Journal of the Ceramic Society of Japan
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
Growth Isotherms of Liquid-Phase Sintered Silicon Nitride
Giuseppe PEZZOTTIHans-Joachim KLEEBEToshihiko NISHIDAGünter ZIEGLER
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1997 Volume 105 Issue 1224 Pages 638-640

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Abstract

Grain-growth data, collected after isothermal treatment of four Si3N4 materials, which contained different metal oxides as densification agents, are revisited. Diffusion-controlled Ostwald ripening mechanism is generally recognized to be mainly responsible for grain coarsening upon post-densification anneal. Emphasis is placed on rationalizing the grain-growth rate in terms of viscosity of the residual intergranular glass. A simple phenomenological equation is given that allows to predict the size of the Si3N4 grains upon annealing process. The pre-exponential coefficient and the exponent of the equation were determined using both grain-growth and intergranular viscosity data of a model Si3N4 system, which contained only pure SiO2 glass at grain boundaries. This general formulation allows to estimate the effective glass viscosity of Si3N4-based materials.

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