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References

  1. H.M. McConnell, in Proc. R.A. Welch Found. Chem. Res., Vol. 11 (1967) p. 144.

    Google Scholar 

  2. H.M. McConnell, J. Chem. Phys. 39 (1963) p. 1910.

    Article  CAS  Google Scholar 

  3. A. Izuoka, S. Murata, T. Sugawara, and H. Iwamura, J. Am. Chem. Soc. 107 (1985) p. 1786; 109 (1987) p. 2631.

    Article  CAS  Google Scholar 

  4. Recently it was pointed out that a factor other than this mechanism might also be taken into account for the experimentally observed couplings for these isomers: M. Deumal, J.J. Novoa, M.J. Beapark, P. Celani, M. Olivucci, and M.A. Robb, J. Phys. Chem. A 102 (1998) p. 8404.

    Article  CAS  Google Scholar 

  5. A.R. Forrester, J.M. Hay, and R.H. Thompson, Organic Chemistry of Stable Free Radicals (Academic Press, London, 1968)

    Google Scholar 

  6. G.D. Mendenhall, D. Griller, and K.U. Ingold, Chem. Br. 10 (1975) p. 284

    Google Scholar 

  7. D. Griller and K.U. Ingold, Acc. Chem. Res. 9 (1976) p. 13 and references therein.

    Article  CAS  Google Scholar 

  8. M. Ballester, Adv. Phys. Org. Chem. 25 (1989) p. 267

    CAS  Google Scholar 

  9. O. Armet, J. Veciana, C. Rovira, J. Riera, J. Castañer, E. Molins, J. Rius, C. Miravitlles, S. Olivella, and J. Brichfeus, J. Phys. Chem. 91 (1987) p. 5608.

    Article  CAS  Google Scholar 

  10. For a compendium of the most relevant characteristics of magnetic materials based on different organic compounds, see P.M. Lathi, ed., Magnetic Properties of Organic Materials (Marcel Dekker, New York, 1999).

    Google Scholar 

  11. A.I. Kitaigorodskii, Molecular Crystals and Molecules (Academic Press, London, 1973).

    Google Scholar 

  12. M. Deumal, J. Cirujeda, J. Veciana, and J.J. Novoa, in Supramolecular Engineering of Synthetic Metallic Materials: Conductors and Magnets, NATO ASI Series C, Vol. 518, edited by J. Veciana, C. Rovira, and D.B. Amabilino (Kluwer Academic Publishers, 1998) p. 105

    Google Scholar 

  13. M. Deumal, J. Cirujeda, J. Veciana, and J.J. Novoa, Chem.— Eur. J. 5 (1999) p. 1617.

    Article  Google Scholar 

  14. M. Tamura, Y. Nakazawa, D. Shiomi, K. Nozawa, Y. Hosokoshi, M. Ishikawa, M. Takahashi, and M. Kinoshita, Chem. Phys. Lett. 186 (1991) p. 401

    Article  CAS  Google Scholar 

  15. Y. Nakazawa, M. Tamura, M. Shirakawa, D. Shiomi, M. Kinoshita, and M. Ishikawa, Phys. Rev. B 46 (1992) p. 8906.

    Article  CAS  Google Scholar 

  16. S.J. Blundell, P.A. Pattenden, R.M. Valladares, F.L. Pratt, T. Sugano, and E. Hayes, Solid State Commun. 92 (1994) p. 569

    Article  CAS  Google Scholar 

  17. T. Sugawara, M.M. Matsushita, A. Izuoka, N. Wada, N. Takeda, and M. Ishikawa, J. Chem. Soc., Chem. Commun. (1994) p. 1723

    Google Scholar 

  18. J. Cirujeda, M. Mas, E. Molins, F. Lanfranc de Panthou, J. Laugier, J.G. Park, C. Paulsen, P. Rey, C. Rovira, and J. Veciana, J. Chem. Soc., Chem. Commun. (1995) p. 709

    Google Scholar 

  19. A. Caneschi, F. Ferraro, D. Gatteschi, A. Le Lirzin, M.A. Novak, E. Rentschler, and R. Sessoli, Adv. Mater. 7 (1995) p. 476

    Article  CAS  Google Scholar 

  20. S.I. Nakatsuji, M. Saiga, N. Haga, A. Naito, T. Hirayama, M. Nakagawa, Y. Oda, H. Anzai, K. Suzuki, T. Enoki, M. Mito, and K. Takeda, New J. Chem. 22 (1998) p. 275.

