The performance of online algorithms for the bin packing problem is usually measured by the asymptotic approximation ratio. However, even if an online algorithm is explicitly described, it is in general difficult to obtain the exact value of the asymptotic approximation ratio. In this paper we show a theorem that gives the exact value of the asymptotic approximation ratio in a closed form when the item sizes and the online algorithm satisfy some conditions. Moreover, we demonstrate that our theorem serves as a powerful tool for the design of online algorithms combined with mathematical optimization.