Journal of the Ceramic Society of Japan
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
Mechanochemical Synthesis of the High Lithium Ion Conductive Amorphous Materials in the Systems Li2S-SiS2 and Li2S-SiS2-Li4SiO4
Hideyuki MORIMOTOHideki YAMASHITAMasahiro TATSUMISAGOTsutomu MINAMI
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2000 Volume 108 Issue 1254 Pages 128-131

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Abstract

Amorphous materials in the system xLi2S⋅(100-x)SiS2, where x ranged from 50 to 70mol%, and (100-y)(0.6Li2S⋅0.4SiS2)⋅yLi4SiO4, where y ranged from 0 to 10mol%, were synthesized by mechanical milling of crystalline starting materials, Li2S, SiS2 and Li4SiO4. At the compositions with large amounts of Li+ ions, a part of crystalline Li2S used as a starting material remained in the milled powder samples. It was found that the milled powder samples in both systems obtained by mechanical milling exhibited high conductivities in the order of 10-4S·cm-1 at room temperature in spite of the presence of small amounts of Li2S crystals. The conductivity values of the pelletized samples of xLi2S⋅(100-x)SiS2 powders maximized at the composition of about x=60. On the other hand, the conductivities in the composition range with y≤5 in the system (100-y)(0.6Li2S⋅0.4SiS2)⋅yLi4SiO4 were nearly the same values in the measured temperature range and higher by a half order of magnitude than those at the composition with y=10. The transport number of lithium ions of the amorphous materials after mechanically milled was almost unity and the potential window was wider than 10V at room temperature.

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