Skip to main content
Log in

Capillary method for measuring near-infrared spectra of microlitre volume liquids

  • Published:
Journal of Zhejiang University-SCIENCE A Aims and scope Submit manuscript

Abstract

The present study theoretically explored the feasibility of the capillary method for measuring near-infrared (NIR) spectra of liquid or solution samples with microlitre volume, which was proposed in our previous studies. Lambert-Beer absorbance rule was applied to establish a model for the integral absorbance of capillary, which was then implemented in numerical analyses of the effects of capillary on various spectral features and dynamic range of absorption measurement. The theoretical speculations indicated that the capillary method might be used in NIR spectroscopy, which was further supported by the empirical data collected from our experiments by comparison between capillary NIR spectra of several organic solvents and cuvette cell NIR spectra.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Dou, X.M., Yuan, B., Zhao, H.Y., Yin, G.Z., Ozaki, Y., 2004. Generalized two-dimensional correlation spectroscopy: theory and applications in analytical field. Science in China Ser. B, 47(3):257–266. [doi:10.1360/03yb0085]

    Article  Google Scholar 

  • Hirschfeld, T., 1985. Lens and wedge absorption cells for FT-IR spectroscopy. Applied Spectroscopy, 39(3):426–430. [doi:10.1366/0003702854248494]

    Article  MathSciNet  Google Scholar 

  • Katsumoto, Y., Adachi, D., Sato, H., Ozaki, Y., 2002. Usefulness of a curve fitting method in the analysis of overlapping overtones and combinations of CH stretching modes. Journal of Near-Infrared Spectroscopy, 10:85–91.

    Article  Google Scholar 

  • Maeda, H., Wang, Y., Ozaki, Y., Suzuki, M., Czarnecki, M.A., Iwahashi, M., 1999. A near-infrared study of hydrogen bonds in alcohols—comparison of chemometrics and spectral analysis. Chemometrics and Intelligent Laboratory Systems, 45(1–2):121–130. [doi:10.1016/S0169-7439(98)00096-3]

    Article  Google Scholar 

  • Murayama, K., Yuan, B., Tomida, M., Ozaki, Y., Era, S., 2003a. Capillary Near-infrared Spectroscopy for Microliter Solutions: Basic and Bio-medical Application. 11th International Conference on Near Infrared Spectroscopy, Cordoba, Spain.

  • Murayama, K., Yuan, B., Ozaki, Y., Tomida, M., Era, S., 2003b. Near-infrared spectroscopy for liquids of microliter volume using capillaries with wall transmission. Analyst, 128(2):957–959. [doi:10.1039/b301142a]

    Article  Google Scholar 

  • Noda, I., 2000. Determination of two-dimensional correlation spectra using the Hilbert transform. Applied Spectroscopy, 54(7):994–999. [doi:10.1366/0003702001950472]

    Article  Google Scholar 

  • Ozaki, Y., Šasic, S., Jiang, J.H., 2001. How can we unravel complicated near infrared spectra?—Recent progress in spectral analysis methods for resolution enhancement and band assignments in the near infrared region. Journal of Near-Infrared Spectroscopy, 9:63–95.

    Article  Google Scholar 

  • Scarff, M., Arnold, S.A., Harvey, L.M., McNeil, B., 2006. Near-infrared spectroscopy for bioprocess monitoring and control: current status and future trends. Critical Reviews in Biotechnology, 26(1):17–39. [doi:10.1080/07388550500513677]

    Article  Google Scholar 

  • Siesler, H.W., Ozaki, Y., Kawata, S., Heise, H.W., 2002. Near-infrared Spectroscopy: Principles, Instruments, Applications. Wiley-VCH, Weinheim, p. 75–84, 179–269.

    Google Scholar 

  • van der Greef, J., Smilde, A.K., 2005. Symbiosis of chemometrics and metabolomics: past, present, and future. Journal of Chemometrics, 19(5–7):376–386. [doi:10.1002/cem.941]

    Article  Google Scholar 

  • Ward, K.R., Ivatury, R.R., Barbee, R.W., Terner, J., Pittman, R., Torres, I.P., Spiess, B., 2006. Near-infrared spectroscopy for evaluation of the trauma patient: A technology review. Resuscitation, 68(1):27–44. [doi:10.1016/j.resuscitation.2005.06.022]

    Article  Google Scholar 

  • Wu, X.H., Chen, D.Z., 2004. Recent development of non-linear patrital least squares in chemometrics. Chinese Journal of Analytical Chemistry, 32(4):534–540 (in Chinese).

    Google Scholar 

  • Yuan, B., Dou, X.M., 2004. Near-infrared spectral studies of hydrogen-bond in water-methanol mixtures. Spectroscopy and Spectral Analysis, 24(11):1319–1322 (in Chinese).

    Google Scholar 

  • Yuan, B., Murayama, K., Wu, Y., Tsenkova, R., Dou, X.M., Era, S., Ozaki, Y., 2003. Temperature-dependent near-infrared spectra of bovine serum albumin in aqueous solution: spectral analysis by principal component analysis and evolving factor analysis. Applied Spectroscopy, 57(10):1223–1229. [doi:10.1366/000370203769699072]

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yuan, B., Koichi, M. Capillary method for measuring near-infrared spectra of microlitre volume liquids. J. Zhejiang Univ. - Sci. A 8, 171–175 (2007). https://doi.org/10.1631/jzus.2007.A0171

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1631/jzus.2007.A0171

Key words

CLC number

Navigation