Skip to main content
Log in

Antiphotocorrosive photocatalysts containing CdS nanoparticles and exfoliated TiO2 nanosheets

  • Article
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

Aimed at designing an efficient visible light active photocatalyst and suppressing the self-corrosion tendency of CdS nanoparticles, a novel composite consisting of CdS nanoparticles and exfoliated two-dimensional (2D) TiO2 nanosheets was successfully fabricated using a simple self-assembly process. The prepared samples were characterized using various techniques including x-ray diffraction, ultraviolet–visible absorption spectroscopy, x-ray photoelectron spectroscopy, scanning electron microscopy, and transmission electron microscopy. It was found that the exfoliated 2D nanosheets played an important role as an ultrathin coating to suppress the photocorrosion of CdS nanoparticles, evidenced by inductively coupled plasma-atomic emission spectrometer analysis. The resultant CdS/TiO2 composites exhibited enhanced photocatalytic activity in the oxidation of Rhodamine B in water under visible light irradiation (λ > 420 nm).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M.A. Fox, M.T. Dulay Heterogeneous photocatalysis. Chem. Rev. 93, 341 (1993)

    Article  CAS  Google Scholar 

  2. A.L. Linsebigler, G.Q. Lu, J.T. Yates Photocatalysis on TiO2 surfaces: Principles, mechanisms, and selected results. Chem. Rev. 95, 735 (1995)

    Article  CAS  Google Scholar 

  3. M. Anpo, H. Yamashita, S.G. Zhang Photoinduced surface chemistry. Curr. Opin. Solid State Mater. Sci. 1, 630 (1996)

    Article  CAS  Google Scholar 

  4. P.V. Kamat Meeting the clean energy demand: Nanostructure architectures for solar energy conversion. J. Phys. Chem. C 111, 2834 (2007)

    Article  CAS  Google Scholar 

  5. M.R. Hoffmann, S.T. Martin, W.Y. Choi, D.W. Bahnemann Environmental applications of semiconductor photocatalysis. Chem. Rev. 95, 69 (1995)

    Article  CAS  Google Scholar 

  6. P.V. Kamat, D. Meisel Nanoparticles in advanced oxidation processes. Curr. Opin. Colloid Interface Sci. 7, 282 (2002)

    Article  CAS  Google Scholar 

  7. A. Fujishima, K. Honda Electrochemical photolysis of water at a semiconductor electrode. Nature 238, 37 (1972)

    Article  CAS  Google Scholar 

  8. O. Carp, C.L. Huisman, A. Reller Photoinduced reactivity of titanium dioxide. Prog. Solid State Chem. 32, 33 (2004)

    Article  CAS  Google Scholar 

  9. X. Chen, S.S. Mao Titanium dioxide nanomaterials: Synthesis, properties, modifications, and applications. Chem. Rev. 107, 2891 (2007)

    Article  CAS  Google Scholar 

  10. G. Liu, L.Z. Wang, C.H. Sun, Z.G. Chen, X.X. Yan, L.N. Chen, H.M. Cheng, G.Q. Lu Nitrogen-doped titania nanosheets towards visible light response. Chem. Commun. (Camb.) 2009, 1383 (2009)

    Article  Google Scholar 

  11. G. Liu, L.Z. Wang, C.H. Sun, X.X. Yan, X.W. Wang, Z.G. Chen, S.C. Smith, H.M. Cheng, G.Q. Lu Band-to-band visible-light photon excitation and photoactivity induced by homogeneous nitrogen doping in layered titaniate. Chem. Mater. 21, 1266 (2009)

    Article  Google Scholar 

  12. R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, Y. Taga Visible-light photocatalysis in nitrogen-doped titanium oxides. Science 293, 269 (2001)

    Article  CAS  Google Scholar 

  13. L.W. Zhang, H.B. Fu, Y.F. Zhu Efficient TiO2 photocatalysts from surface hybridization of TiO2 particles with graphite-like carbon. Adv. Funct. Mater. 18, 2180 (2008)

    Article  CAS  Google Scholar 

  14. X. Zong, H.J. Yan, G.P. Wu, G.J. Ma, F.Y. Wen, L. Wang, C. Li Enhancement of photocatalytic H-2 evolution on CdS by loading MOS2 as cocatalyst under visible light irradiation. J. Am. Chem. Soc. 130, 7176 (2008)

    Article  CAS  Google Scholar 

  15. M. Anpo, M. Takeuchi The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation. J. Catal. 216, 505 (2003)

    Article  CAS  Google Scholar 

  16. J.C. Yu, L. Wu, J. Lin, P.S. Li, Q. Li Microemulsion-mediated solvothermal synthesis of nanosized CdS-sensitized TiO2 crystalline photocatalyst. Chem. Commun. (Camb.). 1552 (2003)

