Assessment of bauxite residue stabilized with lime and graphene oxide as a geomaterial for road applications

Abstract Negative traits of bauxite residue (BR) include low shear strength, inconsistent compaction characteristics and dispersion, render it unsuited geomaterial for engineering applications. The present study aims at stabilizing BR with the combination of lime (L) and graphene oxide (GO) in suitable proportions and investigating their impact on improvement in engineering properties (viz., density, unconfined compressive strength (UCS), dispersion, and durability). Lime of 2-10% and GO of 0.05-0.1% dosages (% weight of BR) are selected for experimentation purpose. Results demonstrate that L and GO together, not the individual additive, is effective to stabilize BR. A substantial improvement in UCS from 710 kPa of raw BR to 3890 kPa after treating with 10% L and 0.1% GO with 60 days curing period has been observed. 6% L and 0.05% GO for strength only in the short-term, and 10% L and 0.05% GO in durability aspect in the long-term are found as optimum dosages. Drastic decline in turbidity from 453 to 83 NTU establishes that L (6%) and GO (0.05%) addition completely alleviates dispersion behavior in BR. Though GO addition is trivial, its effect on strength and durability enhancement of BR is significant. Cementitious gel formations and bonding mechanism leading to particle aggregations are evidenced as the reason behind the improvement in strength and durability of BR. To verify the applicability of amended BR, the obtained findings are compared vis-à-vis with standards, which illustrated that the amended BR could be an excellent resource material in road construction, especially in base or sub-base courses.


Introduction
Primary problems in the use of bauxite residue (BR) as a construction material are lower shear strength, collapse potential, and dispersion (Mishra et al., 2020b). Past research has established that the strength of BR is very low owing to the presence of an excessive quantity of monovalent sodium (Na + ) ions, which hinder particle flocculation (Reddy et al., 2021a, b;Zhang & Tao, 2008). The dispersion behavior of BR makes it vulnerable to severe erosion (Reddy et al., 2016a(Reddy et al., , 2021bSingh et al., 2020). Thus, addressing the strength and dispersion becomes key problems when BR is to be considered as a construction material. Alongside, pH above 10 and the possible leaching of toxic elements under severe alkaline circumstances are a few more deterrents for the low volume usage of BR (Singh et al., 2020;Zhang et al., 2018Zhang et al., , 2020a. On the other hand, road construction requires a substantial quantity of resource materials, which are acquired from naturally available resources. In view of the excessive exploitation of nature and natural resources, the conversion of waste materials into usable geomaterials by appropriately stabilizing them with additives seems promising. BR is one of the potential materials that could be devised as an alternative to naturally depleting materials. Dual problems of low strength and dispersion of BR can be alleviated by amending with suitable additive(s) such that the modified residue meets the requirement when it is to be employed for constructing embankments, rural roads, making of bricks and paving blocks, and developing BR based geopolymer products (Reddy et al., 2016b;Zhang et al., 2020b;Zhao et al., 2019Zhao et al., , 2020. Zhang et al. (2016) have developed a composite material using BR and slag with improved strength characteristics. Jha et al. (2020) have investigated the possibility of using BR to stabilize expansive soils to be used in clay lining system. Kumar & Kumar (2013) have conducted research on the utilization of BR in conjunction with other industrial by-products such as fly ash to produce paving blocks. On a pilot project scale, Kehagia (2008) has used BR for the development of a soil subgrade and road embankment.
Lime is documented as a highly effective additive for treating a range of geomaterials in the field of soil stabilization (Mishra et al., 2020a). Its treatment impacts consistency, compaction, strength, swelling, and dispersion characteristics of various types of problematic soils such as black cotton soil and organic soil (Ajayi, 2012). This can be linked to the versatility and heterogeneity as well as the variety of mineralogical properties of lime (Farhan et al., 2020). A typical comparison of the effect of lime with cement indicates that the improvement of shear strength in lime stabilized soil lasts for more than two years, whereas the latter additive effect continued only for six months (Al-Rawas et al., 2005). In this context, lime could be a potential additive to stabilize the BR. Based on the systematic review of literature, another important knowledge gap that the authors identified is poor understanding of the effect of curing time on lime stabilization. In the knowledge of authors, there are a few literatures available that discusses the influence of lime on BR. Table 1 elucidates the studies as regards to treatment of BR with calcium rich waste materials or lime.
