Synthesis, characterization, computational studies
and single crystal structures of [Ru(N—P)2(O—O)] complexes
- Received: November, 15, 2020
- Revised: December, 23, 2020
- Accepted for publication: December, 28, 2020
- DOI 10.26902/JSC_id74443
- Views: 244
Department of Chemistry, Faculty of Science, University of Jordan, Amman, Jordan
The title complexes [Ru(N—P)2(O—O)] (N—P = (8-diphenylphosphino)quinoline, O—O = dianion of oxalate (1), malonate (2) or 1,1-cyclobutandicarboxylate (3)), are prepared from [Ru(N—P)2Cl2] by a reaction with potassium salt of oxalate, malonate, or cyclobutandicarboxylate, respectively. All the complexes have distorted octahedral structures. Complex 1 crystallizes in the monoclinic system with space groups P21/c. On the other hand, complexes 2 and 3 crystallizes in the triclinic system with the space group P-1. The UV-Vis spectra of the three complexes
are modeled using time dependent density function theory (TD—DFT).
Keywords: 8-diphenylphosphinoquinoline, ruthenium complexes, oxalate, malonate, 1,1-cyclobutandicarboxylate
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Импакт-фактор 0.8 |
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Срок опубликования 4 мес |
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