Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter December 30, 2010

Application of polyaniline as an efficient and novel adsorbent for azo dyes removal from textile wastewaters

  • Reza Ansari EMAIL logo and Zahra Mosayebzadeh
From the journal Chemical Papers

Abstract

In this work, application of polyaniline coated onto wood sawdust (PAni/SD) for the removal of methyl orange (MO) as a typical azo dye from aqueous solutions is introduced. The effects of some important parameters such as pH, initial concentration, sorbent dosage, and contact time on the uptake of MO solution were also investigated. In order to get a better comparison, adsorption experiments were also carried out using commercial grade of granulated activated carbon (GAC) and sawdust without coating (SD) at the same time. It was found that PAni/SD can be used to remove azo dyes such as MO from aqueous solutions very efficiently. Experimental data were analyzed by the Langmuir and Freundlich models of adsorption. Kinetic parameters for the adsorption of MO dyes for the selected adsorbents are also reported. In order to study the possibility of desorption for frequent application, chemical regeneration of the used adsorbents was also investigated. Desorption or recovery of dye and regeneration of adsorbent (PAni/SD) was found to be quite possible and of high performance. Application of modified sawdust with polyaniline for the removal of azo dye is very promising for textile wastewater treatment.

[1] Al-Bastaki, N. (2004). Removal of methyl orange dye and Na2SO4 salt from synthetic waste water using reverse osmosis. Chemical Engineering and Processing, 43, 1561–1567. DOI: 10.1016/j.cep.2004.03.001. http://dx.doi.org/10.1016/j.cep.2004.03.00110.1016/j.cep.2004.03.001Search in Google Scholar

[2] Ansari, R. (2006). Application of polyaniline and its composites for adsorption/recovery of chromium (VI) from aqueous solutions. Acta Chimica Slovenica, 53, 88–94. Search in Google Scholar

[3] Ansari, R., & Alikhani, A. H. (2009). Application of polyaniline/nylon composites coating for corrosion protection of steel. Journal of Coatings Technology and Research, 6, 221–227. DOI: 10.1007/s11998-008-9140-6. http://dx.doi.org/10.1007/s11998-008-9140-610.1007/s11998-008-9140-6Search in Google Scholar

[4] Ansari, R., & Delavar, A. F. (2008). Sorption of silver ion from aqueous solutions using conducting electroactive polymers. Journal of the Iranian Chemical Society, 5, 657–668. 10.1007/BF03246147Search in Google Scholar

[5] Ansari, R., & Keivani, M. B. (2006). Polyaniline conducting electroactive polymers: Thermal and environmental stability studies. E-Journal of Chemistry, 3, 202–217. 10.1155/2006/395391Search in Google Scholar

[6] Ansari, R., & Raofie, F. (2006). Removal of mercuric ion from aqueous solutions using sawdust coated by polyaniline. EJournal of Chemistry, 3, 35–43. 10.1155/2006/523275Search in Google Scholar

[7] Bhadra, S., Khastgir, D., Singha, N. K., & Lee, J. H. (2009). Progress in preparation, processing and applications of polyaniline. Progress in Polymer Science, 34, 783–810. DOI: 10.1016/j.progpolymsci.2009.04.003. http://dx.doi.org/10.1016/j.progpolymsci.2009.04.00310.1016/j.progpolymsci.2009.04.003Search in Google Scholar

[8] Chung, K.-T., Stevens, S. E., & Cerniglia, C. E. (1992). The reduction of azo dyes by the intestinal microflora. Critical Reviews in Microbiology, 18, 175–190. DOI: 10.3109/10408419 209114557. http://dx.doi.org/10.3109/1040841920911455710.3109/10408419209114557Search in Google Scholar PubMed

[9] Guettaï, N., & Ait Amar, H. (2005). Photocatalytic oxidation of methyl orange in presence of titanium dioxide in aqueous suspension. Part I: Parametric study. Desalination, 185, 427–437. DOI: 10.1016/j.desal.2005.04.048. http://dx.doi.org/10.1016/j.desal.2005.04.04810.1016/j.desal.2005.04.048Search in Google Scholar

[10] Ho, Y.-S. (2004). Citation review of Lagergren kinetic rate equation on adsorption reactions. Scientometrics, 59, 171–177. http://dx.doi.org/10.1023/B:SCIE.0000013305.99473.cf10.1023/B:SCIE.0000013305.99473.cfSearch in Google Scholar

[11] Ho, Y. S., & Chiang, C. C. (2001). Sorption studies of acid dye by mixed sorbents. Adsorption, 7, 139–147. DOI: 10.1023/A:1011652224816. http://dx.doi.org/10.1023/A:101165222481610.1023/A:1011652224816Search in Google Scholar

[12] Ho, Y. S., & McKay, G. (1998). Sorption of dyes from aqueous solution by peat. Chemical Engineering Journal, 70, 115–124. DOI: 10.1016/S0923-0467(98)00076-1. 10.1016/S0923-0467(98)00076-1Search in Google Scholar

