doiSerbia

Production of highly porous glass-ceramics from metallurgical slag, fly ash and waste glass

Mangutova Bianka V. (Faculty of Technology and Metallurgy, University 'St. Ciril and Methodius', Skopje, Republic of Macedonia)
Fidancevska Emilija M. (Faculty of Technology and Metallurgy, University 'St. Ciril and Methodius', Skopje, Republic of Macedonia)
Milosevski Milosav I. (Faculty of Technology and Metallurgy, University 'St. Ciril and Methodius', Skopje, Republic of Macedonia)
Bossert Joerg H. (Friedrich Schiller University, Institute of Materials Science and Technology, Jena, Germany)

Glass-ceramics composites were produced based on fly-ash obtained from coal power stations, metallurgical slag from ferronickel industry and waste glass from TV monitors, windows and flasks. Using 50% waste flask glass in combination with fly ash and 20% waste glass from TV screens in combination with slag, E-modulus and bending strength values of the designed systems are increased (system based on fly ash: E-modulus from 6 to 29 GPa, and bending strength from 9 to 75 MPa). The polyurethane foam was used as a pore creator which gave the material porosity of 70(5% (fly ash-glass composite) and a porosity of 65( 5% (slag-glass composite). E-modulus values of the designed porous systems were 3.5(1.2 GPa and 8.1(3 GPa, while the bending strength values were 6.0(2 MPa and 13.2(3.5 MPa, respectively. These materials could be used for the production of tiles, wall bricks, as well as for the construction of air diffusers for waste water aeration.

Keywords: Glass-ceramics, fly ash, ferronickel slag, waste material, porosity, diffusers, aeration