    Google Scholar 

  17. Y. Bessekhouad, N. Chaoui, M. Trzpit, N. Ghazzal, D. Robert, J.V. Weber UV–vis versus visible degradation of Acid Orange II in a coupled CdS/TiO2 semiconductors suspension. J. Photochem. Photobiol., A 183, 218 (2006)

    Article  CAS  Google Scholar 

  18. L.A. Silva, S.Y. Ryu, J. Choi, W. Choi, M.R. Hoffmann Photocatalytic hydrogen production with visible light over Pt-interlinked hybrid composites of cubic-phase and hexagonal-phase CdS. J. Phys. Chem. C 112, 12069 (2008)

    Article  CAS  Google Scholar 

  19. Y. Bessekhouad, D. Robert, J. Weber Bi2S3/TiO2 and CdS/TiO2 heterojunctions as an available configuration for photocatalytic degradation of organic pollutant. J. Photochem. Photobiol., A 163, 569 (2004)

    Article  CAS  Google Scholar 

  20. Y.G. Guo, J.S. Hu, H.P. Liang, L.J. Wan, C.L. Bai TiO2-based composite nanotube arrays prepared via layer-by-layer assembly. Adv. Funct. Mater. 15, 196 (2005)

    Article  CAS  Google Scholar 

  21. J.S. Jang, S.H. Choi, H. Park, W. Choi, J.S. Lee A composite photocatalyst of CdS nanoparticles deposited on TiO2 nanosheets. J. Nanosci. Nanotechnol. 6, 3642 (2006)

    Article  CAS  Google Scholar 

  22. L. Wu, J.C. Yu, X.Z. Fu Characterization and photocatalytic mechanism of nanosized CdS coupled TiO2 nanocrystals under visible light irradiation. J. Mol. Catal. A: Chem. 244, 25 (2006)

    Article  CAS  Google Scholar 

  23. S.Y. Ryu, W. Balcerski, T.K. Lee, M.R. Hoffmann Photocatalytic production of hydrogen from water with visible light using hybrid catalysts of CdS attached to microporous and mesoporous silicas. J. Phys. Chem. C 111, 18195 (2007)

    Article  CAS  Google Scholar 

  24. Di A. Paola, M. Addamo, L. Palmisano Mixed oxide/sulfide systems for photocatalysis. Res. Chem. Interm ed. 29, 467 (2003)

    Article  Google Scholar 

  25. T. Sasaki, M. Watanabe Osmotic swelling to exfoliation. Exceptionally high degrees of hydration of a layered titanate. J. Am. Chem. Soc. 120, 4682 (1998)

    Article  CAS  Google Scholar 

  26. T. Sasaki, Y. Ebina, T. Tanaka, M. Harada, M. Watanabe, G. Decher Layer-by-layer assembly of titania nanosheet/polycation composite films. Chem. Mater. 13, 4661 (2001)

    Article  CAS  Google Scholar 

  27. L.Z. Wang, T. Sasaki, Y. Ebina, Y. Kurashiya, M. Watanabe Fabrication of controllable ultrathin hollow shells by layer-by-layer assembly of exfoliated titania nanosheets on polymer templates. Chem. Mater. 14, 4827 (2002)

    Article  CAS  Google Scholar 

  28. L.Z. Wang, Y. Ebina, K. Takada, T. Sasaki Ultrathin films and hollow shells with pillared architectures fabricated via layer-by-layer self-assembly of titania nanosheets and aluminum Keggin Ions. J. Phys. Chem. B 108, 4283 (2004)

    Article  CAS  Google Scholar 

  29. L.Z. Wang, Y. Ebina, K. Takada, T. Sasaki A new mesoporous manganese oxide pillared with double layers of alumina. Adv. Mater. 16, 1412 (2004)

    Article  CAS  Google Scholar 

  30. N. Sakai, Y. Ebina, K. Takada, T. Sasaki Electronic band structure for titania semiconductor nanosheets revealed by electrochemical and photoelectrochemical studies. J. Am. Chem. Soc. 126, 5851 (2004)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Lianzhou Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yan, X., Liu, G., Wang, L. et al. Antiphotocorrosive photocatalysts containing CdS nanoparticles and exfoliated TiO2 nanosheets. Journal of Materials Research 25, 182–188 (2010). https://doi.org/10.1557/JMR.2010.0007

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/JMR.2010.0007

Navigation