Abstract
We present the development of highly efficient merocyanine solar cells at the example of the dye MD376. Due to their unique processing flexibility, merocyanines have been applied in solution- as well as vacuum-processed organic photovoltaics. In fully vapor-deposited MD376 single cells, efficiencies up to 5.0% were achieved while maintaining a rather simple device setup with only four organic layers. Moreover, MD376 has been successfully introduced to vacuum-processed tandem cell structures, reporting a high open-circuit voltage of 2.1 V.
Similar content being viewed by others
References
Z. He, C. Zhong, X. Huang, W.-Y. Wong, H. Wu, L. Chen, S. Su, and Y. Cao, Adv. Mater., DOI: 10.1002/adma.201103006 (2011).
M. Riede, C. Uhrich, J. Widmer, R. Timmreck, D. Wynands, G. Schwartz, W.-M. Gnehr, D. Hildebrandt, A. Weiss, J. Hwang, S. Sudharka, P. Erk, M. Pfeiffer, and K. Leo, Adv. Funct. Mater. 21, 3019–3028 (2011).
V. Steinmann, N. M. Kronenberg, M. R. Lenze, S. M. Graf, D. Hertel, K. Meerholz, H. Bürckstümmer, E. V. Tulyakova, and F. Würthner, Adv. Energy Mater. 1, 888–893 (2011).
L.-Y. Lin, Y.-H. Chen, Z.-Y. Huang, H.-W. Lin, S.-H. Chou, F. Lin, C.-W. Chen, Y.-H. Liu, and K.-T. Wong, J. Am. Chem. Soc., DOI: 10.1021/ja205126t (2011).
Y. Sun, G. C. Welch, W. L. Leong, C. J. Takacs, G. C. Bazan, and A. J. Heeger, Nature Mater., DOI: 10.1038/NMAT3160 (2011).
F. Würthner, R. Wortmann, and K. Meerholz, ChemPhysChem 3, 17–31 (2002).
S. Köber, M. Salvador, K. Meerholz, Adv. Mater., 23, 4725–4763 (2011).
H. Bürckstümmer, N. M. Kronenberg, M. Gsänger, M. Stolte, K. Meerholz, and F. Würthner, J. Mater. Chem. 20, 240–243 (2010).
N. M. Kronenberg, M. Deppisch, F. Würthner, H. W. A. Lademann, K. Deing, and K. Meerholz, Chem. Commun., 6489-91 (2008).
N. M. Kronenberg, V. Steinmann, H. Bürckstümmer, J. Hwang, D. Hertel, F. Würthner, and K. Meerholz, Adv. Mater. 22, 4193–4197 (2010).
V. Steinmann, N. M. Kronenberg, M. R. Lenze, S. M. Graf, D. Hertel, H. Bürckstümmer, F. Würthner, and K. Meerholz, Appl. Phys. Lett. 99, 193306 (2011).
H. Frohne, S. E. Shaheen, C. J. Brabec, D. C. Müller, N. S. Sariciftci, and K. Meerholz, ChemPhysChem 3, 795–799 (2002).
D. W. Zhao, X. W. Sun, C. Y. Jiang, A. K. K. Kyaw, G. Q. Lo, and D. L. Kwong, Appl. Phys. Lett. 93, 083305 (2008).
T. Ameri, G. Dennler, C. Lungenschmied, and C. J. Brabec, Energ. Environ. Sci. 2, 347 (2009).
A. Hadipour, B. de Boer, and P. W. M. Blom, Org. Electron. 9, 617–624 (2008).
Acknowledgments
The authors thank Dr. Dirk Hertel for fruitful, scientific discussions. For financial support, the authors thank the Deutsche Forschungsgemeinschaft (DFG, project SP1355). Further, we would like to acknowledge the funding through the Federal Ministry of Education and Research (BMBF) of Germany through the OPEG project. We also thank the BASF SE for providing some of the material.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Steinmann, V., Kronenberg, N.M., Lenze, M.R. et al. Towards highly efficient solar cells based on merocyanine dyes. MRS Online Proceedings Library 1390, 00442 (2012). https://doi.org/10.1557/opl.2012.442
Published:
DOI: https://doi.org/10.1557/opl.2012.442