Abstract
Thin films of ZnO co-doped with lithium and phosphorus were deposited on sapphire substrates by RF magnetron sputtering. The films were sequentially deposited from ultra pure ZnO and Li3PO4 solid targets. Post deposition annealing was carried using a rapid thermal processor in O2 and N2 at temperatures ranging from 500 °C to 1000 °C for 3 min. Analyses performed using low temperature photoluminescence spectroscopy measurements reveal luminescence peaks at 3.359, 3.306, 3.245 eV for the co-doped samples. The x-ray diffraction 2θ-scans for all the films showed a single peak at about 34.4° with full width at half maximum of about 0.17°. Hall Effect measurements revealed conductivities that change from p-type to n-type over time.
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Oder, T.N., Smith, A., Freeman, M. et al. Properties of Sputter Deposited ZnO Films Co-doped with Lithium and Phosphorus. MRS Online Proceedings Library 1494, 77–82 (2012). https://doi.org/10.1557/opl.2013.4
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DOI: https://doi.org/10.1557/opl.2013.4