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Synthesis of N′-(1-Pyridin-2-ylmethylene)-2-furohydrazide and Its Application in Construction of a Highly Selective PVC-Based Membrane Sensor for La(III) Ions

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Abstract

A highly La(III) ion-selective PVC membrane sensor based on N′-(1-pyridin-2-ylmethylene)-2-furohydrazide (NPYFH) as an excellent sensing material was successfully developed. The electrode shows a good selectivity for La(III) ion with respect to most common cations including alkali, alkaline earth, transition and heavy metal ions. The proposed sensor exhibits a wide linear response with slope of 19.2 ± 0.6 mV per decade over the concentration range of 1.0 × 10–6–1.0 × 10–1 M, and a detection limit of 7.0 × 10–7 M of La(III) ions. The sensor response is independent of pH in the range of 3.5–10.0. The proposed electrode was applied as an indicator electrode in potentiometric titration of La(III) ion with EDTA.

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Authors and Affiliations

  1. Department of Chemistry, Quchan Branch, Islamic Azad University, Quchan, Iran

    Hassan Ali Zamani

  2. Department of Chemistry, Tehran University, Tehran, Iran

    Mohammad Reza Ganjali, Parviz Norouzi & Mahdi Adib

  3. Department of Chemistry, Tarbiat Modarres University, Tehran, Iran

    Mohammad Aceedy

Authors
  1. Hassan Ali Zamani
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  2. Mohammad Reza Ganjali
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  3. Parviz Norouzi
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  4. Mahdi Adib
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  5. Mohammad Aceedy
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Correspondence to Hassan Ali Zamani.

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Zamani, H.A., Ganjali, M.R., Norouzi, P. et al. Synthesis of N′-(1-Pyridin-2-ylmethylene)-2-furohydrazide and Its Application in Construction of a Highly Selective PVC-Based Membrane Sensor for La(III) Ions. ANAL. SCI. 22, 943–948 (2006). https://doi.org/10.2116/analsci.22.943

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  • DOI: https://doi.org/10.2116/analsci.22.943

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