples for Mn(II). Almost the similar results were observed for the Mn(II) determination in different environmental water samples using both the proposed and ICP-MS methods.
Similar content being viewed by others
REFERENCES
Ruzik, L., Speciation of challenging elements in food by atomic spectrometry, Talanta, 2012, vol. 93, pp. 18–31.
Levy, B.S. and Nassetta, W.J., Neurologic effects of manganese in humans: a review, Int. J. Occup. Environ. Health, 2003, vol. 9, pp. 153–163.
Tuzen, M., Determination of heavy metals in fish samples of the middle Black Sea (Turkey) by graphite furnace atomic absorption spectrometry, Food Chem., 2003, vol. 80, pp. 119–123.
Saterlay, A.J., Agra-Gutierrez, C., Taylor, M.P., Marken, F., and Compton, R.G., Sono-cathodic stripping voltammetry of lead at polished boron-doped diamond electrode: application to the determination of lead in river sediment, Electroanalysis, 1999, vol. 11, pp. 1083–1088.
Karadede, H. and Unlü, E., Concentrations of some heavy metals in water, sediment and fish species from the Atatürk Dam Lake (Euphrates), Turkey, Chemosphere, 2000, vol. 41, pp. 1371–1376.
Forrer, R., Gautschi, K., and Lutz, H., Simultaneous measurement of the trace elements Al, As, B, Be, Cd, Co, Cu, Fe, Li, Mn, Mo, Ni, Rb, Se, Sr, and Zn in human serum and their reference ranges by ICP-MS, Biol. Trace Elem. Res., 2001, vol. 80, pp. 77–93.
Evertz, M., Lürenbaum, C., Vortmann, B., Winter, M., and Nowak, S., Development of a method for direct elemental analysis of lithium ion battery degradation products by means of total reflection X-ray fluorescence, Spectrochim. Acta, B, 2015, vol. 112, pp. 34–39.
Citak, D., Tuzen, M., and Soylak, M., Speciation of Mn(II), Mn(VII) and total manganese in water and food samples by coprecipitation-atomic absorption spectrometry combination, J. Hazard. Mater., 2010, vol. 173. pp.773–777.
Ranjbar, L., Yamini, Y., Saleh, A., Seidi, S., and Faraji, M., Ionic liquid based dispersive liquid-liquid microextraction combined with ICP-OES for the determination of trace quantities of cobalt, copper, manganese, nickel and zinc in environmental water samples, Microchim. Acta, 2012, vol. 177, pp. 119–127.
Liang, P., Sang, H., and Sun, Z., Cloud point extraction and graphite furnace atomic absorption spectrometry determination of manganese(II) and iron(III) in water samples, J. Colloid Interface Sci., 2006, vol. 304, pp. 486–490.
Abou-El-Sherbini, K.S., Kenawy, I.M.M., Hamed, M.A., Issa, R.M., and Elmorsi, R., Separation and preconcentration in a batch mode of Cd(II), Cr(III, VI), Cu(II), Mn(II, VII) and Pb(II) by solid-phase extraction by using of silica modified with N-propylsalicylaldimine, Talanta, 2002, vol. 58, pp. 289–300.
Gundogdu, A., Duran, C., Senturk, H.B., Elci, L., and Soylak, M., Simultaneous preconcentration of trace metals in environmental samples using Amberlite XAD-2010/8-Hydroxyquinoline system, Acta Chim. Slov., 2007, vol. 54, no. 2, pp. 308–316.
Cui, C., He, M., and Hu, B., Membrane solid phase microextraction with alumina hollow fiber on line coupled with ICP-OES for the determination of trace copper, manganese and nickel in environmental water samples, J. Hazard. Mater., 2011, vol. 187, pp. 379–385.
Ozcan, S.G., Satiroglu, N., and Soylak, M., Column solid phase extraction of iron(III), copper(II), manganese(II) and lead(II) ions food and water samples on multi-walled carbon nanotubes, Food Chem. Toxicol., 2010, vol. 48, pp. 2401–2406.
Soylak, M. and Tuzen, M., Diaion SP-850 resin as a new solid phase extractor for preconcentration-separation of trace metal ions in environmental samples, J. Hazard. Mater., 2006, vol. 137, pp. 1496–1501.