Nano-sized elements, such as graphene oxide, have recently become popular as cementitious composites to improve the mechanical properties of soils. The use of graphene oxide (GO) in civil engineering applications has recently seen a significant upsurge in light of its merit as an additive to cementitious material. The review of literature reveals that majority of GO applications are remain confined to cement and concrete, either to improve strength (Gong et al., 2015;Liu et al., 2019), freeze-thaw resistance (Mohammed et al., 2016); porosity (Mohammed et al., 2015); workability (Indukuri et al., 2020) or durability (Priya et al., 2021). GO has also successfully been introduced as part of a hybrid additive to improve the performance of construction materials (Gao et al., 2019;Pateriya et al., 2021). Liu et al. (2018) used GO in hot mix asphalt binder for three types of warm mix additives and reported an increase in viscosity, deformation resistance, and elasticity at high temperatures in the GO-modified mixes. A greater degree of interfacial adhesion between GO and cement mix might explain the significant strength increment of the resultant mix.
It appears from the literature that a few efforts are devoted to explore the usability of GO in soil and waste material stabilization. Zhu et al. (2010) have noticed that liquid limit, plastic limit, and plasticity index of the cement-treated soil samples declines as GO concentration increases. The addition of GO to cement-treated soil resulting in an increment of unconfined compressive strength and shear strength has been reported by Naseri et al. (2016). Strength improvement, reduced compressibility and hydraulic conductivity are all factors in the development of the treated soil (Kai et al., 2019;Pateriya et al., 2019;Zhu et al., 2010).
The review of literature pertinent to BR suggests that it can be stabilized using lime, cement, and other pozzolanic additives with variable success rates. The majority of studies emphasize that it is necessary to stabilize the BR with more than one type of additive, bearing in mind multiple problems as aforementioned. There are no studies to the knowledge of authors that employ lime and graphene oxide, in tandem, to improve the geotechnical properties of BR. The present research focuses on evaluating the performance of L and GO in different proportions together to stabilize the BR. The efficacy is assessed in terms of compaction parameters and strength. In addition to the mechanical studies, durability properties of stabilized BR are evaluated. The results outlined in the paper have practical implications in terms of encouraging the use of BR in road construction as a base/subbase material, backfill material in geotechnical structures, and geomaterial in construction sector.

Materials and testing methodology
Bauxite Residue used in the present study was collected from the waste disposal pond of Vedanta Aluminium Limited, located at Lanjigarh in Kalahandi, Odisha, India. The samples collected were in wet and disturbed state and were collected from 1 m depth at the pond to ensure homogeneous sample collection. Soon after the collection, the wet samples were oven dried and pulverized with wooden mallet to prepared Comparison between the effect of lime only treatment and lime with organic acids treatment on compaction characteristics, UCS and pH of BR.
Characteristics of treated BR improved when the treatment was performed with both lime alone and lime and organic acid together.
the samples for subsequent laboratory testing programmes. Laboratory tests for establishing geotechnical properties including, specific gravity (G), gradational characteristics, consistency limits, compaction characteristics, alkalinity (pH), and classification were performed following ASTM codes. Table 2 presents the results of the aforementioned tests on BR samples.
To examine the effect of lime (L) and graphene oxide (GO) treatment on the strength parameters of the BR, commercial-grade L and GO were purchased from the Golchha enterprises, Jamshedpur. The dosage selected for lime were 0, 2, 4, 6, 8, and 10% and that of GO is 0, 0.05, and 0.1% (by basis of % dry weight of BR). The choice of dosage of lime is based on study by Satayanarayana et al. (2012), who have showed a steady increment in UCS up to 10% of lime dosage. Similalry, the above dosage of GO is decided such that the resultant produce is cost effective. Table 3 shows sample combinations along with designations for which laboratory experiments were performed.
