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Metal Cyanide Networks Formed at an Air-Water Interface: Structure and Magnetic Properties

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Abstract

Extended two-dimensional coordinate covalent networks have been formed at an air-water interface by condensing a Langmuir monolayer of an amphiphillic pentacyanoferrate(III) complex and aqueous nickel(II) ions. The cyanide-bridged arrays were transferred to solid supports by the Langmuir-Blodgett (LB) technique. The resulting thin films were structurally characterized by UV-Vis and FT-IR spectroscopies, X-ray diffraction, X-ray photoelectron spectroscopy (XPS), and SQUID magnetometry. Magnetic measurements on the thin films transferred to Mylar show evidence for ferromagnetic exchange interactions between the S = 1/2 Fe(III) and S = 1 Ni(II) centers.

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Authors and Affiliations

  1. Department of Chemistry, University of Florida, Gainesville, FL, USA

    Jeffrey T. Culp & Daniel R. Talham

  2. Department of Physics, University of Florida, Gainesville, FL, USA

    A. Nicole Morgan & Mark W. Meisel

Authors
  1. Jeffrey T. Culp
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  2. A. Nicole Morgan
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  3. Mark W. Meisel
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  4. Daniel R. Talham
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Culp, J.T., Morgan, A.N., Meisel, M.W. et al. Metal Cyanide Networks Formed at an Air-Water Interface: Structure and Magnetic Properties. MRS Online Proceedings Library 658, 52 (2000). https://doi.org/10.1557/PROC-658-GG5.2

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  • DOI: https://doi.org/10.1557/PROC-658-GG5.2

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