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Title: Li-FSI Impurity Impact Study: Final CRADA Report

Technical Report ·
DOI:https://doi.org/10.2172/1341903· OSTI ID:1341903
 [1];  [1];  [1]
  1. Argonne National Lab. (ANL), Argonne, IL (United States)

There is growing interest in lithium bis(fluorosulfonyl)imide (LiFSI ) as an alternative to LiPF6 and as an additive to electrolytes used in lithium-ion cells. LiFSI has attracted attention because it is reported to have higher ionic conductivity, better high temperature stability, and enhanced stability toward hydrolysis, Also, LiFSI additive to electrolytes can bring benefits of improved storage properties and reduced gas evolution in the cells. Different levels of different electrochemically active impurities could affect the performance of LiFSI as an electrolyte salt for Li-ion batteries, generating inconsistent and conflicting interpretations of the experimental data.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
AC02-06CH11357
OSTI ID:
1341903
Report Number(s):
ANL/ES-C1401001; 133328
Country of Publication:
United States
Language:
English

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