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Measurement of Dissolved Oxygen Based on Enhanced Cerium(IV) Chemiluminescence

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Abstract

The reaction of Ce(IV) with pyrogallol caused chemiluminescence, which was enhanced by dissolved oxygen. Dissolved oxygen in water was able to help in the determination by enhancing the chemiluminescence intensity. The limit of detection calculated from 3swas 43 μmol/dm3, and the relative standard deviation was 1.2% at 613 μmol/dm3 (n = 5). The results obtained for natural and tap water samples were compared with those provided by conventional methods; the agreement between them corroborated the usefulness of the proposed method. The chemiluminescence mechanism was studied by examining the effect of interference with Cl- and measuring the chemiluminescence spectrum. The chemiluminescence emitter, however, could not be identified.

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References

  1. U. Isacsson and G. Wettermark, Anal. Chim. Acta, 1974, 68, 339.

    Article  CAS  Google Scholar 

  2. A. Fontijn, A. J. Sabadell, and R. J. Ronco, Anal. Chem., 1970, 42, 575.

    Article  CAS  Google Scholar 

  3. R. C. Benner and P. H. Stedman, Anal. Chem., 1989, 61, 1268.

    Article  CAS  Google Scholar 

  4. Y. Maeda, K. Aoki, and M. Munemori, Anal. Chem., 1980, 52, 307.

    Article  CAS  Google Scholar 

  5. C. A. Cantrell, D. H. Stedman, and G. J. Wendel, Anal. Chem., 1984, 56, 1406.

    Article  Google Scholar 

  6. D. F. Marino and J. D. Ingle, Jr., Anal. Chim. Acta, 1981, 124, 23.

    Article  CAS  Google Scholar 

  7. K. Fujimori, N. Takenaka, H. Bandow, and Y. Maeda, Anal. Commun., 1998, 35, 307.

    Article  CAS  Google Scholar 

  8. K. Fujimori, Doctoral Thesis at Osaka Prefecture University, 1999.

    Google Scholar 

  9. M. Kitano, Y. Ogasawara, X. Hu, N. Takenaka, H. Bandow, and Y. Maeda, Microchem. J., 1994, 49, 265.

    Article  CAS  Google Scholar 

  10. M. Kitano, K. Fujimori, N. Takenaka, H. Bandow, and Y. Maeda, J. Jpn. Soc. Wat. Environ., 1997, 20, 193.

    Article  CAS  Google Scholar 

  11. X. Hu, M. Kitano, N. Takenaka, H. Bandow, Y. Maeda, and D. Zhang, Bunseki Kagaku, 1994, 43, 1077.

    Article  CAS  Google Scholar 

  12. T. Korenaga, X. Zhou, K. Okada, and T. Moriwake, Anal. Chim. Acta, 1993, 272, 237.

    Article  CAS  Google Scholar 

  13. D. B. Paul, Talanta, 1978, 25, 377.

    Article  CAS  Google Scholar 

  14. M. Yamada, T. Komatu, S. Nakahara, and S. Suzuki, Anal. Chim. Acta, 1983, 155, 259.

    Article  CAS  Google Scholar 

  15. Y. Maeda, X. Hu, S. Itou, M. Kitano, H. Bandow, and M. Munemori, Analyst, 1994, 119, 2237.

    Article  CAS  Google Scholar 

  16. E. G. Sarantonis and A. Townshend, Anal. Chim. Acta, 1986, 184, 311.

    Article  CAS  Google Scholar 

  17. Nihonkikaku, “JIS Handobukku Kougaikankei 1993 (JIS Handbook: Environmental Pollution 1993, in Japanese)”, 1993, Heibunsya, Tokyo, 908.

    Google Scholar 

  18. Chemical Society of Japan (ed.), “Kagaku Binnran 2nd ed. (Handbook of Chemistry, in Japanese)”, 1975, Maruzen, Tokyo, 1206.

    Google Scholar 

  19. F. A. Cotton, G. Wilkinson, C. A. Murilllo, and M. Bochmann, “Advanced Inorganic Chemistry,” 6th ed., 1999, John Wiley & Sons Inc., New York, 1125.

    Google Scholar 

  20. N. J. Turro, “Modern Molecular Photochemistry,” 1978, The Benjamin/Cummings Publishing Co., Menol Park, 594.

    Google Scholar 

  21. S. Yamamoto, “Tikyukagakukouza: Rikusui (Lecture of Geophysics: Surface Water, in Japanese)”, 1968, Vol. 9, Kyouritu, Tokyo, 40.

    Google Scholar 

  22. M. Kobayashi, Y. Nomura, and A. Okamura, “Koukou Kagaku” (High School Chemistry, in Japanese)”, 1988, Suuken, Tokyo, 221.

    Google Scholar 

  23. M. Yamada and S. Suzuki, “Seibutuhakkou to Kagakuhakkou: Kiso to Jikkenn (Bioluminescence and Chemiluminescence: Foundation and Experimental, in Japanese)”, ed. K. Imai, 1989, Hirokawasyoten, Tokyo, 108.

  24. S. I. Montalvo and J. D. Ingle, Jr., Talanta, 1993, 40, 167.

    Article  CAS  Google Scholar 

  25. J. Stauff, Z. Phys. Chem., N. F., 1965, 49, 58.

    Article  Google Scholar 

  26. A. A. Alwarthan, Anal. Chim. Acta, 1995, 317, 233.

    Article  CAS  Google Scholar 

  27. A. U. Khan and M. Kasha, J. Am. Chem. Soc., 1970, 92, 3293.

    Article  CAS  Google Scholar 

  28. D. Slawinska and J. Slawinski, Anal. Chem., 1975, 47, 2101.

    Article  CAS  Google Scholar 

  29. X. Hu, N. Takenaka, M. Kitano, H. Bandow, Y. Maeda, and M. Hattori, Analyst, 1994, 119, 1829.

    Article  CAS  Google Scholar 

  30. Wavelength at which the glass filters have 50% transmittance. Their absorbance sharply increases in the vicinity of T50 and becomes about 1 after T50.

  31. H. Kobayashi, “Hakkou no Buturi (Physics of Luminescence, in Japanese)”, 2000, Asakura, Tokyo, 153.

    Google Scholar 

  32. Hamamatsu Photonics, Ltd., “Catalog: Photomultiplier tubes and products related with those”, 77.

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Author notes

  1. Keiichi Fujimori

    Present address: Department of Applied Science, Faculty of Engineering, Osaka Institute of Technology, 5-16-1, Omiya Asahi, Osaka, 535-8585, Japan

Authors and Affiliations

  1. Department of Applied Materials Science, College of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Sakai, Osaka, 599-8531, Japan

    Keiichi Fujimori, Norimichi Takenaka, Hiroshi Bandow & Yasuaki Maeda

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  1. Keiichi Fujimori
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  2. Norimichi Takenaka
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  3. Hiroshi Bandow
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  4. Yasuaki Maeda
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Fujimori, K., Takenaka, N., Bandow, H. et al. Measurement of Dissolved Oxygen Based on Enhanced Cerium(IV) Chemiluminescence. ANAL. SCI. 17, 161–166 (2001). https://doi.org/10.2116/analsci.17.161

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  • DOI: https://doi.org/10.2116/analsci.17.161

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