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Study on Preferential Selectivity of Nuclear Grade Resin Indion-223 towards some Bivalent Ions

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Abstract:

In the present paper attempts are made to understand the selectivity of nuclear grade cation exchange resin Indion-223 in H+ form towards Ca2+ and Mg2+ bivalent ions in the solution based on thermodynamic concept. It was observed that with rise in temperature the equilibrium constant K values for H+/Ca2+ uni-bivalet ion exchange reactions increases from 0.000397 to 0.000639. Similarly for H+/Mg2+ uni-bivalet ion exchange reactions the equilibrium constant K values increases from 0.000177 to 0.000333. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 38.92 and 51.46 kJ/ mol respectively. The difference in K values and enthalpy values were used to predict the selectivity behaviour of the resin towards the Ca2+ and Mg2+ bivalent ions in the solution. The thermodynamic concept of the present study can be applied to understand the selectivity behaviour of different nuclear as well as non-nuclear grade resins towards wide range of ionic species present in the exchanging liquid medium.

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Periodical:

International Letters of Chemistry, Physics and Astronomy (Volume 34)

Pages:

11-21

DOI:

https://doi.org/10.56431/p-4b9z2i

Citation:

Cite this paper

Online since:

May 2014

Authors:

Pravin U. Singare*, Akmal L. Khan Mohammed, N.N. Dixit

Keywords:

Bivalent Exchange Reactions, Cation Exchange, Enthalpy Change, Equilibrium Constant, Indion-223, Ionic Selectivity, Nuclear Grade Resins, Reaction Thermodynamics

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Creative Commons CC BY 4.0

* - Corresponding Author

References

[2010] 45. P.U. Singare, R.S. Lokhande , N.G. Samant , M.R. Dhatrak, Colloid Journal, 72(4), 538- 543(2010). 46. P.U. Singare, R.S. Lokhande, N.Samant, Natural Science, 1(2), 124-128 (2009). 47. R.S. Lokhande, P.U. Singare, M.H. Dole, Russ. J. Physical Chemistry, 83(13), 2313-2317

DOI: 10.1134/s1061933x10040150

Google Scholar

[2009] 48. P.U. Singare, R.S. Lokhande, T.S. Prabhavalkar, Bull. Chem. Soc. Ethiop., 22(3), 415- 421 (2008). 49. R.S. Lokhande, P.U. Singare, A.R. Kolte, Bull. Chem. Soc. Ethiop., 22(1), 107-114

DOI: 10.4314/bcse.v22i3.61226

Google Scholar

[2008] 50. R. S. Lokhande, P. U. Singare, A. B. Patil, Russian Journal of Physical Chemistry A, 81(12), 2059-2063 (2007). 51. P.U. Singare, R.S. Lokhande, M.B. Nadar, Oriental Journal of Chemistry, 25(4), 879-883

DOI: 10.1134/s0036024407120254

Google Scholar

[2009] 52. P.U. Singare, R.S. Lokhande, M.B. Nadar, Oriental Journal of Chemistry, 25(3), 755-758

Google Scholar

[2009] 53. P.U. Singare, R.S. Lokhande, M.B. Nadar, Oriental Journal of Chemistry, 25(3), 587-592

Google Scholar

[2009] 54. P.U. Singare, R.S. Lokhande, M.R. Dhatrak (M.D. Karad), Oriental Journal of Chemistry, 25(3), 687-693 (2009). 55. P.U. Singare, R.S. Lokhande, Rochelle D'Souza, Rasāyan Journal of Chemistry, 2(2), 507-511, (2009). 56. P.U. Singare, R.S. Lokhande, Rochelle D'Souza, Rasāyan Journal of Chemistry, 2(4), 941-945 (2009). 57. P.U. Singare, R.S. Lokhande, Rochelle D'Souza, Rasāyan Journal of Chemistry, 2(3), 645-648 (2009). 58. P.U. Singare, R.S. Lokhande, S.Y. Pimple, Rasāyan Journal of Chemistry, 2(1), 75-80

DOI: 10.4236/ojpc.2011.12007

Google Scholar

[2009] 59. P.U. Singare, R.S. Lokhande, S.Y. Pimple, Rasāyan Journal of Chemistry, 2(2), 315-321

Google Scholar

[2009] 60. P.U. Singare, R.S. Lokhande, S.Y. Pimple, Rasāyan Journal of Chemistry, 2(3), 617-621

Google Scholar

[2009] 61. P.U. Singare, R.S. Lokhande, P.C. Vartak, Rasāyan Journal of Chemistry, 2(1), 96-100

Google Scholar

[2009] 62. P.U. Singare, R.S. Lokhande, P.C. Vartak, Rasāyan Journal of Chemistry, 2(2), 491-496

Google Scholar

[2009] 63. P.U. Singare, R.S. Lokhande, P.C. Vartak, Rasāyan Journal of Chemistry, 2(4), 807-812

Google Scholar

[2009] 64. P.U. Singare, R.S. Lokhande, M.G. Patil, Rasāyan Journal of Chemistry, 2 (1), 114-119

Google Scholar

[2009] 65. P.U. Singare, R.S. Lokhande, M.G. Patil , Rasāyan Journal of Chemistry, 2(3), 566-571

Google Scholar

[2009] 66. P.U. Singare, R.S. Lokhande, M.G. Patil, Rasāyan Journal of Chemistry, 2(4), 861-864

Google Scholar

[2009] 67. P.U. Singare, R.S. Lokhande, N.P. Vanmali, Rasāyan Journal of Chemistry, 2(2), 280-284

Google Scholar

[2009] 68. P.U. Singare, R.S. Lokhande, N.P. Vanmali, Rasāyan Journal of Chemistry, 2(2), 280-284

