Skip to main content
Log in

Dynamic Specific Heat of a Metallic Glass-Former

  • Published:
MRS Online Proceedings Library Aims and scope

Abstract

Modulated temperature calorimetry measurements on the bulk glass forming Pd40Ni40P20 alloy are reported in the frequency range between 1/30 s−1 and 1/1000 s−1. These measurements represent the first experimental assessment of the slow relaxation modes of a metallic liquid over a substantial frequency interval. The results reveal the typical behavior known for dissipative systems. The frequency-dependence of the dynamic specific heat is compared to results of dynamic rheology measurements that have been performed on the same material at similar modulation frequencies to compare the dynamic response of the respective modes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. A. Heesemann, K. Rätzke, F. Faupel, J. Hoffmann and K. Heinemann, Europhys. Lett., 29, 221 (1995).

    Article  Google Scholar 

  2. R. Busch, JOM, 7, 39 (2000).

    Article  Google Scholar 

  3. N.O. Birge, Phys. Rev. B, 34, 1631 (1986).

    Article  CAS  Google Scholar 

  4. P.S. Gill, S.R. Sauerbrunn and M. Reading, J. Therm. Anal., 40, 931 (1993).

    Article  CAS  Google Scholar 

  5. X. Hu, T.B. Tan, Y. Li, G. Wilde and J.H. Perepezko, J. Non-Cryst. Solids, 260, 228 (1999).

    Article  CAS  Google Scholar 

  6. J.E.K. Schawe, Thermochim. Acta, 260, 1 (1995).

    Article  CAS  Google Scholar 

  7. O. Bustin and M. Descamps, J. Chem. Phys., 110, 10982 (1999).

    Article  CAS  Google Scholar 

  8. J. Jäckle, Phys. Bl, 52, 351 (1996).

    Article  Google Scholar 

  9. K. Schröter, G. Wilde, R. Willnecker, M. Weiss, K. Samwer and E. Donth, Eur. Phys. J., 5, 1 (1998).

    Article  Google Scholar 

  10. G. Wilde, G.P. Görler, R. Willnecker and H.J. Fecht, J. Appl. Phys., 87, 1141 (2000).

    Article  CAS  Google Scholar 

  11. W. Kauzmann, Chem. Rev., 43, 219 (1948).

    Article  CAS  Google Scholar 

  12. G. Wilde, G.P. Görler, R. Willnecker and G. Dietz, Appl. Phys. Lett., 65, 397 (1994).

    Article  CAS  Google Scholar 

  13. M. Beiner, J. Korus, H. Lockwenz, K. Schröter and E. Donth, Macromolecules, 29, 5183 (1996).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wilde, G. Dynamic Specific Heat of a Metallic Glass-Former. MRS Online Proceedings Library 644, 33 (2000). https://doi.org/10.1557/PROC-644-L3.3

Download citation

  • Published:

  • DOI: https://doi.org/10.1557/PROC-644-L3.3

Navigation