Abstract
High quality CdS thin films made with ultrasonic agitation during chemical bath deposition were investigated. The change in band gap and variation of atomic stacking during the film growth was observed as a function of bath pH. The band gap of as-deposited thin films of CdS was found to be between 2.26 eV and 2.50 eV, the highest being observed when the pH was 9.0. The transition from cubic (β-CdS) to hexagonal (a-CdS) was observed with decreasing pH. The lattice parameters of CdCl2 treated CdS were found to be a = 0.414 nm and c = 0.672 nm. Calculations based on the Sherrer formula showed significant grain growth after annealing with CdCl2. No apparent effect of ultrasonication on crystalline structure of CdS was seen in this method, although ultrasonication was noted to produce films with a higher quality optical surface. A maximum bath temperature was fixed at 70°C in order to suppress the rate of homogeneous reaction and minimise the evaporation of ammonia from the chemical bath.
Similar content being viewed by others
References
M.A. Contreras, B. Egaas, K. Ramanathan, J. Hiltner, A. Swartzlander, F. Hasoon, R. Noufi, Prog. Photovoltaics:Res.Appl. 7 (1999) 331.
A. Catalano, Solar Energy Materilas and Solar Cells 41/42(1996)205.
R.B. Hall and J.D. Meakin, Thin Solid Films, 63, 1979, p.203.
G. Sasikala, P. Thilakan, C. Subramanian, Solar Energy Materials & Solar Cells 62 (2000) 275.
Giedrius Laukaitis, Seppo Lindroos, Sigitas Tamulevicius, Markku Leskela, Applied Surface Science 185, (2001)134.
Paul O'Brien, Tahir Saeed, Journal of Crystal growth 158 (1996) 497.
F.S. Hasoon, M.M. Al-Jassim, A. Swartzelander, P. Sheidon, A.A.J. Al-Douri, and A.A. Alnajjar, 26th IEEE photovoltaic Specialists Conference, September 29- Octorber 3, 1997, Anaheim, California.
N.B. Chaure, S. Bordas, A.P. Samantilleke, S.N. Chaure, J. Haigh, I.M. Dharmadasa, Thin Solid Films 437 (2003) 10.
Ting L. Chu and Shirley S. Chu, Solid-State Electronics 38 (1995) 533.
Jun Young Choi, Kang-Jin Kim, Ji-Beom Yoo, Donghwan Kim, Solar Energy 64 (1998) 41.
A. Cortes, H. Gomez, R.E. Marotti, G. Riveros, E.A. Dalchiele, Solar Energy Materials & Solar Cells 82 (2004) 21.
K. S. Ramaiah, R.D. Pilkington, A.E. Hill, R.D. Tomlinson, A.K. Bhatnagar, Materials Chemistry and Physics 68 (2001) 22.
T.L. Chu, S.S. Chu, N. Schultz, C. Wang, C.Q. Wu, J. Electrochem. Soc. 139 (1992) 2443.
H.R. Moutinho, D. Albin, Y. Yan, R.G. Dhere, X. Li, C. Perkins, C.S. Jiang, B. To, M.M. Al-Jassim, Thin Solid Films 436 (2003) 175.
P.N. Gibson, M.E. Ozsan, D. Lincot, P. Cowache, D. Summa, Thin Solid Films 361–362 (2000) 34.
Acknowledgments
This work was funded by the EPSRC under grant ER/R50585/01
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ketipearachchi, U.S., Lane, D.W., Rogers, K.D. et al. Bath pH Dependence on the Structural and Optical Properties of Chemical Bath Deposited CdS Thin Films. MRS Online Proceedings Library 836, L5.35 (2004). https://doi.org/10.1557/PROC-836-L5.35
Published:
DOI: https://doi.org/10.1557/PROC-836-L5.35