Initially, standard Proctor compaction tests were performed for the aforementioned combinations as per ASTM (2007d) standard. Unconfined compressive strength (UCS) tests were carried out on stabilized samples as per the ASTM (2007a). A series of samples for the combinations shown in Table 2 were prepared by compacting to maximum dry unit weight (γ dmax ) at optimum moisture content (w opt ). The prepared samples were placed in the polybags to prevent moisture loss and cured for 7, 21, 45, and 60 days. Another identical set of samples was prepared for durability testing purposes. Each stabilized sample for durability test was initially cured for 7 days at an ambient condition and thereafter, it was immersed in water for 4 hours. After continuous 4 hours of immersion in water, UCS of the sample was measured. As there are no specified guidelines available to determine the durability of stabilized waste materials, values specified in the IRC: SP 89 (IRC, 2018) were referred to.
Additionally, dispersion tests (crumb tests) on the stabilized samples were conducted, as per ASTM (2019). For testing purposes, cylindrical samples were prepared with a length-to-diameter ratio of two, similar to that needed for UCS test according to ASTM (2007c). The samples were visually observed and photographed for any disintegration effect. The disintegrated particles from the sample affect the turbidity of the water. Hence, the turbidity of the water was measured using a Hach 2100N turbidity meter. Finally, pH of all the stabilized samples was measured according to ASTM (2007b).
To verify the inter-particle bonding and cementation effects of stabilized BR with L and GO, Scanning Electron Microscope (SEM) analysis was performed. It is to be noted that the SEM analysis was conducted on those stabilized samples, which were already subjected to UCS. Thus, curing periods remain common across samples used for SEM and UCS. A small portion of the stabilized soil was separated from the middle of soil core and was coated with a thin layer of gold for two minutes using Hitachi E-1010 Ion Sputter at a vacuum of 6 Pa before the analysis. The gold coating facilities to reveal the best morphological characteristic of the sample, simultaneously avoiding charging problems during testing.
To establish mineralogical compositions of the stabilized samples, X-Ray Diffraction (XRD) analysis was performed. For this purpose, sample grabbed from the stabilized soil core that was already subjected to UCS test was used. It was then oven dried at 105 °C for 24 hours, ground to powder form and sieved through 75 μm sieve. 4 g of this powder sample was scanned for 2θ ranging from 5 ° to 70 ° (Bragg angle) with a step increment of 0.01 ° and a time of 0.5 s/step size using a copper X-ray tube (Cu-Ka) at current and voltage of 30 mA and 40 kV.  BR + 2% Lime + 0% GO R1 3.