    Article  CAS  Google Scholar 

  21. Hernàndez, M. Mas, E. Molins, C. Rovira, and J. Veciana, Angew. Chem., Int. Ed. Engl. 32 (1993) p. 882

    Article  Google Scholar 

  22. J. Cirujeda, E. Hernàndez-Gasio, C. Rovira, J.-L. Stanger, P. Turek, and J. Veciana, J. Mater. Chem. 5 (1995) p. 243

    Article  CAS  Google Scholar 

  23. J. Cirujeda, L.E. Ochando, J.M. Amigó, C. Rovira, J. Rius, and J. Veciana, Angew. Chem., Int. Ed. Engl. 34 (1995) p. 55

    Article  CAS  Google Scholar 

  24. J. Veciana, J. Cirujeda, C. Rovira, E. Molins, and J.J. Novoa, J. Phys. I France 6 (1996) p. 1967.

    Article  CAS  Google Scholar 

  25. T. Nogami, K. Tomioka, T. Ishida, H. Yoshikawa, M. Yasui, F. Iwasaki, H. Iwamura, N. Takeda, and M. Ishikawa, Chem. Lett. (1994) p. 29

    Google Scholar 

  26. K. Togashi, R. Imachi, K. Tomioka, H. Tsuboi, T. Ishida, T. Nogami, N. Takeda, and M. Ishikawa, Bull. Chem. Soc. Jpn. 69 (1996) p. 2821 and references cited therein.

    Article  CAS  Google Scholar 

  27. R. Chiarelli, A. Novak, A. Rassat, and J.L. Tholence, Nature 363 (1993) p. 147.

    Article  CAS  Google Scholar 

  28. For a review listing all nitroxide-based magnets, see D.B. Amabilino and J. Veciana, in MagnetoScience: Molecules to Materials, Vol. 1, edited by J. Miller and M. Drillon (Wiley-VCH, Weinheim, 2000).

  29. A. Rassat and R. Chiarelli, in Magnetic Molecular Materials, NATO ASI Series E, Vol. 198, edited by D. Gatteschi, O. Kahn, J.S. Miller, and F. Palacio (Kluwer Academic Publishers, Dordrecht, 1991) p. 191

  30. R. Chiarelli, A. Rassat, Y. Dromzee, Y. Jeannin, M.A. Novak, and J.L. Tholence, Phys. Scr., T 49B (1993) p. 706.

    Article  Google Scholar 

  31. A. Zheludev, R. Chiarelli, B. Delley, B. Gillon, A. Rassat, E. Ressouche, and J. Schweizer, J. Magn. Magn. Mater. 140-144 (1995) p. 1439.

    Article  CAS  Google Scholar 

  32. P. Fluekiger, J. Weber, R. Chiarelli, A. Rassat, and Y. Ellinger, Int. J. Quantum Chem. 45 (1993) p. 649.

    Article  CAS  Google Scholar 

  33. P.-M. Allemand, K.C. Khemani, A. Koch, F. Wudl, K. Holczer, S. Donovan, G. Grüner, and J.D. Thompson, Science 253 (1991) p. 301.

    Article  CAS  Google Scholar 

  34. C. Arcon, P. Cevc, A. Omerzu, and R. Blinc, Phys. Rev. Lett. 80 (1998) p. 1529.

    Article  CAS  Google Scholar 

  35. T.C. Kobayashi, M. Takiguchi, C.U. Hong, K. Maya, A. Kajiwara, A. Harada, and M. Kamachi, J. Magn. Magn. Mater. 140-144 (1995) p. 1447.

    Article  CAS  Google Scholar 

  36. T. Sugano, M. Tamura, M. Kinoshita, Y. Sakai, and Y. Ohashi, Chem. Phys. Lett. 200 (1992) p. 235

    Article  CAS  Google Scholar 

  37. Y. Pei, O. Kahn, L. Abersold, L. Ouahab, F. Lebarre, L. Pardi, and J.L. Tholence, Adv. Mater. 6 (1994) p. 681.

    Article  CAS  Google Scholar 

  38. A.J. Banister, N. Bricklebank, I. Lavender, J.M. Rawson, C.I. Gregory, B.K. Tanner, W. Clegg, M.R.J. Elsegood, and F. Palacio, Angew. Chem., Int. Ed. Engl. 35 (1996) p. 2433

    Article  Google Scholar 

  39. F. Palacio, G. Antorrena, R. Castro, R. Burriel, J.M. Rawson, J.N.B. Smith, N. Bricklebank, J.J. Novoa, and C. Ritter, Phys. Rev. Lett. 79 (1997) p. 2336.

