Abstract
A solvothermal method was used to prepare zirconia and yttria-stabilized zirconia (YSZ) particles using zirconium hydroxide and yttrium hydroxide particles as precursors and ethanol or isopropanol as reaction media. The particle properties were characterized with x-ray diffractometry, scanning electron microscopy, transmission electron microscopy, thermal analysis, laser particle-size analysis, nitrogen adsorption (Brunauer–Emmett–Teller method) and Zeta potential analysis. Cubic/tetragonal ZrO2 and YSZ nanocrystals with crystallite size around 5 nm were obtained. The effect of different hydroxide precursors, attrition milling of hydroxide precursors, solvothermal processing conditions, and mineralizer was investigated and discussed by referring to the crystallization process of zirconium hydroxides.
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References
F.F. Lange: Powder processing science and technology for increased reliability. J. Am. Ceram. Soc. 72, 3 (1989).
J.S. Reed: Principles of Ceramic Processing, 2nd ed. (John Wiley & Sons, 1995).
Science and Technology of Zirconia III edited by S. Somiya, N. Yamamoto, and N.Y. Yanagida (American Ceramic Society, Columbus, OH, 1988).
J.R. Groza: Nanosintering. Nanostruct. Mater. 12, 987 (1999).
M.J. Mayo: Processing of nanocrystalline ceramics from ultrafine particles. Int. Mater. Rev. 41, 85 (1996).
M.J. Mayo, A. Suresh, and W.D. Porter: Thermodynamics for nanosystems: Grain and particle-size dependent phase diagrams. Rev. Adv. Mater. Sci. 5, 100 (2003).
J.A. Lewis: Colloidal processing of ceramics. J. Am. Ceram. Soc. 83, 2341 (2000).
T. Tsukada, S. Venigalla, A.A. Morrone, and J.H. Adair: Low-temperature hydrothermal synthesis of yttrium-doped zirconia powders. J. Am. Ceram. Soc. 82, 1169 (1999).
S. Somiya and T. Akiba: Hydrothermal zirconia powders: A bibliography. J. Eur. Ceram. Soc. 9, 81 (1999).
R.R. Piticescu, C. Monty, D. Taloi, A. Motoc, and S. Axinte: Hydrothermal synthesis of zirconia nanomaterials. J. Eur. Ceram. Soc. 21, 2057 (2001).
E. Tani, M. Yoshimura, and S. Somiya: Formation of ultrafine tetragonal ZrO2 powder under hydrothermal conditions. J. Am. Ceram. Soc. 66, 11 (1983).
H. Nishizawa, N. Yamasaki, and K. Matsuoka: Crystallization and transformation of zirconia under hydrothermal conditions. J. Am. Ceram. Soc. 65, 343 (1982).
G. Dell’Agli and G. Mascolo: Hydrothermal synthesis of ZrO2–Y2O3 solid solutions at low temperature. J. Eur. Ceram. Soc. 20, 139 (2000).
X.M. Wang, G. Lorimer, and P. Xiao: Solvothremal synthesis and processing of yttria-stabilized zirconia nanopowder. J. Am. Ceram. Soc. 88, 809 (2005).
H. Zile, X.M. Wang, P. Xiao, and J. Shi: Solvent effect on microstructure of yttria-stabilized zirconia (YSZ) particles in solvothermal synthesis. J. Eur. Ceram. Soc. 26, 2257 (2006).
Y.B. Khollam, A.S. Deshpande, A.J. Patil, H.S. Potdar, S.B. Deshpande, and S.K. Date: Synthesis of yttria stabilized cubic zirconia (YSZ) powders by microwave-hydrothermal route. Mater. Chem. Phys. 71, 235 (2001).
G. Dell’Agli, A. Colantuono, and G. Mascolo: The effect of mineralizers on the crystallization of zirconia gel under hydrothermal conditions. Solid State Ionics 123, 87 (1999).