[13] Huang, H., Feng, X., & Zhu, J.-J. (2008). Synthesis, characterization and application in electrocatalysis of polyaniline/Au composite nanotubes. Nanotechnology, 19, 145607. DOI: 10.1088/0957-4484/19/14/145607. http://dx.doi.org/10.1088/0957-4484/19/14/14560710.1088/0957-4484/19/14/145607Search in Google Scholar

[14] Huang, M.-R., Peng, Q.-Y., & Li, X.-G. (2006). Rapid and effective adsorption of lead ions on fine poly(phenylenediamine) microparticles. Chemistry — A European Journal, 12, 4341–4350. DOI: 10.1002/chem.200501070. http://dx.doi.org/10.1002/chem.20050107010.1002/chem.200501070Search in Google Scholar

[15] Hung, W.-S., Humphrey, B. D., & MacDiarmid, A. G. (1986). Polyaniline, a novel conducting polymer. Morphology and chemistry of its oxidation and reduction in aqueous electrolytes. Journal of the Chemical Society, Faraday Transactions 1, 82, 2385–2400. DOI: 10.1039/F19868202385. http://dx.doi.org/10.1039/f1986820238510.1039/f19868202385Search in Google Scholar

[16] Kang, E. T., Neoh, K. G., & Tan, K. L. (1998). Polyaniline: A polymer with many interesting intrinsic redox states. Progress in Polymer Science, 23, 277–324. DOI: 10.1016/S0079-6700(97)00030-0. http://dx.doi.org/10.1016/S0079-6700(97)00030-010.1016/S0079-6700(97)00030-0Search in Google Scholar

[17] Kitani, A., Satoguchi, K., Iwai, K., & Ito, S. (1999). Electrochemical behaviors of polyaniline/polyaniline-sulfonic acid composites. Synthetic Metals, 102, 1171–1172. DOI: 10.1016/S0379-6779(98)01009-1. http://dx.doi.org/10.1016/S0379-6779(98)01009-110.1016/S0379-6779(98)01009-1Search in Google Scholar

[18] Küçükosmanoğlu, M., Gezici, O., & Ayar, A. (2006). The adsorption behaviors of methylene blue and methyl orange in a diaminoethane sporopollenin-mediated column system. Separation and Purification Technology, 52, 280–287. DOI: 10.1016/j.seppur.2006.05.005. http://dx.doi.org/10.1016/j.seppur.2006.05.00510.1016/j.seppur.2006.05.005Search in Google Scholar

[19] Lebo, S. E., Jr., Gargulak, J. D., & McNally, T. J. (2001) Lignin. In J. I. Kroschwitz, & M. Howe-Grant (Eds.), Kirk-Othmer encyclopedia of chemical technology (5th ed., Vol. 15, pp. 1–24). New York, NY, USA: Wiley. DOI: 10.1002/0471238961.1209071412 0914.a01.pub2. Search in Google Scholar

[20] Li, D., Huang, J., & Kaner, R. B.. (2009a). Polyaniline nanofibers: A unique polymer nanostructure for versatile applications. Accounts of Chemical Research, 42, 135–145. DOI: 10.1021/ar800080n. http://dx.doi.org/10.1021/ar800080n10.1021/ar800080nSearch in Google Scholar PubMed

[21] Li, J., Mi, C., Li, J., Xu, Y., Jia, Z., & Li, M. (2008a). The removal of MO molecules from aqueous solution by the combination of ultrasound/adsorption/photocatalysis. Ultrasonics Sonochemistry, 15, 949–954. DOI: 10.1016/j.ultsonch.2008. 03.002. http://dx.doi.org/10.1016/j.ultsonch.2008.03.00210.1016/j.ultsonch.2008.03.002Search in Google Scholar PubMed

[22] Li, X.-G., Feng, H., & Huang, M.-R. (2009b). Strong adsorbability of mercury ions on aniline/sulfoanisidine copolymer nanosorbents. Chemistry — A European Journal, 15, 4573–4581. DOI: 10.1002/chem.200802431. http://dx.doi.org/10.1002/chem.20080243110.1002/chem.200802431Search in Google Scholar PubMed

[23] Li, X.-G., Li, A., & Huang, M.-R. (2008b). Facile high-yield synthesis of polyaniline nanosticks with intrinsic stability and electrical conductivity. Chemistry — A European Journal, 14, 10309–10317. DOI: 10.1002/chem.200801025. http://dx.doi.org/10.1002/chem.20080102510.1002/chem.200801025Search in Google Scholar PubMed

[24] Li, X.-G., Ma, X.-L., Sun, J., & Huang, M.-R. (2009c). Powerful reactive sorption of silver(I) and mercury(II) onto poly(ophenylenediamine) microparticles. Langmuir, 25, 1675–1684. DOI: 10.1021/la802410p. http://dx.doi.org/10.1021/la802410p10.1021/la802410pSearch in Google Scholar PubMed

