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The use of multinuclear solid state NMR for the characterization of siloxane-oxide hybrid nanocomposites

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Abstract

The objective of this paper is to review various solid state NMR techniques that have been, or can be used for the structural characterization of siloxane—oxide hybrid systems prepared by sol-gel process, and to discuss the type of information they provide, as well as their limitations. More precisely, this paper focuses on NMR techniques to probe and quantify the different types of oxo-bridges (M–O–M of oxide network, Si–O–Si of siloxane chains and Si–O–M siloxane–MxOy interface) in siloxane-oxide nanocomposites prepared through hydrolysis and condensation of organosilanes and M(OR)n alkoxides. In addition the influence of the functionality of the silicon alkoxides and the nature of the MxOy oxides on the extent of the Si-O-M interface will be examined.

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Acknowledgments

The authors are grateful to M. Nacken and D. Hoebbel (INM, Saarbrücken) for the synthesis of the cyclic titanodiphenylsiloxane and to D. Padro and R. Dupree (University of Warwick) for their help in recording the 47,49Ti static NMR spectrum.

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Authors and Affiliations

  1. Chimie de la Matière Condensée, Université Pierre et Marie Curie, 4 place Jussieu, 75252, Paris Cedex 05, France

    Christel Gervais, Beatriz Julián, Florence Babonneau & Clément Sanchez

  2. Departamento de Química Inorgánica y Orgánica, Campus de Riu Sec, Universitat Jaume I, 12071, Castellón, Spain

    Beatriz Julián, Eloisa Cordoncillo & Purificación Escribano

  3. Department of Physics, University of Warwick, Coventry, CV4 7AL, U.K.

    Mark E. Smith

Authors
  1. Christel Gervais
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  2. Beatriz Julián
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  4. Purificación Escribano
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  5. Mark E. Smith
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  6. Florence Babonneau
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  7. Clément Sanchez
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Gervais, C., Julián, B., Cordoncillo, E. et al. The use of multinuclear solid state NMR for the characterization of siloxane-oxide hybrid nanocomposites. MRS Online Proceedings Library 847, 385–396 (2004). https://doi.org/10.1557/PROC-847-EE6.2

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