Equilibrium and Adsorption Kinetic Study of Metal Ni(II) using Persimmon Tannin Gel

Authors

  • La O. Ahmad University of Halu Oleo
  • Ulfa H. Syam University of Halu Oleo
  • Laode A. Kadir University of Halu Oleo
  • Nohong Nohong University of Halu Oleo
  • Muh Natsir University of Halu Oleo
  • Nasriadi Dali University of Halu Oleo
  • Imran Imran University of Halu Oleo
  • Tahril Tahril Tadulako University
  • Thamrin Azis University of Halu Oleo

DOI:

https://doi.org/10.22487/j24775185.2022.v11.i2.pp111-116

Keywords:

Heavy metal, adsorption of Ni(II), persimmon tannin gel

Abstract

Heavy metal concentration exceeding the threshold amount is hazardous to the environment, so it needs some treatment. The study aimed to know the capacity and kinetics of adsorption. This study used the adsorption method to remove the heavy metal ion Ni(II) using persimmon tannin gel. Influences of time contact, pH, and ion concentration in the adsorption process were also investigated. Results showed optimum adsorption at 60 minutes of time contact and pH 5. Variation of concentration made the adsorption decrease as metal ion Ni(II) concentration increased. The maximum adsorption capacity was 23.14 mg/g by using pseudo-second-order adsorption kinetic model.

Author Biographies

La O. Ahmad, University of Halu Oleo

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Ulfa H. Syam, University of Halu Oleo

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Laode A. Kadir, University of Halu Oleo

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Nohong Nohong, University of Halu Oleo

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Muh Natsir, University of Halu Oleo

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Nasriadi Dali, University of Halu Oleo

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Imran Imran, University of Halu Oleo

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Tahril Tahril, Tadulako University

Department of Chemistry, Faculty of Teacher Training and Education

Thamrin Azis, University of Halu Oleo

Department of Chemistry, Faculty of Mathematics and Natural Sciences

References

Ab. Ari Setiawan, Anis Shofiyani , Intan Syahbanu (2017), Pemanfaatan Limbah Daun Nenas (Ananas Comosus) Sebagai Bahan Dasar Arang Aktif Adsorpsi Fe(II), 6(3), 66-74.

Ahmad Saad, Julien Bousquet, Nora Fernandez-Castro, Antoine Loquet, Julie Géan(2021), New Insights into Wine Taste: Impact of Dietary Lipids on Sensory Perceptions of Grape Tannins, J. Agric. Food Chem., 69 (10), 3165–3174

Anita Imawati1, Adhitiyawarman (2015), Kapasitas adsorpsi maksimum ion Pb (II) oleh arang aktif ampas kopi teraktivasi HC1 dan H3PO4, Jurnal Kimia Khatulistiwa, 4(2), 50-61.

Bounmy Keochaiyom, Jia Wan, Guangming Zeng, Danlian Huang, Wenjing Xue, Liang Hu, Chao Huang, Chen Zhang, Min Cheng (2017), Synthesis and application of magnetic chlorapatite nanoparticles for zinc(II), cadmium (II) and lead (II) removal from water solutions, Journal of Colloid and Interface Science, vol 505, 824-835.

Dennise Alejandra Murguía Flores, Ahmad La Ode, Ko-Ki Kunimoto, Jaime Bonilla Rios(2015), Immobilization Of Persimmon Tannin On Cellulose Viscoperals Of Caffeine From Aqueous Solution, MRS Online Proceedings Library Archive, Vol 1767, 93-105.

Idongesit O Ekpenyong, Effiong J Okon, Kufre E Essien and Okon E Okon (2021), Adsorption of Pb2+ from wastewater using modified and unmodified plantain pseudo stem waste as adsorbent. International Journal of Science and Research Archive, 03(01), 093–096.

I. A. Gede Widihati (2009), Adsorpsi Ion Pb 2+ oleh Lempung Terinterkalasi Surfaktan, Jurnal Kimia, 3(1), 27-32.

La Ode Ahmad, Le Hoang My Linh, Mio Akimoto, Yusuke Kaneki, Mitsunori Honda, Mitsuhiro Suda and Ko-Ki Kunimoto (2013), Persimmon Tannin Gel: Formation by Autoxidation and Caffeine Adsorption Properties, Food Sci. Technol. Res, 19 (4), 697 – 703.

Matheis F.J.D.P. Tanasale , Yusthinus T. Malea , Nina B. Gariumb (2020), Kinetika Adsorpsi Zat Warna Tartrazina Menggunakan Limbah Ampas Tahu sebagai Adsorben, Fullerene Journ. Of Chem, 5(2), 63-72.