[25] Malik, P. K. (2004). Dye removal from wastewater using activated carbon developed from sawdust: adsorption equilibrium and kinetics. Journal of Hazardous Materials, 113, 81–88. DOI: 10.1016/j.jhazmat.2004.05.022. http://dx.doi.org/10.1016/j.jhazmat.2004.05.02210.1016/j.jhazmat.2004.05.022Search in Google Scholar PubMed

[26] Miras, M. C., Acevedo, D. F., Monge, N., Frontera, E., Rivarola, C. R., & Barbero, C. A. (2008). Organic chemistry of polyanilines: Tailoring properties to technological applications. The Open Macromolecules Journal, 2, 58–73. DOI: 10.2174/1874343900802010058. http://dx.doi.org/10.2174/187434390080201005810.2174/1874343900802010058Search in Google Scholar

[27] Mittal, A., Malviya, A., Kaur, D., Mittal, J., & Kurup, L. (2007). Studies on the adsorption kinetics and isotherms for the removal and recovery of Methyl Orange from wastewaters using waste materials. Journal of Hazardous Materials, 148, 229–240. DOI: 10.1016/j.jhazmat.2007.02.028. http://dx.doi.org/10.1016/j.jhazmat.2007.02.02810.1016/j.jhazmat.2007.02.028Search in Google Scholar PubMed

[28] Noroozi, B., Sorial, G. A., Bahrami, H., & Arami, M. (2007). Equilibrium and kinetic adsorption study of a cationic dye by a natural adsorbent.Silkworm pupa. Journal of Hazardous Materials, 139, 167–174. DOI: 10.1016/j.jhazmat.2006.06.021. http://dx.doi.org/10.1016/j.jhazmat.2006.06.02110.1016/j.jhazmat.2006.06.021Search in Google Scholar PubMed

[29] Sapurina, I., & Stejskal, J. (2009). Ternary composites of multi-wall carbon nanotubes, polyaniline, and noble-metal nanoparticles for potential applications in electrocatalysis. Chemical Papers, 63, 579–585. DOI: 10.2478/s11696-009-0061-3. http://dx.doi.org/10.2478/s11696-009-0061-310.2478/s11696-009-0061-3Search in Google Scholar

[30] Singh, V., Sharma, A. K., Tripathi, D. N., & Sanghi, R. (2009). Poly(methylmethacrylate) grafted chitosan: An efficient adsorbent for anionic azo dyes. Journal of Hazardous Materials, 161, 955–966. DOI: 10.1016/j.jhazmat.2008.04.096. http://dx.doi.org/10.1016/j.jhazmat.2008.04.09610.1016/j.jhazmat.2008.04.096Search in Google Scholar PubMed

[31] Stejskal, J., Trchova, M., Brožova, L., & Prokeš, J. (2009). Reduction of silver nitrate by polyaniline nanotubes to produce silver.polyaniline composites. Chemical Papers, 63, 77–83. DOI: 10.2478/s11696-008-0086-z. http://dx.doi.org/10.2478/s11696-008-0086-z10.2478/s11696-008-0086-zSearch in Google Scholar

[32] Sujatha, M., Geetha, A., Sivakumar, P., & Palanisamy, P. N. (2008). Orthophosphoric acid activated babul seed carbon as an adsorbent for the removal of methylene blue. E-Journal of Chemistry, 5, 742–753. 10.1155/2008/418267Search in Google Scholar

[33] Teng, M.-Y., & Lin, S.-H. (2006). Removal of methyl orange dye from water onto raw and acid-activated montmorillonite in fixed beds. Desalination, 201, 71–81. DOI: 10.1016/j.desal.2006.03.521. http://dx.doi.org/10.1016/j.desal.2006.03.52110.1016/j.desal.2006.03.521Search in Google Scholar

[34] Tsai, W. T., Chang, C. Y., Lin, M. C., Chien, S. F., Sun, H. F., & Hsieh, M. F. (2001). Adsorption of acid dye onto activated carbons prepared from agriculture waste bagasse by ZnCl2 activation. Chemosphere, 45, 51–58. DOI: 10.1016/S0045-6535(01)00016-9. http://dx.doi.org/10.1016/S0045-6535(01)00016-910.1016/S0045-6535(01)00016-9Search in Google Scholar

[35] Weidlich, C., Mangold, K.-M., & Jüttner, K. (2001). Conducting polymers as ion-exchangers for water purification. Electrochimica Acta, 47, 741–745. DOI: 10.1016/S0013- 4686(01)00754-X. http://dx.doi.org/10.1016/S0013-4686(01)00754-X10.1016/S0013-4686(01)00754-XSearch in Google Scholar

Published Online: 2010-12-30
Published in Print: 2011-2-1

© 2011 Institute of Chemistry, Slovak Academy of Sciences

Downloaded on 19.4.2024 from https://www.degruyter.com/document/doi/10.2478/s11696-010-0083-x/html
Scroll to top button