Effect of L and GO on compaction properties
Dry unit weight (γ d ) versus moisture content (w %) relationships are developed for raw BR as well as BR treated with varying proportions of L is shown in Figure 1. It is seen from the figure that γ dmax decreased and w opt increased with an increase in lime content, except corresponding to 2%. Generally, lime imbibes water for hydration. As the lime content increases, water requirement for its hydration increases. It is however can be noted that the reaction of lime with water is exothermic in nature. As a result, some part of water generally gets evaporated during the reaction process. These statements can be linked to an increase in w opt with an increase in lime content. Figure 2 represents the variation of γ dmax and w opt with a change in dosage of lime. It is evident from Figure 2 that there is a continuous decrease in γ dmax and an increase in ⱳ opt with increment of lime dosage. The maximum and minimum values of γ dmax and w opt are measured as 16.9 and 15.1 kN/ m 3 at 26.1 and 32.2% respectively. When lime content is increased from 2 to 10%, γ dmax decreased from 16.9 to 15.1 kN/ m 3 whereas w opt increased from 26.1 to 32.2%. Though lime content of 2% has yielded the highest values of γ dmax and w opt , trend lines of these parameters merged at a lime dosage of 6%. Thus, 6% of lime dosage is used for experimentation to understand the effect of L and GO hybrid additive in BR. It is also obvious that γ dmax value of 16.3 kN/m 3 meets the density requirement as prescribed by IRC 89 (IRC, 2010) for various civil engineering applications. The results in Figure 2 corroborate well with earlier studies by Mishra et al. (2019) and Ajayi (2012), who have stabilized the bauxite residue and soil using lime and noticed a decline in γ dmax with simultaneous increase in w opt . Similarly, Figure 3 depicts compaction curves established on BR for GO content of 0, 0.05, and 0.1% against a fixed L dosage of 6%. It is seen that γ dmax increased and w opt decreased with an increase in GO content. The reason behind the increment of density and decrement of moisture content can be explained by Lambs' theory. According to which, at low water content, attractive forces between the particles are stronger than repulsive forces. Hence, soils compacted at moisture content less than optimum moisture content have a flocculated structure (Zhu et al., 2010).
An increment of moisture content increases the repulsive forces. The soil compacted at moisture content more than w opt usually has a dispersed structure. It can be observed an improved compaction characteristic of BR samples when different percentages of GO (0, 0.05, and 0.1%) are incorporated but by keeping constant amount of lime (6%). The γ dmax value increased from 16.3 to 17.5 kN/ m 3 and w opt decreased from 30 to 27%. These observations excellently confirm the study by Naseri et al. (2016), who have illustrated an increase in GO quantity in the soil sample increases γ dmax , while lowering w opt . The increment of γ dmax is not only consistent but also meets IRC SP: 20-200220- (IRC , 2002 recommendations for road construction applications, as it prescribes a minimum value of 16.19 kN/m 3 .   The increase in dry unit weight can be attributed to interaction between GO and cementitious compounds formed by the reaction of lime with BR. As GO acts as nuclei sites for hydration products, its presence plays an important role in the formation of thicker crystals with denser growth, which have a capability to intertwine BR particles (Zhu et al., 2010). The decrement in w opt can be attributed to interface bonding between GO and cementitious products, as well as decrement of pores in samples. Corroborating the same, Naseri et al. (2016) have reported similar results of increment in γ dmax and decrement in w opt when GO sheets are added to soil/cement matrix. Confirming the above delineations, Lima et al (2017) have demonstrated a similarity in the hydration reaction occurring due to the admix of BR to calcium hydroxide to that of reaction between cement and water. On similar lines, Gordon et al. (1996) have highlighted the possible production of cementitious compounds including C-S-H gels when lime is added to BR. However, the quantity may comparatively low as reactive silica content in BR is relatively low and strength improvement of the matrix may also be due to formation of calcium aluminates (CA, possibly C 5 A 3 ) as well through the leftover alumina in BR. Mishra et al. (2019) have performed the XRD analysis on lime treated BR and illustrated the generation of cementitious compounds in presence of water. The results of XRD analysis performed in the present study, which will be discussed in the later section, also confirm the generation of various cementitious materials when lime and GO are added to BR.
It is a proven fact that BR contains high alkaline content and predominance of iron oxide, which is unusually greater than in normal soils. Thus, the impact of these variables on compaction parameters must be thoroughly understood, as there are no earlier studies that focused on such impacts of these variables on compaction properties. In the present study, compaction curves, as presented in Figure 1, clearly show that treated BR is sensitive to the moisture content. This implies that BR requires more compaction energy to achieve desirable outcomes.
Validation of the compaction characteristics in Figures 1 and 3 with the literature shows that these trends are quite similar to other wastes , except for non-ferrous slags, which exhibits extremely high γ dmax at little w opt . The findings in Figures 1 and 3 suggest that admix of L and GO together apparently overwhelms the extreme alkalinity and high iron content effects. It is also evident from the curves that the effect of GO is more vivid than L as regards to compaction properties of BR.