G. Dell’Agli and G. Mascolo: Zirconia-yttria (8 mol%) powder hydrothermally synthesized from different y-based precursors. J. Eur. Ceram. Soc. 24, 915 (2004).
J. Zhao, W. Fan, D. Wu, and Y. Sun: Stable nanocrystalline zirconia sols prepared by a novel method: Alcohol thermal synthesis. J. Mater. Res. 15, 402 (2000).
M. Inoue, H. Kominami, and T. Inui: Solvothermal synthesis of large surface area zirconia. Res. Chem. Intermed. 24, 571 (1998).
H.J. Noh, D.S. Seo, H. Kim, and J.K. Lee: Synthesis and crystallization of anisotropic shaped ZrO2 nanocrystalline powders by hydrothermal process. Mater. Lett. 57, 2425 (2003).
Y.W. Zhang, G. Xu, Z.G. Yan, Y. Yang, C.S. Liao, and C.H. Yan: Nanocrystalline rare earth stabilized zirconia: Solvothermal synthesis via heterogeneous nucleation-growth mechanism, and electrical properties. J. Mater. Chem. 12, 970 (2002).
G. Dell’Agli and G. Mascolo: Agglomeration of 3 mol% Y-TZP powders synthesized by hydrothermal treatment. J. Eur. Ceram. Soc. 21, 29 (2001).
Y.V. Kolen’ko, V.D. Maximov, A.A. Burukhin, V.A. Muhanov, and B.R. Churagulov: Synthesis of ZrO2 and TiO2 nanocrystalline powders by hydrothermal process. Mater. Sci. Eng., C 23, 1033 (2003).
C.D. Sagel-Ransijn, A.J.A Winubst, A.J. Burggraaf, and H. Verweij: The influence of crystallization and washing medium on the characteristics of nanocrystalline Y-TZP. J. Eur. Ceram. Soc. 16, 159 (1996).
D.L. Norton: Theory of hydrothermal systems. Ann. Rev. Earth Planet. Sci. 12, 155 (1984).
C. Huang, Z. Tang, and Z. Zhang: Differences between zirconium hydroxide [Zr(OH)4· n H2O] and hydrous zirconia (ZrO2·n H2O). J. Am. Ceram. Soc. 84, 1637 (2001).
K. Matsui and M. Ohgai: Formation mechanism of hydrous zirconia particles produced by hydrolysis of ZrOCl2 solutions: IV. Effects of ZrOCl2 concentration and reaction temperature. J. Am. Ceram. Soc. 85, 545 (2002).
G.M. Muha and P.A. Vaughan: Structure of the complex ion in aqueous solutions of zirconyl and hafnyl oxyhalides. J. Chem. Phys. 33, 194 (1960).
A. Clearfield: Structural aspects of zirconium chemistry. Rev. Pure Appl. Chem. 14, 91 (1964).
C. Kaya, J.Y. He, X. Gu, and E.G. Butler: Nanostructured ceramic powders by hydrothermal synthesis and their application. Microporous Mesoporous Mater. 54, 37 (2002).
Lange’s Handbook of Chemistry, 15th ed., edited by J.A. Dean (McGraw-Hill, Columbus, OH, 1999).
S. Komarneni, R. Roy, and Q.H. Li: Microwave-hydrothermal synthesis of ceramic powders. Mater. Res. Bull. 27, 1393 (1992).
Y. Zhang, G. Xu, Z. Yan, Y. Yang, C. Liao, and C. Yan: Nanocrystalline rare earth stabilized zirconia: Solvothermal synthesis via heterogeneous nucleation-growth mechanism, and electrical properties. J. Mater. Chem. 12, 970 (2002).
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Wang, X.M., Xiao, P. Solvothermal synthesis of zirconia and yttria-stabilized zirconia nanocrystalline particles. Journal of Materials Research 22, 46–55 (2007). https://doi.org/10.1557/jmr.2007.0012
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DOI: https://doi.org/10.1557/jmr.2007.0012