Abstract
Multi-epoxy functional - glycidyl ether is used as a cross-linking epoxy compound between modified 22'44'-tetrahydroxybenzophenone and silicone molecules. The adduct reaction products, as effective abrasion resistant coatings and yet reactive in the sol gel process, are formulated into the colloidal based polysiloxane resin as an essential part of the solution for dip coating sheets. Such coatings incorporate ultraviolet radiation selection or absorbing compounds with superb chemical stability and mechanical strength for coatings on substrates such as glass. The hardness of these coatings was measured at 6H following ASTM (D-3363) film hardness by pencil test. The resulting coatings were exposed to ultraviolet (UV-A) radiation during a time greater than 600 hours. The exposed samples still maintain excellent absorption in the UV range.
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References
Handbook of Material Weathering, George Wypych, ed., Williams Andre Publishing, Chenil & Publishing, Toronto & New York, 2003.
MIL - C — 675c, Section 4.5.10 — Eraser Rub Test. Standard Test Method for Determining Abrasion Resistance of Coating on Glass Substrates.
MIL - C — 48497A, Section 4.5.3.1 — Tape Test. Standard Test Method for Determining Coating Adhesion on Glass Substrates.
D3363-92a — American Standard Test Method for Film Hardness by Pencil Test.
ASTM G154-00a1 — Standard Practice for Operating Fluorescent Light Apparatus for UV Exposure of Nonmetallic Materials, adopted 2000.
ASTM D 4587-01 — Standard Practice for Fluorescent UV-Condensation Exposures of Paint and Related Coatings, adopted 2001.
Acknowledgments
The authors would like to acknowledge the support and help by
I — FTIR measurements taken by Prof. Dr. Lisa C. Klein’s Sol-gel group at Rutgers, The State University of New Jersey.
II — Exposure to UV radiation and Humidity Chamber experiments performed by Prof. Dr. Rolf Clasen at Universität des Saarlandes, Saarbrücken, Germany.
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Arfsten, N., Alvarez, M.A. “Abrasion Resistant Coatings with Ultraviolet Absorption, via sol-gel dipping method.”. MRS Online Proceedings Library 847, 230–238 (2004). https://doi.org/10.1557/PROC-847-EE13.44
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DOI: https://doi.org/10.1557/PROC-847-EE13.44