Understandably, the effect of GO on compaction characteristics of BR is quite opposite to that treatment with lime only. When used latter additive alone there is a continual decrement of density and increment of moisture content, which will not fetch any advantage. The GO content in the present study is limited to 0.1% bearing in mind the cost of this material. Demonstrably, the compaction results when compared vis-à-vis with different code recommendations portray that the combination of L and GO is doable to stabilize the highly alkaline bauxite residue.

Dispersion behavior
The performance of the L and GO combination on dispersion, is checked by crumb tests that are carried out on samples prepared by varying GO dosages (0, 0.05, and 0.1%) and lime of 0-10%. Corresponding to 0% L plus GO, the sample is considered a control test. Images of BR samples immersed in water after treating with L and GO are presented in Figure 4. As is evident from the results illustrated in Figure 4, the untreated sample (Figure 4a) is heavily dispersed, resulting in dark and cloudy water inside the beaker. Whereas samples treated with increasing dosage of L and GO showed recession in dispersion behavior (Figure 4b and Figure 4f). The density of suspended particles decreased in which samples treated with L and GO are immersed, as the solution in these beakers became clearer. Stable samples with less disintegration of particles can also be seen with an increase in dosage of L and GO. Further to ascertain the dispersion behavior, change in turbidity of the solution is measured, as shown in Figure 5.
The turbidity value of untreated BR is measured as high as 453 NTU (Nephelometric turbidity unit). A continual decrement in turbidity for higher dosage of L and GO indicates the ability of these additives in mitigating the dispersion behavior of BR samples. However, there are no specific guidelines in the literature that link turbidity to dispersion activity. Therefore, no proposition is made about the optimum dosage of L and GO combination. Incidentally, L of 6% and GO of 0.05%, and L of 10% and GO of 0.1% have yielded significantly lower values of turbidity of 88 and 14 NTU.
Dispersion is a phenomenon that occurs in soil when it has a sizeable amount of exchangeable sodium ions (Li et al., 2021;Mishra et al., 2020a). Dispersion behavior in the BR appears to be exacerbated by the deficiency of clay particles and the existence of substantial sodium ions concentration. Compared to the presence of monovalent excess Na + ions in the BR, concentrations of these divalent cations are exceedingly limited, resulting in the dispersive character . As evident from Figure 4, dispersion activity in BR is decreased. This may be linked to the predominance of Ca 2+ ions with the addition of lime. Divalent cations (Ca 2+ and Mg 2+ ) might have mitigated the dispersion by lowering the flocculation state. As the dosage of GO is increased, as it includes many hydroxyl groups that are formed by hydrogen bonding between the network of hydrogels and free water, there is a decrement in turbidity value. GO can also form a cross-linkage with calcium. The vast network of hydrogels, hydrogen bonding, and gel formed by cross-linking of GO with calcium all work together to improve particle binding and thereby, decline dispersion behavior in BR (Kai et al., 2019).

Effect of L and GO on UCS
UCS measured on BR samples stabilized with varying proportions of L and GO (refer to Table 2 for designation of mixes) for short (7 & 21 days) and long-term (45 & 60 days) curing periods are presented in Figure 6 in the form of bar chart.
A remarkable improvement in UCS of treated samples can be noticed, highlighting the performance as well as the effectiveness of L and GO together for stabilizing highly alkaline wastes like BR. The variation of UCS is also fairly distinct between L and GO. It can be seen that as curing period increases so does UCS value. It is observed that the strength attained by untreated BR on 7 th , 21 st , 45 th , and 60 th day of curing is 412, 532, 692, and 710 kPa. Where as, those BR samples treated with 10% L and 0.1% GO attained a maximum strength of 1871, 2635, 3612, and 3890 kPa on the 7 th , 21 st , 45 th , and 60 th day of curing. The improvement in UCS is 4.54, 4.95, 5.22, and 5.47 times the strength of untreated BR sample. The considerable increment in strength is a strong indication that the amended BR complies with the code provisions for a specific engineering application. Bearing this in mind, an attempt is made to find out the field applications of stabilized BR in various civil engineering applications, as discussed herein.
