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Journal of the Serbian Chemical Society 2003 Volume 68, Issue 2, Pages: 137-145
https://doi.org/10.2298/JSC0302137I
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Sulfur retention by ash during coal combustion - Part I: A model of char particle combustion

Ilić Mladen (Institute for Nuclear Sciences 'Vinča', P. O. Box 522, YU-11001 Belgrade)
Grubor Borislav ORCID iD icon (Institute for Nuclear Sciences 'Vinča', P. O. Box 522, YU-11001 Belgrade)
Manović Vasilije (Faculty of Mining and Geology University of Belgrade, Đušina 7, YU-11000 Belgrade, Yugoslavia)

A model for the combustion of porous char particles as a basis for modeling the process of sulfur retention by ash during coal combustion is developed in this paper. The model belongs to the microscopic intrinsic models and describes the dynamic behavior of a porous char particle during combustion taking into account temporal and spatial changes of all important physical properties of the char particle and various combustion parameters. The parametric analysis of the enhanced model shows that the model represents a good basis for the development of a model for the process of sulfur retention by ash during coal combustion. The model enables the prediction of the values of all parameters necessary for the introduction of reactions between sulfur compounds and mineral components in ash, primarily calcium oxide.

Keywords: dynamic model, char combustion, sulfur retention by ash