Su, X., Wang, M., Zhang, Y., Zhang, J., Zhang, H., and Jin, Q., Semi-online preconcentration of Cd, Mn and Pb on activated carbon for GFASS, Talanta, 2003. 59, pp. 989–997.
Kendüzler, E., Türker, A.R., and Yalçinkaya, Ö., Separation and preconcentration of trace manganese from various samples with Amberlyst 36 column and determination by flame atomic absorption spectrometry, Talanta, 2006, vol. 69, pp. 835–840.
Afzali, D., Mostafavi, A., Etemadi, F., and Ghazizadeh, A., Application of modified multiwalled carbon nanotubes as solid sorbent for separation and preconcentration of trace amounts of manganese ions, Arab. J. Chem., 2012, vol. 5, pp. 187–191.
Ghaedi, M., Niknam, K., Taheri, K., Hossainian, H., and Soylak, M., Flame atomic absorption spectrometric determination of copper, zinc and manganese after solid-phase extraction using 2,6-dichlorophenyl-3,3-bis(indolyl)methane loaded on Amberlite XAD-16, Food Chem. Toxicol., 2010, vol. 48, pp. 891–897.
Tony, K., Kartikeyan, S., Vijayalakshmy, B., Rao, T.P., and Padmanabha Iyer, C.S., Flow injection on-line preconcentration and flame atomic absorption spectrometric determination of iron, cobalt, nickel, manganese and zinc in sea-water, Analyst, 1999, vol. 124, pp. 191–195.
Afzali, D., Taher, M.A., Mostafavi, A., and Mobarakeh, S.Z.M., Thermal modified Kaolinite as useful material for separation and preconcentration of trace amounts of manganese ions, Talanta, 2005, vol. 65, pp. 476–480.
Doutan, M., Filik, H., and Apak, R., Preconcentration of manganese(II) from natural and sea water on a palmitoyl quinolin-8-ol functionalized XAD copolymer resin and spectrophotometric determination with the formaldoxime reagenti, Anal. Chim. Acta, 2003, vol. 485, pp. 205–212.
Huseyinli, A.A., Alieva, R., Haciyeva, S., and Güray, T., Spectrophotometric determination of aluminium and indium with 2,2',3,4-tetrahydroxy-3',5'-disulphoazobenzene, J. Hazard. Mater., 2009, vol. 163, pp. 1001–1007.
Barakat, S.A., Determination of manganese in steel after extraction of dimethyldistearylammonium permanganate, J. Hazard. Mater., 1999, vol. 393, pp. 223–226.
Winkler, W., Buhl, F., Arenhövel-Pacuła, A., and Hachuła, U., Spectrophotometric method for the determination of manganese with phenylfluorone in the presence of Triton X-100 and cetylpyridinium chloride in pharmacological preparations and vegetable fertilizers, Anal. Bioanal. Chem., 2003, vol. 376, pp. 934–937.
Gandhi, M.N. and Khopkar, S.M., A rapid method for the extractive separation of trace level manganese(II) from an aquatic environment, Anal. Sci., 1992, vol. 8, pp. 233–236.
Argekar, A.P. and Shetty, A.K., Extraction of manganese(II) with bis(2, 4, 4-trimethylpentyl)monothiophosphinic acid and its spectrophotometric determination with formaldoxime, Anal. Sci., 1997, vol. 13, pp. 131–135.
Topuz, B. and Macit, M., Solid phase extraction and preconcentration of Cu(II), Pb(II), and Ni(II) in environmental samples on chemically modified Amberlite XAD-4 with a proper Schiff base, Environ. Monit. Assess., 2011, vol. 173, nos. 1–4, pp. 709–722.
Author information
Authors and Affiliations
Corresponding author
About this article
Cite this article
Berrin Topuz, Sennur Merve Yakut Preconcentration and Separation of Mn(II) from Eenvironmental Water Samples on N,N-bis (Salicylidene) Cyclohexanediamine Functionalized Amberlite XAD-4 Resin and Its Spectrophotometric Assessment. J. Water Chem. Technol. 42, 45–53 (2020). https://doi.org/10.3103/S1063455X20010099
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.3103/S1063455X20010099