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Transport Properties of the Intercalated Layered Cathode Materials: LiXMo2O4.

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Abstract

The mixed conducting LixMO2O4 system was shown to exhibit a high energy density (530Wh/kg) and average voltage (3.1V), suggesting that it would be a good candidate for a cathode in a Li-anode secondary battery. The transport properties of these oxide materials were then investigated by solid state 7Li NMR, dc and ac electrical measurements. The following phases are emphasized in this study: Li1.3MO2O4, Li2MO2O4, and the hydrated phase Li0.5 (H2O)1.3MO2O4.

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References

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Acknowledgement

The authors wish to thank Professor G. Sigel, Rutgers University, and Dr J.H. Wernick, Bell Communication Research, for supporting this project, as well as Dr P. Barboux and E. Vogel, Bell Communication Research, for technical discussions.

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Authors and Affiliations

  1. Ceramics Department, Rutgers Univ., Piscataway, NJ, 08855, USA

    S. Colson, S. Szu & L.C. Klein

  2. Bellcore,331, Newman Springs Rd., Red Bank, NJ, 07701, USA

    J.M. Tarascon

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  1. S. Colson
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  2. J.M. Tarascon
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  3. S. Szu
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  4. L.C. Klein
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Colson, S., Tarascon, J., Szu, S. et al. Transport Properties of the Intercalated Layered Cathode Materials: LiXMo2O4.. MRS Online Proceedings Library 210, 405–410 (1990). https://doi.org/10.1557/PROC-210-405

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  • DOI: https://doi.org/10.1557/PROC-210-405

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