Chemical Industry and Chemical Engineering Quarterly 2015 Volume 21, Issue 2, Pages: 319-330
https://doi.org/10.2298/CICEQ140423032K
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Dissolution kinetics of South African coal fly ash and the development of a semi-empirical model to predict dissolution
Koech Lawrence (Department of Chemical Engineering, Vanderbijlpark Campus, Vaal University Of Technology, Private Bag X, Vanderbijlpark, South Africa)
Everson Ray (Department of Chemical and Minerals Engineering, Potchefstroom Campus, North West University, private Bag X, Potchefstroom, South Africa)
Neomagus Hein (Department of Chemical and Minerals Engineering, Potchefstroom Campus, North West University, private Bag X, Potchefstroom, South Africa)
Rutto Hilary (Department of Chemical Engineering, Vanderbijlpark Campus, Vaal University Of Technology, Private Bag X, Vanderbijlpark, South Africa)
Wet flue gas desulphurization (FGD) is a crucial technology which can be used
to abate the emission of sulphur dioxide in coal power plants. The
dissolution of coal fly ash in adipic acid is investigated by varying acid
concentration (0.05-0.15M), particle size (45- 150μm), pH (5.5-7.0),
temperature (318-363K) and solid to liquid ratio (5-15 wt %.) over a period
of 60 minutes which is a crucial step in wet (FGD). Characterization of the
sorbent was done using X-ray fluorescence (XRF), X-ray diffraction (XRD),
Furrier transform infrared (FTIR), scanning electron microscope (SEM) and
Branauer-Emmett-Teller (BET) surface area. BET surface area results showed an
increase in the specific surface area and SEM observation indicated a porous
structure was formed after dissolution. The experimental data was analyzed
using the shrinking core model and the diffusion through the product layer
was found to be the rate limiting step. The activation energy for the process
was calculated to be 10.64kJ/mol.
Keywords: flue gas desulphurization, coal fly ash, dissolution, shrinking core model, activation energy