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https://doi.org/10.21256/zhaw-4261| Publication type: | Conference paper |
| Type of review: | Peer review (publication) |
| Title: | Inactivation of palladium-based oxygen scavenger system by volatile sulphur compounds present in the headspace of packaged food |
| Authors: | Röcker, Bettina Rüegg, Nadine Glöss, Alexia N. Yeretzian, Chahan Yildirim, Selçuk |
| DOI: | 10.21256/zhaw-4261 10.1002/pts.2220 |
| Published in: | Packaging Technology and Science |
| Proceedings: | Packaging Technology and Science |
| Volume(Issue): | 30 |
| Issue: | 8 |
| Page(s): | 427 |
| Pages to: | 442 |
| Conference details: | 20th IAPRI World Conference on Packaging 2016, Sao Paulo, 12-15 June 2016 |
| Issue Date: | 2017 |
| Publisher / Ed. Institution: | Wiley |
| ISSN: | 0894-3214 |
| Language: | English |
| Subjects: | Volatile sulphur compounds; Palladium; Oxygen scavengers; Catalyst poisoning |
| Subject (DDC): | 664: Food technology |
| Abstract: | An oxygen scavenger based on a catalytic system with palladium (CSP) was recently developed to remove oxygen in food packagings. Although the CSP worked with various types of food, with some foods, an inhibition of the CSP was observed. Because such catalytic systems are susceptible to poisoning by sulfurcontaining compounds, the aim of this study was to understand the inactivation of palladium-based catalysts in presence of foods containing volatile sulfur compounds (VSCs). To achieve this, the oxygen scavenging activity (OSA) of the CSP was evaluated in presence of selected food products. Afterwards, VSCs mainly present in these foods were exposed to the CSP, and the influence on the OSA was evaluated. Finally, headspace analysis was performed with the diluted VSCs and with the packaged food products using proton transfer reaction time-of-flight mass spectrometry. It was found that the catalytic activity of the CSP was inhibited when VSCs were present in the headspace in concentrations ranging between 10.8–36.0 ppbv (dimethyl sulfide, DMS), 1.2–7.2 ppbv (dimethyl disulfide), 0.7–0.9 ppbv (dimethyl trisulfide), 2.1–5.8 ppbv methional) and 4.6–24.5 ppbv (furfuryl thiol). It was concluded that in packaged roast beef and cheese, DMS may be the compound mainly responsible for the inactivation of the CSP. In packagings containing ham, the key compounds were hydrogen sulfide and methanethiol; in peanuts, it was methanethiol; and in par-baked buns, an accumulation of methional, DMS, butanethiol and methionol. When potato chips were packaged, it was demonstrated that when VSCs are present in low concentrations, oxygen can still be scavenged at a reduced OSA. |
| URI: | https://digitalcollection.zhaw.ch/handle/11475/7082 |
| Fulltext version: | Submitted version |
| License (according to publishing contract): | Licence according to publishing contract |
| Departement: | Life Sciences and Facility Management |
| Organisational Unit: | Institute of Food and Beverage Innovation (ILGI) |
| Appears in collections: | Publikationen Life Sciences und Facility Management |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| 2016_Röcker_Inactivation of Pd-based oxygen scavenger_final_submitted manuscript.pdf | eingereichte Version / submitted version | 921.74 kB | Adobe PDF |  View/Open |
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Röcker, B., Rüegg, N., Glöss, A. N., Yeretzian, C., & Yildirim, S. (2017). Inactivation of palladium-based oxygen scavenger system by volatile sulphur compounds present in the headspace of packaged food [Conference paper]. Packaging Technology and Science, 30(8), 427–442. https://doi.org/10.21256/zhaw-4261
Röcker, B. et al. (2017) ‘Inactivation of palladium-based oxygen scavenger system by volatile sulphur compounds present in the headspace of packaged food’, in Packaging Technology and Science. Wiley, pp. 427–442. Available at: https://doi.org/10.21256/zhaw-4261.
B. Röcker, N. Rüegg, A. N. Glöss, C. Yeretzian, and S. Yildirim, “Inactivation of palladium-based oxygen scavenger system by volatile sulphur compounds present in the headspace of packaged food,” in Packaging Technology and Science, 2017, vol. 30, no. 8, pp. 427–442. doi: 10.21256/zhaw-4261.
RÖCKER, Bettina, Nadine RÜEGG, Alexia N. GLÖSS, Chahan YERETZIAN und Selçuk YILDIRIM, 2017. Inactivation of palladium-based oxygen scavenger system by volatile sulphur compounds present in the headspace of packaged food. In: Packaging Technology and Science. Conference paper. Wiley. 2017. S. 427–442
Röcker, Bettina, Nadine Rüegg, Alexia N. Glöss, Chahan Yeretzian, and Selçuk Yildirim. 2017. “Inactivation of Palladium-Based Oxygen Scavenger System by Volatile Sulphur Compounds Present in the Headspace of Packaged Food.” Conference paper. In Packaging Technology and Science, 30:427–42. Wiley. https://doi.org/10.21256/zhaw-4261.
Röcker, Bettina, et al. “Inactivation of Palladium-Based Oxygen Scavenger System by Volatile Sulphur Compounds Present in the Headspace of Packaged Food.” Packaging Technology and Science, vol. 30, no. 8, Wiley, 2017, pp. 427–42, https://doi.org/10.21256/zhaw-4261.
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