Mega Dona Indriana, Danar Purwonugroho andDarjito Darjito, Adsorpsi Seng ( II) Menggunakan Biomassa Azolla microphylla Diesterifikasi dengan Asam Sitrat (2014) Jurnal Ilmu Kimia Universitas Brawijaya,2( 2), 534-540.

Mehmet Kayra Tanaydina, Ali Goksub (2021), Optimization of the adsorption of methyl green dye on almond shells using central composite design, Desalination and Water Treatment, 227, 425–439.

Muhammad Raziq Rahimi Kooh, Muhammad Khairud Dahri, Linda B.L. Lim (2016),

The removal of rhodamine B dye from aqueous solution using Casuarina equisetifolia needles as adsorbent, Cogent Environmental Science Vol 2 Issue 1, 1-14

Paul Egwuonwu Dim, Lukman Shehu Mustapha,Mutsee Termtanun (2021), Isotherm, Kinetics, and Thermodynamic Studies, Of Adsorption Of Cd From Textile Effluent With Acid Modified Clay, Journal of Chemical Technology and Metallurgy, 56(5), 1016-1029

Peng Zhou, Hua Yuan, Lijun Ou, Peng Zhiyuan (2019), Removal of Cd(II) and Cu(II) ions from aqueous solutions using tannin-phenolic polymer immobilized on cellulose, Journal of Macromolecular Science, Vol 6 Issue 7, 717-722.

P.Senthil Kumar, R.V.Abhinaya, K.Gayathri Lashmi, V. Arthi, R. Pavithra, V. Sathyaselvabala, S. Dinesh Kirupha and S. Sivanesan (2011), Adsorption of methylene blue dye from aqueous solution by agricultural waste: Equilibrium, thermodynamics, kinetics, mechanism and process design, Colloid Journal, 73(5),

Sijing Li, Kerry L. Wilkinson, Keren A. Bindon (2018), Compositional Variability in Commercial Tannin and Mannoprotein Products, American Journal of Enology and Viticulture, 69, 176-181.

Soroosh Roshan Zekayat, Fereshteh Raouf, Seved Siamak Ashraf Talesh (2020), Simultaneous adsorption of Cu2+ and Cr (VI) using HDTMA-modified zeolite: isotherm, kinetics, mechanism, and thermodynamic studies, Water Science & Technology, Vol 8 Issue 9, 2020.

Thamrin Azis, L.0. Ahmad, Fajrin E. Rosa, Laode A. Kadir (2019), Study of Equilibrium and Kinetics of Pb(II) in Solution Using Persimmon Tannin Gel as an Adsorbent, Jurnal Kimia Sains dan Aplikasi, 22 (6), 310-316.

Widihati, I.A.G., Suastuti N.G.A.M.D.A., dan Nirmalasari M.A.Y., 2012, Studi Kinetika Adsorpsi Larutan Ion Logam Kromium (Cr) menggunakan Arang Batang Pisang (Musa Paradisiaca), Jurnal Kimia, 6 (1)

Xiaoli Yuan, Dongshan Zhou, Wentang Xia, Juan An, Xuejiao Zhou, Jianguo Yin (2020), Adsorption of Cd(II) ions from aqueous solution by wasted lowgrade phosphorus-containing oolitic hematite: equilibrium, kinetics, and thermodynamics, Desalination and Water Treatment, Vol 192, 271–282.

Soroosh Roshan Zekayat, Fereshteh Raouf, Seved Siamak Ashraf Talesh (2020), Simultaneous adsorption of Cu2+ and Cr (VI) using HDTMA-modified zeolite: isotherm, kinetics, mechanism, and thermodynamic studies, Water Science & Technology, Vol 8 Issue 9, 2020.

Xindi Zhang, Hongyue Wang, Qianyun Jia, Jiaqing Cao, Xiangrong Zhang (2021), Extraction and application of tannin in the medical, food, and chemical industries, Journal of Polyphenols, 3 (1), 62-75.

Downloads

Published

2022-05-30

How to Cite

Ahmad, L. O., Syam, U. H. ., Kadir, L. A. ., Nohong, N., Natsir, M. ., Dali, N. ., Imran, I., Tahril, T., & Azis, T. (2022). Equilibrium and Adsorption Kinetic Study of Metal Ni(II) using Persimmon Tannin Gel. Jurnal Akademika Kimia, 11(2), 111–116. https://doi.org/10.22487/j24775185.2022.v11.i2.pp111-116

Issue

Section

Articles

Most read articles by the same author(s)