Abstract
The mechanical properties of cement-based materials must be controlled by the microstructure, pore geometry and chemical composition of the cement, by the properties of the aggregate, and by the nature of the cement-aggregate bond. While the precise form of the strength vs. microstructure relationship is as yet only imperfectly understood, enough is known to permit us to predict what alterations in the microstructure are required for the production of materials with very high strengths. There are also techniques available for reducing the brittleness that is often a characteristic of high-strength materials. The present paper presents an overview of the strength vs. microstructure relationships that can be used to predict the properties of high strength cement-based materials, and a brief review of some of the methods for achieving high strengths.
Similar content being viewed by others
References
A.W. Skempton, Trans. Newcoraen Society, XXXV, 117 (1962–1963).
S.P. Shah (ed.), High Strength Concrete, Proceedings of a Workshop Held at the University of Illinois at Chicago Circle, 1979.
S. Diamond, in Ref. 2, p. 36.
G. Idorn, in Proceedings of the Fifth International Symposium on the Chemistry of Cement (The Cement Association of Japan, Tokyo, 1968) Vol. III, p. 411.
S. Brunauer, Am. Sci., 50, 210 (1962).
T.C. Powers, in Proceedings of the Fourth International Symposium on the Chemistry of Cement (National Bureau of Standards, Washington, D.C., 1960), Vol. II, p. 577.
R.F. Feldman and P.J. Sereda, Mat. et Constr. 1, 509 (1968).
R.F. Feldman and P.J. Sereda, Eng. J. (Canada) 53, 53 (1970).
V.S. Ramachandran, R.F. Feldman and J.J. Beaudoin, Concrete Science (Heyden & Son Ltd., London, 1981).
H.F.W. Taylor, in Cement Production and use (Publication No. 79-08, Engineering Foundation, New York, 1979), p. 107.
J.F. Young, in Z.P. Bazant and F.H. Wittmann (eds.), Creepand Shrinkage in Concrete Structures (John Wiley & Sons Ltd., 1982), p. 3.
F.H. Wittmann, in Creepand Shrinkage in Concrete Structures (John Wiley & Sons Ltd., 1982), p. 129.
Lucretius, Onthe Nature of the Universe (tr. by R. Latham), (Penguin Books, Harmondsworth, England, 1951), p. 43.
R. Feret, Bull. Soc. Encour. Ind. Natn., Paris, 1604 (1897).
T.C. Powers and T.L. Brownyard, Bulletin22, (Portland Cement Association, Skokie, Illinois, 1948).
M. Yu. Bal’shin, Doklady Aka. Nauk. S.S.S.R., 67, 831 (1949).
E. Ryshkewitch, J. Amer. Ceram. Soc., 36, 65 (1953).
K.K. Schiller, Brit. J. Appl. Phys., 11, 338 (1960).
S. Mindess, J. Amer. Ceram. Soc., 53, 621 (1970).
J. Jambor, in Proceedings of the International Conference on Pore Structure and Properties of Materials (RILEM/IUPAC, Prague, Czechoslovakia, 1973), Vol. II, D75.
Y. Zaitsev, in 7th International Congress on the Chemistry of Cement (Paris, 1980), Vol. III, p. VI-176.
P.J. Sereda, R.F. Feldman and V.S. Ramachandran, in 7th International Congress on the Chemistry of Cement (Paris, 1980), Vol. I, p. VI-1/3.
J.J. Beaudoin, Cem. Concr. Res., 12, 705 (1982).
A.A. Griffith, Phil. Trans. R. Soc., A221, 163 (1920).
S. Mindess, in F.H. Wittmann (ed.), Frature Mechanics of Concrete (Elsevier Scientific Publications Company, Amsterdam, 1983), p. 1.
J.D. Birchall, A.J. Howard and K. Kendall, Nature, 289, 388 (1981).
J.D. Birchall, A.J. Howard and K. Kendall, Proc. Brit. Ceram. Soc., 32, 25 (1982).
K. Kendall, A.J. Howard and J.D. Birchall, in Technology in the 1990s: Developments in Hydraulic Cements (The Royal Society, London, 1983), p. 139.
J.J. Beaudoin, Cem. Concr. Res., 13, 81 (1983).
N. McN. Alford, Cem. Concr. Res., 11, 605 (1981).
N. McN. Alford, G.W. Groves and D.D. Double, Cem. Concr. Res., 12, 349 (1982).
S. Mindess, In F.H. Wittmann (ed.), Fracture Mechanics of Concrete (Elsevier Scientific Publishing Company, Amsterdam, 1983), p. 534.
F.V. Lawrence, Jr., J.F. Young and R.L. Berger, Cem. Concr. Res., 7, 369 (1977).
J. Jambor, in Hydraulic Cement Pastest Their Structure and Properties (Cement and Concrete Association, Wexham Springs, 1976), p. 175.