As such, Indian Road Congress (IRC) SP:20 (2002) recommends a minimum UCS value of 1500 kPa of the chemically stabilized waste after 28 days of curing to be used in sub-base or base course of rural roads. Similarly, the required minimum UCS value according to IS-37 (2018) at 7 days for cement-treated sub-base (CTSB) is 750 kPa. Evidently, many combinations of mixes meet the above requirement of minimum UCS as per the IRC codes. Incidentally, the strength attained in the long-term default conforms to or even exceeds the strength requirement of sub-base and base  course of rural roads and chemically treated sub-base course for pavements. However, the base course of flexible pavement requires to have a minimum of 4500 kPa of UCS value in 7 days. L of 10% and GO of 0.1% have produced UCS of 3890 kPa after 60 days, which is nearer to the required value of 4500 kPa, though it is unable to accomplish the desired strength. Higher dosage of L and GO might enhance the strength beyond 4500 kPa. However, such combination might increase the overall cost of the construction. Thus, in terms of cost economics, it is prudent to choose the lower percentage of L and GO combination. Understandably, combinations of L of 6% and GO of 0.05% in the short-term (UCS value of 1504 kPa after 21 days) and L of 4% and GO of 0.05% (UCS value after 60 days is 1581 kPa) in the long-term produced a minimum strength of 1500 kPa, which renders suitability of the samples as resource materials for sub-base and base course of rural roads.

Durability properties
The durability test is conducted to identify the stability of the material under diverse environmental conditions. Figure 7 presents the durability test results for different mix combinations. It is observed that mixed proportions of R1, R2, and R3 have either collapsed or are unable to retain their shape in water. Hence, UCS tests are not conducted on these samples. Samples treated with 8 and 10% L maintain their shape and size and produced adequate results after 4 hours of immersion.
From Table 4 and Figure 7, it is evident that samples R4 to R10 displayed a significant decrease in strength, as is true that the ratio of UCS of immersed samples to nonimmersed samples is calculated as < 80%. As per IRC: SP: 89 Part-1 (2010), if the strength ratio is < 80% such samples are unfit to be recommended for road construction purposes. It can be witnessed that mixes from R10 to R15 exhibited the strength that is greater than 80% of the strength of samples that are not plunged in water. Such combinations satisfy the a fore mentioned criteria and thus, they may be considered as regards to the durability. Further from the durability viewpoint, it can be stated that L of 10% and GO of 0.05% can be considered optimum dosage, as it fulfills the minimum strength requirement. Figures 6 and 7 establish that when only the lime content and combination of L and GO in BR is increased, UCS improvement is striking. Clearly, the increase in mechanical strength is obvious before and after dipping in water, where the before state indicates strength in the short-term and the after state indicates durability in the long-term. As the silica content  in BR is reportedly low, amount of generated cementitious products can understandably low when admixed lime alone. Hence, the increment in UCS is also lower when only L is added to BR, as evident from Figure 6. Results from study by Satayanarayana et al. (2012) shows a steady increase in UCS of lime treated BR and it postulates that this increase is due to the interaction between silica and alumina of BR and lime mix. Intriguingly, the introduction of GO to the matrix seemingly generated additional strength in the treated BR samples. At this juncture, the addition of GO together with L largely might have aided to attain higher strength of the desired level, as can be witnessed that strength of L + GO combination samples are pointedly higher vis-à-vis with those samples treated only with L. Generation of cementitious products due to reaction of L and BR (Gordon et al., 1996) and subsequent reaction of the cementitious and hydration products with GO is postulated to be contributing to the higher strength of the BR modified with the combination of L and GO. It is even interesting to note that a very modest addition of GO has greatly contributed to strength and durability enhancement, as is true from Figures 6 and 7. Table 5 shows the value of pH measured on BR samples stabilized with GO and L at various combinations and curing periods. The pH of raw BR is measured as 12.5. A glance at the results illustrates that the addition of L and GO has led to only a trivial reduction in pH of treated samples (the lowest observed pH is 11.8) against 12.5 of RBR, even after curing period of 60 days. A minute change in pH emphasizes that there are no obvious impacts, in terms of environmental, on the stabilized BR.

