Abstract
Results of some studies on the interaction of noble metals with quercetin (Q) and quercetin-5′-sulfonic acid (QSA), the compounds of flavonoid group, are presented. The reactions of chloride complexes of the metals: RuOHCl52–, PdCl42–, OsCl62–, PtCl62– and AuCl4– with both reagents were examined. The redox reactions of ruthenium and gold with Q and QSA have been identified. The reaction of the metals with both reagents results in the formation of the oxidized form of Q that exhibits maximum absorbance at 291 nm. Ruthenium and gold react with the examined reagents under similar conditions: 0.04 M HCl and 1 × 10–4 M Q (or QSA). The CH3OH + H2O (1:1) (Q) and pure aqueous (QSA) media can be used. The reaction of gold with Q is slow at room temperature. It can be accelerated by heating the solution being examined. The reaction proceeds significantly faster when the water-soluble sulfonic derivative of quercetin, quercetin-5′-sulfonic acid, is used as a reagent. The new species formed can make the basis of spectrophotometric methods for the determination of ruthenium and gold. The molar absorptivities at 291 nm are equal to 5.0 × 103 and 2.2 × 104 L mol–1 cm–1 for Ru and Au, respectively, independently of the reagent used. Some methods for the determination of the content of gold (0.04%) in a cosmetic cream were developed.
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Balcerzak, M., Kopacz, M., Kosiorek, A. et al. Spectrophotometric Studies of the Interaction of Noble Metals with Quercetin and Quercetin-5′-Sulfonic Acid. ANAL. SCI. 20, 1333–1337 (2004). https://doi.org/10.2116/analsci.20.1333
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DOI: https://doi.org/10.2116/analsci.20.1333