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Sensitive Electrochemical Capsaicin Sensor Based on a Screen Printed Electrode Modified with Poly(sodium 4-styrenesulfonate) Functionalized Graphite

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Abstract

A sensitive capsaicin sensor was constructed based on a poly(sodium 4-styrenesulfonate) functionalized graphite modified screen printed electrode (PSS-Grp/SPE) in this study. The PSS-Grp and poly(diallyldimethylammonium chloride) functionalized graphite (PDDA-Grp) were easily synthesized by interacting Grp with PSS and PDDA through sonication, and resulted in negative and with positive charges on the surface, respectively. The prepared PSS-Grp and PDDA-Grp were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and ultraviolet and visible spectroscopy (UV-vis). The electrochemical performance of PSS-Grp in a 50 μM capsaicin solution presented a current density of 33 μA cm–2, which was much higher than the PDDA-Grp of 1.5 μA cm–2. Our study showed that capsaicin could interact better with strong negative charges on the PSS-Grp/SPE surface to give a higher electrochemical response. The direct electrochemical sensing of capsaicin was achieved at PSS-Grp/SPE using differential pulse stripping voltammetry (DPSV) under the optimized conditions.

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Acknowledgments

The authors thank the National Natural Science Foundation of China (No. 21372088), the Fund of Guangzhou Science Technology and Innovation Commission (201508020010), and the Fund of Hainan Science and Technology Department (KJHZ2015-32) for financial supports.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510641, P. R. China

    Yan Wang, Bin-Bin Huang, Wan-Lin Dai & Jian-Shan Ye

  2. Hainan Institute for Food Control, No. 9, Yaogu Yi Road, Xiu Ying District, Haikou, 570311, P. R. China

    Bin Xu & Tian-Liang Wu

  3. Guangzhou Ingsens Sensor Technology Co., Ltd., Guangzhou, 510535, P. R. China

    Jia-Ping Ye

Authors
  1. Yan Wang
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  2. Bin-Bin Huang
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  3. Wan-Lin Dai
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  4. Bin Xu
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  5. Tian-Liang Wu
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  6. Jia-Ping Ye
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  7. Jian-Shan Ye
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Correspondence to Jian-Shan Ye.

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Wang, Y., Huang, BB., Dai, WL. et al. Sensitive Electrochemical Capsaicin Sensor Based on a Screen Printed Electrode Modified with Poly(sodium 4-styrenesulfonate) Functionalized Graphite. ANAL. SCI. 33, 793–799 (2017). https://doi.org/10.2116/analsci.33.793

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  • DOI: https://doi.org/10.2116/analsci.33.793

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