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Extraction Ability of 4-Benzoyl-3-phenyl-5-isoxazolone towards 4f-Ions into Ionic and Molecular Media

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Abstract

The distribution constants of 4-benzoyl-3-phenyl-5-isoxazolone (HPBI) and deprotonated one (PBI–) between hydrophobic ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C1C4im][Tf2N]) and aqueous phases were determined, together with the acid-dissociation constant of HPBI. The solvent extraction of three selected lanthanoid ions (La3+, Eu3+, and Lu3+) with HPBI from aqueous nitrate phase into [C1C4im][Tf2N] has been investigated. Application of the ionic liquid as the extracting phase greatly enhanced the extraction performance of HPBI for lanthanoid ions compared with that in the chloroform system. A slope analysis was conducted in order to compare the results of the solution 4f-ion coordination chemistry in ionic and molecular media. The composition of the extracted species was established to be anionic tetrakis entities, Ln(PBI)4–, for light, middle, and heavy lanthanoid ions in an ionic environment (Ln denotes lanthanoid ion). Nevertheless, the typical neutral chelate lanthanoid complexes of the type Ln(PBI)3 have been detected when the conventional molecular diluent chloroform was applied as an organic phase.

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Acknowledgments

The authors are grateful to the Matsumae International Foundation for the research fellowship grant 17G03. This work was financially supported by JSPS KAKENHI Grant Number 16K00619.

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Authors and Affiliations

  1. Advanced Science Research Center, Japan Atomic Energy Agency, Tokai, Ibaraki, 319-1195, Japan

    Maria Atanassova, Hiroyuki Okamura, Ayano Eguchi, Yuki Ueda, Tsuyoshi Sugita & Kojiro Shimojo

  2. Department of General and Inorganic Chemistry, University of Chemical Technology and Metallurg, 8 Kliment Okhridski blvd., 1756, Sofia, Bulgaria

    Maria Atanassova

  3. Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, 274-8510, Japan

    Ayano Eguchi

Authors
  1. Maria Atanassova
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  2. Hiroyuki Okamura
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  3. Ayano Eguchi
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  4. Yuki Ueda
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  5. Tsuyoshi Sugita
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  6. Kojiro Shimojo
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Correspondence to Maria Atanassova or Kojiro Shimojo.

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Atanassova, M., Okamura, H., Eguchi, A. et al. Extraction Ability of 4-Benzoyl-3-phenyl-5-isoxazolone towards 4f-Ions into Ionic and Molecular Media. ANAL. SCI. 34, 973–978 (2018). https://doi.org/10.2116/analsci.18P166

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  • DOI: https://doi.org/10.2116/analsci.18P166

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