doiSerbia

Modelling of polyester fabric dyeing in the presence of ultrasonic waves

Kodrić Marija (Faculty of Technology, Leskovac)
Stojanović Sandra (Faculty of Technology, Leskovac)
Marković Branka (Faculty of Technology, Leskovac)
Đorđević Dragan (Faculty of Technology, Leskovac)

In this paper, modelling of dyeing, i.e. adsorptive behaviour of disperse dyes on polyester fibres (dyeing), under the influence of ultrasound has been considered with the aim of getting the data about mechanisms of binding the dyes and defining the conditions of dyeing process of this synthetic fibres along with additional energy source without the use of carriers, compounds that increase permeability of the fibres and help dyeing. Dyeing - adsorption is conducted under different conditions, and the concentration of dyes, mass of the substrate, recipes and time of dyeing were being varied. It has been established that ultrasound allows dyeing without carriers and the efficiency of dyeing depends on the time of contact, initial concentration of the dye and the amount of absorbent - material. There is the continuity of growth of the amount of bound dye to the mass of the absorbent. Characteristic graphs, obtained from Langmuir isotherm, have confirmed that this model ensures precise description of polyester dyeing by disperse dye. Kinetic of dyeing has been remarkably interpreted by pseudo second-order in regards to the high functionality.

Keywords: adsorption, polyester, disperse dye, ultrasound, Langmuir isotherm, kinetics