pH of lime and graphene oxide stabilized BR samples
The primary reason for the small change in pH can be linked to the fact that both L and RBR have pH values in the same range which is nearly 12-12.5. Hence, the addition of lime does not affect the pH of treated samples. The quantity of GO available in treated samples is also minimal. This may be a reason why there is an insignificant change in the pH of treated samples.

Mineralogical and morphological analysis
An attempt further is made to understand and confirm the improvement in strength, durability, and dispersion by confirming the mineralogical compositions of BR treated with L alone and that with L and GO by XRD analysis. Mix designated as R3 (BR + 6% L) and R8 (BR + 6% L + 0.05% GO) are considered for the analysis, as these are found to be the optimum dosage from the perspective of strength, compaction and dispersion. Figure 8 shows the X-Ray diffractogram patterns after identifying the dominant minerals and cementitious compounds.
As per the Kai et al. (2019), the mechanism behind strength improvement when GO along with cement is admixed to unstabilized material, is a reaction of calcium silicate hydrate (C-S-H) and Ca(OH) 2, which are products formed after the hydration of cement, with carboxylic acid groups on GO particles. It is stated that the contact produces a strong covalent connection at GO-composite interface, which improves load-transfer efficiency from the cement matrix to the GO and consequently improves the composite's mechanical characteristics. Whereas in the study by Wan & Zhang (2020), it is elaborated that the chemical reaction occurs at the interface between GO and cementitious gels leads to an increase in Young's modulus as well as concentration of gel formations under alkaline environment. Contrary to C-S-H as reported by Kai et al. (2019), CSHH and CASH are found in the L and GO treated samples in the present study ( Figure 8). Thus, it can be inferred that the reaction of CSHH, CASH along with Ca(OH) 2 with carboxylic acid groups on GO might be occurring in the L and GO treated samples. Further, the study by Pateriya et al. (2019) demonstrates that GO is a nanomaterial additive and it plays an important role in filling the pores within the matrix by providing nucleation sites. The prevalence of strong covalent bonding, increased Young's modulus and the activity of pore filling might have led to imparting additional strength to the matrix through creation of dense compact structure and further improvement in the durability properties, as reported in Figures 6 and 7. Addition of L and GO also introduces refinement in morphology of treated BR samples. For this purpose, morphological features of treated BR samples have been established by SEM analysis. Figure 9 depicts SEM images captured on RBR and that amended with L of 6% only and L of 6% with GO of 0.05%. These mix proportions are chosen based on the conclusions derived from the foregoing results and discussion. Visual observations reveal a higher degree of particle agglomerations of L stabilized BR (Figure 9b) as compared with RBR ( Figure 9a). Generation of CSHH and other cementitious products in the treated BR microstructure can be postulated as the reason for agglomerations in the matrix when lime is added to BR. Generally, the generated crystals are clustered to create bundles that result in pore filling and crystal overlapping. Since the BR and L promote the pozzolanic reaction, the mineral structure of L stabilized BR has changed to the agglomerated columnar mixture, as is evident from Figure 9b. These phenomena well justify the improvement in strength in the short-term period ( Figure 6) and durability in the long-term (Figure 7) simultaneously descending dispersion behavior ( Figure 5). Figure 9c shows the densified aggregation of cementitious products after adding GO to the mixture and they adhere each other tightly. When GO is introduced in the matrix, it fills the pores and acts as a nuclei to the cementitious products, resulting the mixture continue to develop, gradually becoming thicker and form the circular shape, and eventually agglomerate to cover the pores (Kai et al., 2019). They may also cross-link with calcium present in lime, allowing the substance to convert into the gel. The combination of the vast network of cementitious products such as Portlandite, Tricalcium aluminate, Dicalcium silicate, Calcium aluminum silicate hydrate, and Calcium silicate hydroxide hydrate along with GO resulted in an improvement in particle binding, bonding and aggregation. These processes well rationalize the strength and durability improvement in the long-term period (Figures 6 and 7).
