Skip to main content
Log in

The Role of Nitrogen-Induced Localization and Defects in InGaAsN (≈ 2% N): Comparison of InGaAsN Grown by Molecular Beam Epitaxy and Metal-Organic Chemical Vapor Deposition

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

Nitrogen vibrational mode spectra, Hall mobilities, and minority carrier diffusion lengths are examined for InGaAsN (≈ 1.1 eV bandgap) grown by molecular beam epitaxy (MBE) and metal-organic chemical vapor deposition (MOCVD). Independent of growth technique, annealing promotes the formation of In-N bonding, and lateral carrier transport is limited by large scale (Ęmean free path ) material inhomogeneities. Comparing solar cell quantum efficiencies for devices grown by MBE and MOCVD, we find significant electron diffusion in the MBE material (reversed from the hole diffusion occurring in MOCVD material), and minority carrier diffusion in InGaAsN cannot be explained by a “universal”, nitrogen-related defect.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Weyers, M. Sato, and H. Ando, Jpn. J. Appl Phys. 31 Pt. 2, 853 (1992).

    Article  Google Scholar 

  2. W. G. Bi and C. W. Tu, Appl. Phys. Lett. 70, 1608 (1997).

    Article  CAS  Google Scholar 

  3. M. Kondow, T. Kitatani, S. Nakatsuka, M. C. Larson, K. Nakahara, Y. Yazawa, and M. Okai, IEEE J. of Selected Topics in Quant. Elect. 3, 719 (1997), and references therein.

    Article  CAS  Google Scholar 

  4. K D. Choquette, J. F. Klem, A.J. Fischer, O. Blum, A. A. Allerman, I.J. Fritz, S. R. Kurtz, W. G. Breiland, R. M. Sieg, K. M. Geib, J. W. Scott, and R. L. Naone, Electron. Lett. 36, 1388 (2000).

    Article  CAS  Google Scholar 

  5. Sarah R. Kurtz, D. Myers, and J. M. Olsen, Proc. 26th IEEE Photovoltaics Spec. Conf. (IEEE, New York, 1997), p. 875.

    Google Scholar 

  6. Steven R. Kurtz, A. A. Allerman, E. D. Jones, J. M. Gee, J. J. Banas, and B. E. Hammons, Appl. Phys. Lett. 74, 729 (1999).

    Article  CAS  Google Scholar 

  7. E. V. K. Rao, A. Ougazzaden, Y. Le Bellego, and M. Juhel,, Appl. Phys. Lett. 72, 1409 (1998).

    Article  CAS  Google Scholar 

  8. V. Riede, H. Neumann, H. Sobotta, R. Schwabe, W. Siefert, and S. Schwetlick, Phys. Stat. Sol.(a) 93, K151 (1986).

    Article  CAS  Google Scholar 

  9. Sarah Kurtz, J. Webb, L. Gedvilas, D. Friedman, J. Geisz, J. Olsen, R. King, D. Joslin, and N. Karam, Appl. Phys. Lett. 78, 748 (2001).

    Article  CAS  Google Scholar 

  10. Steven R. Kurtz, A. A. Allerman, C. H. Seager, R. M. Sieg, and E. D. Jones, Appl. Phys. Lett. 77, 400 (2000).

    Article  CAS  Google Scholar 

  11. C. Skierbiszewski, P. Perlin, P. Wisniewski, T. Suski, W. Walukiewicz, W. Shan, J. W. Ager, E. E. Haller, J. F. Geisz, D. J. Friedman, J. M. Olsen, and S. R. Kurtz, Phys. Stat. Sol.(b) 216, 135 (1999).

    Article  CAS  Google Scholar 

  12. N. F. Mott and E. A. Davis, Electronic Processes in Non-Crystalline Materials, 2nd Ed., Clarendon Press, Oxford, 1979

    Google Scholar 

  13. V. G. Karpov, A. Ya. Shik, and B. I. Shklovski, Sov. Phys. Semi. 16, 901 (1982).

    Google Scholar 

  14. H. Paul Maruska, Amal K. Ghosh, Albert Rose, and Tom Feng, Appl. Phys. Lett. 36, 381 (1980).

    Article  CAS  Google Scholar 

  15. H. A. McKay, R. M. Feenstra, T. Schmidtling, and U. W. Pohl, Appl. Phys. Lett. 78, 82 (2001).

    Article  CAS  Google Scholar 

  16. H. Lyeo, C. K. Shih, A. A. Allerman, S. R. Kurtz, and E. D. Jones, to be published

  17. Sylvia G. Spruytte, Christopher W. Coldren, James S. Harris, William Wampler, Peter Krispin, Klaus Ploog, and Michael C. Larson, J. Appl. Phys. 89, 4401 (2001).

    Article  CAS  Google Scholar 

  18. PC1D Version 5.2, Copyright P. A. Basore and D. A. Clugston, Univ. of New South Wales, Aus. (1998).

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kurtz, S.R., Allerman, A.A., Klem, J.F. et al. The Role of Nitrogen-Induced Localization and Defects in InGaAsN (≈ 2% N): Comparison of InGaAsN Grown by Molecular Beam Epitaxy and Metal-Organic Chemical Vapor Deposition. MRS Online Proceedings Library 692, 171 (2001). https://doi.org/10.1557/PROC-692-H1.7.1

Download citation

  • Published:

  • DOI: https://doi.org/10.1557/PROC-692-H1.7.1

Navigation