Skip to main content
SpringerLink
Log in

Separation of Inorganic Anions on a Chemically Bonded 18-Crown-6 Ether Stationary Phase in Capillary Ion Chromatography

  • Published:
Analytical Sciences Aims and scope Submit manuscript

Abstract

Inorganic anions were separated on a chemically bonded 18-crown-6 ether (18C6E) stationary phase in capillary ion chromatography. In this study 18C6E groups were chemically bonded on silica gel via reaction with 3-glycidyloxypro-pyltrimethoxysilane, followed by reaction with 2-aminomethyl-18C6E. Analyte anions were separated in the ion-exchange mode based on the fact that the eluent cation was trapped on the 18C6E and it worked as the anion-exchange site. The eluent cation and eluent anion as well as the eluent concentration affected the retention of the analyte anions. Different selectivity was achieved by using an acetonitrile-rich eluent. The present stationary phase was applied for the determination of UV-absorbing anions contained in saliva samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Small, T. S. Stevens, and W. C. Bauman, Anal. Chem., 1975, 47, 1801.

    Article  CAS  Google Scholar 

  2. P. R. Haddad and P. E. Jackson, “Ion Chromatography: Principles and Applications (J. Chromatogr. Library Vol. 46)”, 1990, Elsevier, Amsterdam, London, New York, Tokyo, 233.

  3. J. D. Lamb and R. G. Smith, J. Chromatogr., A, 1991, 546, 73.

    Article  CAS  Google Scholar 

  4. M. W. Läubi and B. Campus, J. Chromatogr., A, 1995, 706, 103.

    Article  Google Scholar 

  5. K. Ohta, K. Kusumoto, Y. Takao, A. Towata, S. Kawakami, M. Ohashi, and T. Takeuchi, Chromatographia, 2003, 58, 171.

    Article  CAS  Google Scholar 

  6. J. D. Lamb, R. G. Smith, and J. Jagodzinski, J. Chromatogr., A, 1993, 640, 33.

    Article  CAS  Google Scholar 

  7. T. Takeuchi and L. W. Lim, Anal. Sci., 2011, 27, 1019.

    Article  CAS  PubMed  Google Scholar 

  8. H. S. Cho, H. J. Choi, and M. H. Hyun, J. Chromatogr., A, 2009, 1216, 7446.

    Article  CAS  PubMed  Google Scholar 

  9. Y. Machida, H. Nishi, K. Nakamura, H. Nakai, and T. Sato, J. Chromatogr., A, 1998, 805, 82.

    Article  Google Scholar 

  10. M. H. Hyun, J. Sep. Sci., 2006, 29, 750.

    Article  CAS  PubMed  Google Scholar 

  11. T. Takeuchi and L.W. Lim, Anal. Sci., 2010, 26, 937.

    Article  CAS  PubMed  Google Scholar 

  12. L.W. Lim, L. Rong, and T. Takeuchi, Anal. Sci., 2012, 28, 205.

    Article  CAS  PubMed  Google Scholar 

  13. T. Takeuchi and D. Ishii, J. Chromatogr., 1981, 213, 25.

    Article  CAS  Google Scholar 

  14. J. S. Fritz and D. T. Gjerde, “Ion Chromatography”, 3rd, completely revised and enlarged ed., Wiley-VCH, Weinheim, 2000, 88.

  15. A. J. Smetana and A. I. Popov, J. Solution Chem., 1980, 9, 183.

    Article  CAS  Google Scholar 

  16. R. M. Izatt, R. E. Terry, B. L. Haymore, L. D. Hansen, N. K. Dalley, A. G. Avondet, and J. J. Christensen, J. Am. Chem. Soc., 1976, 98, 7620.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Engineering, Gifu University, 1-1 Yanagido, Gifu, 501-1193, Japan

    Toyohide Takeuchi, Kimi Tokunaga & Lee Wah Lim

Authors
  1. Toyohide Takeuchi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kimi Tokunaga
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Lee Wah Lim
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Toyohide Takeuchi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Takeuchi, T., Tokunaga, K. & Lim, L.W. Separation of Inorganic Anions on a Chemically Bonded 18-Crown-6 Ether Stationary Phase in Capillary Ion Chromatography. ANAL. SCI. 29, 423–427 (2013). https://doi.org/10.2116/analsci.29.423

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.2116/analsci.29.423

Search

Navigation