In order to realize better understanding of influential order sequences of surrounding atmospheres on break arc durations of electrical contacts in DC load conditions, a quantitative mathematical model, which aims to indicate dependences of break arc durations on several gas parameters such as molecular mass, viscosity, specific heat capacity, thermal conductivity, electro-negativity, and ionization potential, was analyzed. Break arc durations of AgCdO contact pairs were measured in several kinds of surrounding atmospheres (N₂, Ar, He, air, O₂ and CO₂) under different DC voltage and current conditions, and data fitting processes were conducted. As a result, a candidate mathematical model was established, which could indicate possible influential order sequences of surrounding atmospheres on break arc durations in the range of the tested conditions.