Bonding of the particles can exist in several ways in the resultant matrix of L and GO stabilized BR. To delineate the same, a conceptual schematic has been drawn, as shown in Figure 10. Boehmite [ALO(OH)] can replace the carbon in the COOH group to form bonding between BR particles and GO. Hydrogen bonds can develop through hydroxyl ions in water with GO sheets, as is shown in Figure 10. These hydrogen bonds can also exist through the bonding of GO and water present in tricalcium aluminate (3CaO⋅Al 2 O 3 ⋅6H 2 O) (refer to Figure 8) generated due to the reaction between BR and lime in presence of water. Generally, water decomposes into hydroxyl ions (OH -) and hydrogen ions (H + ) when a mixture of water, BR, L, and GO is admixed, by virtue of their chemical nature. The decomposed hydroxyl ions from water as well as from broken edges of GO sheets can combine with calcium oxide to generate Portlandite [Ca(OH) 2 ] (refer to Figure 8). This leads to a constant generation of OHin the matrix. Further sodalite (3Na 2 O⋅3Al 2 O 3 ⋅6SiO 2 ⋅Na 2 SO 4 ) in BR will continue to react with Ca(OH) 2 to create CSHH in the presence of opulent hydroxides. Aluminum oxide and free sodium ions present in the BR can also react with hydroxyl ions to produce aluminum hydroxide [Al(OH) 3 ] and sodium  hydroxide (NaOH). These compounds encapsulate the BR particles within the gel substance or entrap the particles by adherence. Figure 10 illustrates the encapsulation and entrapment mechanism of BR particles and the consequent aggregation process, as visualized from SEM images depicted Figure 9. Such consequences excellently corroborate the strength and durability increment with the addition of L and GO together, as reported in Figures 6 and 7, and mitigation of dispersion as illustrated in Figure 5.

Conclusions
This study presents a novel viewpoint on the effective amendment of the extremely alkaline BR and demonstrates that the lime and graphene oxide combination are necessary and could be considered as potential stabilizer combination. The various results show that lime and GO can significantly improve the strength and durability characteristics concurrently declining the dispersion behavior of bauxite residue. It is important to note that though the addition of GO is trivial, it yet contributed for successful conversion of BR into usable geomaterial. The study finds that 6% L + 0.05% GO in strength, compaction and dispersion perspective and 10% L + 0.05%GO in durability perspective are found as optimum dosages. The strength attainment of 3031 kPa with 10% L alone and 1500 kPa with 6% L + 0.05% GO surpass the acceptability criteria of IRC SP: 20-2002 and IRC 37:2018, indicating that the stabilized BR could be a rich resource material for constructing base and sub-base layers of rural roads and subbase of flexible pavements. The crumb test results reveal that the addition of small amount of L and GO greatly helped in stability i.e. retention of shape and prevention of collapse or dispersion, of BR samples. The morphological analysis visibly displayed encapsulation and entrapment of particles by gel structures and inter-particle binding and bonding in the treated BR samples. Overall, the study complements the utilization of bauxite residue as a road construction material. Nevertheless, the strength properties of bauxite residue with amendments under extreme climatic conditions (such as drought and freeze-thaw) including leaching characteristics are also worth exploring in the future studies.

Declaration of interest
The authors have no conflicts of interest to declare. All co-authors have observed and affirmed the contents of the paper and there is no financial interest to report.

Data availability
The datasets generated analyzed in the course of the current study are available from the corresponding author upon request.