    Article  CAS  Google Scholar 

  40. M.S. Platz, in Diradicals, edited by W.T. Borden (Wiley Interscience, New York, 1982) p. 195

    Google Scholar 

  41. A.E. Chichibabain, Ber. 40 (1907) p. 1810

    Article  Google Scholar 

  42. J. Thiele and H. Balhorn, Chem. Ber. 37 (1904) p. 1463

    Article  Google Scholar 

  43. W. Schlenk and M. Braun, Ber. 48 (1915) p. 661.

    Article  CAS  Google Scholar 

  44. For reviews discussing high-spin molecular approaches to organic magnetic materials, see J.S. Miller, A.J. Epstein, and W.M. Reiff, Chem. Rev. 88 (1988) p. 201

    Article  CAS  Google Scholar 

  45. H. Iwamura, Adv. Phys. Org. Chem. 26 (1990) p. 179

    CAS  Google Scholar 

  46. D.A. Dougherty, Acc. Chem. Res. 24 (1991) p. 88

    Article  CAS  Google Scholar 

  47. H. Iwamura and N. Koga, Acc. Chem. Res. 26 (1993) p. 346

    Article  CAS  Google Scholar 

  48. H. Kurreck, Angew. Chem., Int. Ed. Engl. 32 (1993) p. 1409

    Article  Google Scholar 

  49. A. Rajca, Chem. Rev. 94 (1994) p. 871.

    Article  CAS  Google Scholar 

  50. W.T. Borden, in Diradicals, edited by W.T. Borden (Wiley Interscience, New York, 1982) p. 1.

    Google Scholar 

  51. A.M. Trozzolo, R.W. Murray, G. Smolinsky, W.A. Yager, and E. Wasserman, J. Am. Chem. Soc. 85 (1963) p. 2526

    Article  CAS  Google Scholar 

  52. K. Itoh, Chem. Phys. Lett. 1 (1967) p. 235

    Article  CAS  Google Scholar 

  53. E. Wasserman, R.W. Murray, W.A. Yager, A.M. Trozzolo, and G. Smolinski, J. Am. Chem. Soc. 89 (1967) p. 5076.

    Article  CAS  Google Scholar 

  54. Y. Teki, T. Takui, K. Itoh, H. Iwamura, and K. Kobayashi, J. Am. Chem. Soc. 105 (1983) p. 3722

    Article  CAS  Google Scholar 

  55. T. Sugawara, S. Bandow, K. Kimura, H. Iwamura, and K. Itoh, J. Am. Chem. Soc. 106 (1984) p. 6449

    Article  CAS  Google Scholar 

  56. Y. Teki, T. Takui, H. Yagi, K. Itoh, and H. Iwamura, J. Chem. Phys. 83 (1985) p. 539

    Article  CAS  Google Scholar 

  57. T. Sugawara, S. Bandow, K. Kimura, and H. Iwamura, J. Am. Chem. Soc. 108 (1986) p. 368

    Article  CAS  Google Scholar 

  58. Y. Teki, T. Takui, K. Itoh, H. Iwamura, and K. Kobayashi, J. Am. Chem. Soc. 108 (1986) p. 2147

    Article  CAS  Google Scholar 

  59. I. Fujita, Y. Teki, T. Takui, T. Kinoshita, K. Itoh, F. Miko, Y. Sawaki, H. Iwamura, A. Izuoka, and T. Sugawara, J. Am. Chem. Soc. 112 (1990) p. 4074.

    Article  CAS  Google Scholar 

  60. A.I. Kitaigorodskii, Molecular Crystals and Molecules, Chapters 13, 14, and 31 (Academic Press, London, 1973).

    Google Scholar 

  61. T. Ishida, K. Inoue, N. Koga, N. Nakamura, and H. Iwamura, in Electrical, Optical, and Magnetic Properties of Organic Solid State Materials, edited by L.Y. Chiang, A.F. Garito, and D.J. Sandman (Mater. Res. Soc. Symp. Proc. 247, Pittsburgh, 1992) p. 407.

