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A Simplified and Turn-on Fluorescence Chemosensor Based on Coumarin Derivative for Detection of Aluminium(III) Ion in Pure Aqueous Solution

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Abstract

A novel chemosensor L based on coumarin Schiff-base was synthesized and investigated. Sensor L showed remarkable selectivity for Al3+ in Tris-HCl aqueous buffer solution (pH 7.2), and the selectivity was not affected by the presence of a large excess of other competitive ions. The sensor responded rapidly to Al3+ in aqueous solutions with a 2:1 stoichiometry. Meanwhile, it indicated significant improvement of quantum efficiency and ideal fluorescent lifetime.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Southeast University, 211189, Nanjing, Jiangsu, P. R. China

    Li-Qiang Yan, Mei-Fang Cui, Yan Zhou, Yun Ma & Zheng-Jian Qi

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  1. Li-Qiang Yan
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  2. Mei-Fang Cui
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  3. Yan Zhou
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Correspondence to Zheng-Jian Qi.

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Yan, LQ., Cui, MF., Zhou, Y. et al. A Simplified and Turn-on Fluorescence Chemosensor Based on Coumarin Derivative for Detection of Aluminium(III) Ion in Pure Aqueous Solution. ANAL. SCI. 31, 1055–1059 (2015). https://doi.org/10.2116/analsci.31.1055

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