Google Scholar

[2009] 69. P.U. Singare, R.S. Lokhande, N.P. Vanmali, Rasāyan Journal of Chemistry, 2(3), 593-597

Google Scholar

[2009] 70. P.U. Singare, R.S. Lokhande, N.P. Vanmali, Rasāyan Journal of Chemistry, 2(4), 901-906

Google Scholar

[2009] 71. P.U. Singare, R.S. Lokhande, V.Y. Pattebahadur, Int. J. Chem. Sci., 7(2), 797-804 (2009). 72. P.U. Singare, R.S. Lokhande, V.Y. Pattebahadur, Int. J.Chem. Sci., 7(2), 722-730 (2009). 73. P.U. Singare, R.S. Lokhande, V.Y. Pattebahadur, Int. J. Chem. Sci., 7(2), 1472-1478 (2009). 74. P.U. Singare, R.S. Lokhande, A.R. Kolte, M.H. Dole, P.Karthikeyan, S.A. Parab, Int. J. Chem. Sci., 6(4), 2172-2181 (2008). 75. R.S. Lokhande, P.U. Singare, P.Karthikeyan, Journal of Indian Council of Chemists, 25(2), 117-121 (2008). 76. R.S. Lokhande, P.U. Singare, Journal of Indian Council Chemists, 24(02), 73-77 (2007). 77. N.N. Andreev, Yu.I.Kuznetsov, Russian Journal of Physical Chemistry, 64, 1537 (1990). 78. A. Bhargava, C. Janardanan, Indian Journal of Chemistry, 36A, 624 (1997). 79. D. Muraviev, A. Gonzalo, M. Valiente, Anal. Chem., 67, 3028 (1995). 80. G.E. Boyd, F. Vaslow, S. Lindenbaum, J. Phys. Chem., 71, 2214 (1967). 81. J.F. Duncan, Aus.J.Chem.Soc., 8, 1 (1955). 82. G.E. Boyd, F. Vaslow, S. Lindenbaum, J.Phys.Chem., 68, 590 (1964). 83. A. Schwarz, G.E. Boyd, J. Phys. Chem., 69, 4268 (1965). 84. N.I. Gamayunov, Russ. J. Phys. Chem., 64, 1787 (1990). 85. G.E. Boyd, G.E. Myers, J. Phys. Chem., 60, 521 (1956). 86. O.D. Bonner, J. Phys. Chem., 59, 719 (1955). 87. O.D. Bonner, J. Phys. Chem., 58, 318 (1954). 88. S.Lindenbaum, C.F. Jumper, G.E. Boyd, J. Phys. Chem., 63, 1924 (1959). 89. K.A. Kraus, R.J. Raridon, J.Phys.Chem., 63, 1901 (1959). 90. O.D. Bonner, W.H. Payne, J.Phys.Chem., 58,183 (1954). 91. W.J. Argersinger, A.W. Davidson, J.Phys.Chem., 56, 92 (1952). 92. O.D. Bonner, R.R. Pruett, J.Phys.Chem., 63, 1420 (1959). 93. O.D. Bonner, F.L. Livingston, J.Phys.Chem., 60, 530 (1956). 94. O.D. Bonner, L.L. Smith, J.Phys.Chem., 61, 326 (1957). 95. O.D. Bonner, C.F. Jumper, O.C. Rogers, J. Phys. Chem., 62, 250 (1958). 96. O.D. Bonner, L.L. Smith, J.Phys.Chem., 61, 1614 (1957). 97. J.Kielland, J. Soc. Chem. Ind., (London) 54, 232 (1935). 98. A.P. Vanselow, J. Am. Chem. Soc., 54, 1307(1932). 99. G.L. Gaines (Jr.), H.C. Thomas, J.Chem.Phys., 21, 714 (1953). 100.K.A. Kraus, R.J. Raridon, D.L. Holcomb, Chromatogr. J., 3,178 (1960). 101. R.S. Lokhande, P.U. Singare, A.B. Patil, Russ. J. Phys. Chem. A, 81, 2059 (2007). 102. P.U. Singare, R.S. Lokhande, T.S. Prabhavalkar, Bull. Chem. Soc. Ethiop., 22, 415

Google Scholar

[2008] 103. R.S. Lokhande, P. U. Singare, J. Ind. Council Chem., 24, 73 (2007). 104. R.S. Lokhande, P.U. Singare, A.R. Kolte, Bull. Chem. Soc. Ethiop., 22,107 (2008). 105. K.G. Heumann, K. Baier, Chromatographia, 15, 701 (1982). 106. O.D. Bonner, G.Dickel, H.Brummer, Z. Physik. Chem., (Frankfurt), 25, 81 (1960). 107. G.L. Starobinet, V.S. Soldatov, A.A. Krylova, Russ. J. Phys. Chem., 41, 194 (1967). 108. Pravin U. Singare, Akmal L. Khan Mohammed, N. N. Dixit, International Letters of Chemistry, Physics and Astronomy 14(2) (2014) 127-135. 109. Pravin U. Singare, Akmal L. Khan Mohammed, N. N. Dixit, International Letters of Chemistry, Physics and Astronomy 14(2) (2014) 190-198. 110. Pravin U. Singare, Akmal L. Khan Mohammed, N. N. Dixit, International Letters of Chemistry, Physics and Astronomy 14(2) (2014) 199-207. 111. Pravin U. Singare, Akmal L. Khan Mohammed, N. N. Dixit, International Letters of Chemistry, Physics and Astronomy 14(2) (2014) 231-239. ( Received 08 May 2014; accepted 20 May 2014 ) -

Google Scholar

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