J. Jambor, in Proceedings of the Sixth International Congress on the Chemistry of Cement (Moscow, 1974), preprint.
L. Hjorth, in Nordic Concrete Research Publications No. 1 (The Nordic Concrete Federation, Oslo, 1982), p. 901.
R.F. Feldman and J.J. Beaudoin, Cem. Concr. Res., 6, 389 (1976).
H.F.W. Taylor, Cera. Concr. Res., 7, 465 (1977).
J.M. Crennan, S.A.S. El-Hemaly and H.F.W. Taylor, Cem. Concr. Res., 7, 495 (1977).
D.O. Woolf, in Significance of Tests and Properties of Concrete and Concrete-Making Materials (ASTM STP 169-A, American Society for Testing and Materials, Philadelphia, 1966), p. 462.
R.C. Meininger, in Significance of Tests and Properties of Concrete and Concrete-Making Materials (ASTM STP 169-B, American Society for Testing and Materials, Philadelphia, 1978), p. 657.
F.H. Wittmann, in Ref. 2, p. 8.
G. Fagerlund, in Proceedings of the International Symposium on Pore Structure and Properties of Materials (RILEM/IUPAC, Prague, 1973), p. D51.
T.T.C. Hsu, F.O. Slate, G.M. Sturraan and G. Winter, J. Amer. Concr. Inst., 60, 209 (1963).
K.M. Alexander, J. Wardlaw and D.J. Gilbert, in A.E. Brooks and K. Newman (eds.), The Structure of Concrete (Cement and Concrete Association, London, 1968), p. 59.
S.P. Shah, in Ref. 2, p. 1.
K.H. Gerstle, in Ref. 2, p. 43.
S. Ahmad and S.P. Shah, in Proceedings of the CSCE-ASCE-ACI-CEB International Symposium on Nonlinear Design of Concrete Structures (University of Waterloo, Waterloo, Ontario, Canada, 1979).
A.E. Naaman, in Ref. 2, p. 194.
S.E. Coleman, M. Maage and S. Diamond, Final Report, Joint Highway Research Project FWHA/lN/JHRP-82/2 (Purdue University, West Lafayette, Indiana, 1982), p. 281.
G. Tognon, P. Ursella and G. Coppetti, J. Amer. Concr. Inst., 77, 171 (1980).
P.T. Wang, S.P. Shah and A.E. Naaman, J. Struct. Div., ASCE, 104, 1761 (1978).
S. Mindess, The Relationship Between the Strength and Microstructure of Autoclaved Calcium Silicate Materials (Ph.D. Thesis, Stanford University, Stanford, California, 1970).
M. Yudenfreund, I. Odler and S. Brunauer, Cem. Concr. Res., 2, 313 (1972).
M. Yudenfreund, J. Skalny, R. Sh. Mikhail and S. Brunauer, Cem. Concr. Res., 2, 331 (1972).
M. Yudenfreund, K.M. Hanna, J. Skalny, I. Odler and S. Brunauer, Cem. Concr. Res., 2, 731 (1972).
D.M. Roy, G.R. Gouda and A. Bobrowsky, Cem. Concr. Res., 2, 349 (1972).
D.M. Roy and G.R. Gouda, J. Amer. Ceram. Soc., 56, 549 (1973).
D.M. Roy and G.R. Gouda, in Proceedings of the Sixth International Congress on the Chemistry of Cement (Moscow, 1974), preprint paper No. 92.
G.J. Verbeck and R.A. Helmuth, in Proceedings of the Fifth International Symposium on the Chemistry of Cement (The Cement Association of Japan, Tokyo, 1968), Vol. III, p. 1.
D. Manning and B. Hope, Cem. Concr. Res., 1, 631 (1971).
T. Fukuchi and Y. Ohama, in Polymers in Concrete (SP-58, American Concrete Institute, Detroit, Michigan, 1978), p. 215.
S. Mindess, in F.H. Wittmann (ed.), Fracture Mechanics of Concrete (Elsevier, Amsterdam, 1983), p. 481.
N. Thaulow, Cem. Concr. Res., 4, 269 (1974).
L. Hjorth, in Technology in the 1990s; Developments in Hydraulic Cements (The Royal Society, London, 1983), p. 167.
D.J. Hannant, D.C. Hughes and A. Kelly, in Technolgy in the 1990s; Developments in Hydraulic Cements (The Royal Society, London, 1983), p. 175.
A.J. Majumdar and V. Laws, in Technology in the 1990s; Developments in Hydraulic Cements (The Royal Society, London, 1983), p. 191.
R.J. Gray, J. Mater. Sci., 19, 861 (1984).
R.J. Gray, J. Mater. Sci., 19, 1680 (1984).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Mindess, S. Relationships between Strength and Microstructure for Cement-Based Materials: An Overview. MRS Online Proceedings Library 42, 53–68 (1984). https://doi.org/10.1557/PROC-42-53
Published:
Issue Date:
DOI: https://doi.org/10.1557/PROC-42-53