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Electric conduction of ceramic membranes modified with nanoparticles of an inorganic ion exchanger

  • Physical Chemistry of Water Treatment Processes
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Abstract

The article has investigated electric conduction of systems including composite ceramic membranes whose macropores are filled with an ion-exchange component—hydrated with zirconium dioxide and the solution of 1,1-charged electrolyte HCl. It was found that experimental values of electric conduction of membranes are the values of the same order as the electric conduction of an equilibrium solution. Based on potentiometric transport numbers of counterions we computed electric conduction of the ion-exchanger-solution system with the account of not only electrolyte, which is in intraporous solution, but also of counterions localized in the phase of the ion-exchanger. We have proposed a model equation linking electrical conduction of the membrane, the ion-exchanger, and the solution. An assumption was made about the presence in the pores of nano-dimensional channels being formed when introducing the ion-exchanger to the matrix.

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References

  1. Michaeli, L. and Kedem, O., Trans. Faraday Soc., 1961, vol. 57, no. 10, pp. 1185–1190.

    Article  CAS  Google Scholar 

  2. Kedem, O. and Katchalsky, A., ibid., 1964, vol. 59, no. 8, pp. 1918–1930.

    Google Scholar 

  3. Zabolotskii, V.I. and Nikonenko, V.V., Perenos ionov v membranakh (Transport of Ions in Membranes), Moscow: Nauka, 1996.

    Google Scholar 

  4. Strathmann, H., Ion-Exchange Membrane Separation Processes, New York, Wiley, 2004.

    Google Scholar 

  5. Tanaka, Yo., Ion-Exchange Membranes. Fundamentals and Applications, Amsterdam: Elsevier, 2007.

    Google Scholar 

  6. Gnusin, N.P., Berezina, N.P., Kononenko, N.A. and Dyomina, O.A., J. Membr. Sci., 2004, vol. 243, no. 1, pp. 301–310.

    Article  CAS  Google Scholar 

  7. Berezina, N.P., Kononenko, N.A., Dyomina, O.A., and Gnusin, N.P., Adv. Colloid. Interface Sci., 2008, vol. 139, nos. 1/2, pp. 3–28.

    Article  CAS  Google Scholar 

  8. Linkov, V.M., Dzyaz’ko, Yu.S., Belyakov, V.N., and Atamanyuk, V.Yu., Zhurn. Prikl. Khim., 2007, vol. 80, no. 4, pp. 590–595.

    Google Scholar 

  9. Dzyazko, Yu.S., Mahmoud, A., Lapicque, F., and Belyakov, V.N., J. Appl. Electrochem., 2007, vol. 37, no. 3, pp. 209–217.

    Article  CAS  Google Scholar 

  10. Dzyaz’ko, Yu.S., Belyakov, V.N., Stefanyak, N.V., and Vasilyuk, S.L., Ukr. Khim. Zhurn., 2006, vol. 72, no. 6, pp. 26–31.

    Google Scholar 

  11. Sukhotin, A.M., Spravochnik po elektrokhimii (Reference Book on Electrochemistry), Leningrad, Khimiya, 1981.

    Google Scholar 

  12. Dzyaz’ko, Yu.S., Rozhdestvenskaya, L.M., Vasilyuk, S.L., Khimiya i Tekhnologiya Vody, 2008, vol. 31, no. 5, pp. 498–508.

    Google Scholar 

  13. Dzyaz’ko, Yu.S., Ukr. Khim. Zhurn.,2008, vol. 74, no. 8, pp. 82–85.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Dumanskii Institute of Colloid and Water Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    Yu. S. Dzyaz’ko & S. L. Vasilyuk

Authors
  1. Yu. S. Dzyaz’ko
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  2. S. L. Vasilyuk
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Original Russian Text © Yu.S. Dzyaz’ko, S.L. Vasilyuk, 2009, published in Khimiya i Tekhnologiya Vody, 2009, Vol. 31, No. 6, pp. 653–664.

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Dzyaz’ko, Y.S., Vasilyuk, S.L. Electric conduction of ceramic membranes modified with nanoparticles of an inorganic ion exchanger. J. Water Chem. Technol. 31, 373–380 (2009). https://doi.org/10.3103/S1063455X09060058

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  • DOI: https://doi.org/10.3103/S1063455X09060058

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