1961 Volume 3 Issue 3 Pages 156-167
Yoshimuraite, a new barium-titanium-manganese complex silicate mineral, was found in an alkali-pegmatitic facies bordering the bedded manganese deposit of the Misago ore body of the Noda-Tamagawa mine. Yoshimuraite occurs as dark-brownish platy to tabular crystals, or sometimes in the stellate groups embedded in coarse aggregates of barium-bearing potashfeldspar, quartz, richterite, urbanite, rhodonite etc.
It resembles lamprophyllite and astrophyllite which usually occur in alkali-pegmatites. It is orange brown in colour, brittle and has a perfect cleavage parallel to {010} and distinct cleavages on {10 ?? } and {101}. Polysynthetic twinning on {010} is common. Hardness, 41/2; Sp. gr., 4.13 (obs.) and 4.21 (calc.). Triclinic, with a0=7.00, b0=14.71, c0=5.39Å, α=93.5°, β=90.2°, γ=95.3°, and a:b:c=0.476:1:0.366. Space group, P ?? . Biaxial positive with α=1.763, β=1.777, γ=1.785, (+)2V=85°-90° ρ〉υ, and absorption X〈Y ?? Z. Optical orientation, γ′ nearly parallel to c-axis, α′ nearly parallel to a-axis. Pleochroism, α bright yellow, β orange-brown, γ brown.
Chemical analysis by J. Ito gave SiO2 18.25, TiO2 10.00, Fe2O3 1.32, FeO 1.47, MnO 17.64, MgO 0.56, ZnO 0.50, BaO 33.51, SrO 4.62, Na2O 0.16, K2O 0.03, P2O5 3.98, SO3 5.40, Cl 0.41, H2O(±) 2.34, less for Cl 0.09, total 100.10%. The results indicate a formula of approximately X2Y2 (Ti, Fe) O (Si2O7) ?? (P, S)O4 ?? (OH) or X2Y2 (Ti, Fe) (SiO4)2 ?? (P, S)O4 ?? (OH), where X=Ba, Sr and Na, Y=Mn, Fe, Mg and Zn.
The mineral is named after Professor Toyofumi Yoshimura who has contributed much to the study of manganese minerals in Japan.