    CAS  Google Scholar 

  62. N. Mataga, Theor. Chim. Acta 10 (1968) p. 372.

    Article  CAS  Google Scholar 

  63. K. Matsuda, N. Nakamura, K. Takahashi, K. Inoue, N. Koga, and H. Iwamura, J. Am. Chem. Soc. 117 (1995) p. 5550

    Article  CAS  Google Scholar 

  64. K. Matsuda, N. Nakamura, K. Oinoue, N. Koga, and H. Iwamura, Bull. Chem. Soc. Jpn. 69 (1996) p. 1483.

    Article  CAS  Google Scholar 

  65. A. Rajca, J. Wongsrirantanakul, S. Rajca, and R. Cerny, Angew. Chem., Int. Ed. Engl. 37 (1998) p. 1229.

    Article  CAS  Google Scholar 

  66. J. Sedó, N. Ventosa, D. Ruiz-Molina, M. Mas, E. Molins, C. Rovira, and J. Veciana, Angew. Chem., Int. Ed. Engl. 37 (1998) p. 330

    Article  Google Scholar 

  67. N. Ventosa, D. Ruiz-Molina, J. Sedó, C. Rovira, X. Tomás, J.-J. André, A. Bieber, and J. Veciana, Chem. Eur. J. 5 (1999) p. 3533.

    Article  CAS  Google Scholar 

  68. H. Tomioka, M. Hattori, K. Hirai, K. Sato, D. Shiomi, T. Takui, and K. Itoh, J. Am. Chem. Soc. 120 (1998) p. 1106.

    Article  CAS  Google Scholar 

  69. A. Calder, A.R. Forrester, P.G. James, and G.R. Luckhurst, J. Am. Chem. Soc. 91 (1969) p. 3724

    Article  CAS  Google Scholar 

  70. K. Mukai, H. Nagai, and K. Ishizu, Bull. Chem. Soc. Jpn. 48 (1975) p. 2381

    Article  CAS  Google Scholar 

  71. T. Ishida and H. Iwamura, J. Am. Chem. Soc. 113 (1991) p. 4238

    Article  CAS  Google Scholar 

  72. F. Kanno, K. Inoue, N. Koga, and H. Iwamura, J. Phys. Chem. 97 (1993) p. 13267.

    Article  CAS  Google Scholar 

  73. K.R. Stickley and S.C. Blackstock, J. Am. Chem. Soc. 116 (1994) p. 11576.

    Article  CAS  Google Scholar 

  74. M.A. Murray, P. Kaszynski, D.A. Kasisaki, W.-H. Change, and D.A. Dougherty, J. Am. Chem. Soc. 116 (1994) p. 8152.

    Article  CAS  Google Scholar 

  75. Y. Sano, M. Tanaka, N. Koga, K. Matsuda, H. Iwamura, P. Rabu, and M. Drillon, J. Am. Chem. Soc. 119 (1997) p. 8246

    Article  CAS  Google Scholar 

  76. S. Karasawa, Y. Sano, T. Akita, N. Koga, T. Itoh, H. Iwamura, P. Rabu, and M. Drillon, J. Am. Chem. Soc. 120 (1998) p. 10080.

    Article  CAS  Google Scholar 

  77. K. Inoue and H. Iwamura, J. Am. Chem. Soc. 116 (1994), p. 3173

    Article  CAS  Google Scholar 

  78. H. Iwamura, K. Inoue, and T. Hayamizu, Pure Appl. Chem. 68 (1996) p. 243

    Article  CAS  Google Scholar 

  79. D.C. Oniciu, K. Matsuda, and H. Iwamura, J. Chem. Soc., Perkin Trans. 2 (1996) p. 907

    Google Scholar 

  80. H. Iwamura, K. Inoue, and N. Koga, New J. Chem. 22 (1998) p. 201

    Article  CAS  Google Scholar 

  81. A.S. Markosyan, T. Hayamizu, H. Iwamura, and K. Initroxideue, J. Phys.: Condens. Matter 10 (1998) p. 2323.

    CAS  Google Scholar 

  82. K. Matsuda and M. Irie, Chem. Lett. (2000) p. 16; Tetrahedron Lett. 41 (2000) p. 2577; J. Am. Chem. Soc. 122 (2000) in press.

    Google Scholar 

  83. W. Fujita and K. Awaga, Science 286 (1999) p. 261.

    Article  CAS  Google Scholar 

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Veciana, J., Iwamura, H. Organic Magnets. MRS Bulletin 25, 41–51 (2000). https://doi.org/10.1557/mrs2000.223

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